Composition and method for preparing the same

Patent metadata

Field	Value
Publication number	US-2024228421-A1
Application number	US-202218148648-A
Country	US
Kind code	A1
Filing date	Dec 30, 2022
Priority date	Dec 30, 2022
Publication date	Jul 11, 2024
Grant date	—

Abstract

A composition and a method for preparing the same are provided. The method for preparing the composition includes providing a polyethylene terephthalate waste. The polyethylene terephthalate waste is subjected to a depolymerization in the presence of a catalyst and an alcoholysis agent to obtain a mixture, wherein an oxidizing atmosphere is continuously introduced into the depolymerization. The mixture is subjected to a solid-liquid separation to obtain a solid. The solid is subjected to a purification to obtain the composition.

First claim

What is claimed is:

1 . A method for preparing a composition, comprising:
providing a polyethylene terephthalate waste; subjecting the polyethylene terephthalate waste to a depolymerization in the presence of a catalyst and an alcoholysis agent to obtain a mixture, wherein an oxidizing atmosphere is continuously introduced into the depolymerization; subjecting the mixture to a solid-liquid separation, obtaining a solid; and subjecting the solid to a purification, obtaining the composition.

2 . The method as claimed in claim 1 , wherein the polyethylene terephthalate waste is polyethylene terephthalate bottle sheet, polyethylene terephthalate fabric, polyethylene terephthalate film, or a combination thereof.

3 . The method as claimed in claim 1 , wherein the catalyst comprises metal oxide, metal hydroxide, metal alkoxide, metal organic acid salt, metal carbonate, or a combination thereof.

4 . The method as claimed in claim 1 , wherein the catalyst comprises lithium oxide, lithium hydroxide, lithium acetate, lithium carbonate, sodium oxide, sodium hydroxide, sodium acetate, sodium carbonate, potassium oxide, potassium hydroxide, potassium acetate, magnesium oxide, magnesium hydroxide, magnesium acetate, carbonic acid Magnesium, calcium oxide, calcium hydroxide, calcium acetate, calcium carbonate, titanium oxide, titanium hydroxide, titanium acetate, titanium carbonate, zinc oxide, zinc hydroxide, zinc acetate, zinc carbonate, manganese oxide, manganese hydroxide, manganese acetate, manganese carbonate, tin acetate, antimony oxide, sodium methoxide, sodium ethoxide, potassium methoxide, potassium ethoxide, or a combination thereof.

5 . The method as claimed in claim 1 , wherein the alcoholysis agent is a dihydric alcohol.

6 . The method as claimed in claim 1 , wherein the alcoholysis agent is mono-ethylene glycol, diethylene glycol, propylene glycol, butylene glycol, or a combination thereof.

7 . The method as claimed in claim 1 , wherein the oxidizing atmosphere comprises oxygen, ozone, or a combination thereof.

8 . The method as claimed in claim 1 , wherein the depolymerization has a temperature of 140° C. to 240° C., and the depolymerization has a process time of 0.5 hour to 8 hours.

9 . The method as claimed in claim 1 , wherein the purification comprises a recrystallization treatment.

10 . The method as claimed in claim 9 , wherein the purification further comprises an adsorption treatment.

11 . The method as claimed in claim 1 , wherein a ratio of a flow rate of the oxidizing atmosphere to a weight of the polyethylene terephthalate waste and the alcoholysis agent is 100 sccm/Kg to 3,000 sccm/Kg.

12 . A composition, comprising:
99.5 wt % to 99.997 wt % of a compound, wherein the compound is bis(2-hydroxyethyl) terephthalate, or a combination of bis(2-hydroxyethyl) terephthalate and bis(2-hydroxyethyl) terephthalate oligomer; 0.001 wt % to 0.25 wt % of mono(2-hydroxyethyl) terephthalate; and 0.001 wt % to 0.25 wt % of 2-hydroxyethyl[2-(2-hydroxyethoxy)ethyl]terephthalate, based on the weight of the composition.

13 . The composition as claimed in claim 12 , wherein the compound is a combination of bis(2-hydroxyethyl) terephthalate (BHET) and bis(2-hydroxyethyl) terephthalate oligomer, wherein an amount of bis(2-hydroxyethyl) terephthalate is 97 wt % to 99.897 wt %, and an amount of bis(2-hydroxyethyl) terephthalate oligomer is 0.1 wt % to 2.45 wt %, based on the weight of the composition.

14 . The composition as claimed in claim 12 , further comprising:
0.00001 wt % to 0.003 wt % of catalyst, based on the weight of the composition.

Assignees

• Ind Tech Res Inst

Inventors

• Kuo Shin-Liang
• Tung Yu-Lan
• Chang Wen-Sheng
• Huang Kung-Hsun
• Lee Tein-San
• Huang Shu-Chuan

Classifications

• B01J21/063

  Titanium; Oxides or hydroxides thereof · CPC title

• C07C69/82

  Terephthalic acid esters · CPC title

• C07C67/00 Primary

  Preparation of carboxylic acid esters · CPC title

• C07C67/03

  by reacting an ester group with a hydroxy group · CPC title

• C08J11/24

  containing hydroxyl groups · CPC title