Room-temperature operable all-solid-state battery

Patent metadata

Field	Value
Publication number	US-2024213452-A1
Application number	US-202318242945-A
Country	US
Kind code	A1
Filing date	Sep 6, 2023
Priority date	Dec 22, 2022
Publication date	Jun 27, 2024
Grant date	—

Abstract

Disclosed is an all-solid-state battery, which includes a plurality of intermediate layers including a first layer including a carbon material and a second layer including a metal and disposed on at least one surface of the first layer, and in which a lithium precipitation layer in which lithium is electrodeposited is located at the interface of an anode current collector at 40° C. or less, thereby improving volume expansion of the all-solid-state battery and maximizing battery performance.

First claim

What is claimed is:

1 . An all-solid-state battery comprising:
an anode current collector; a lithium inducing layer disposed on the anode current collector; a solid electrolyte layer disposed on the lithium inducing layer such that the lithium inducing layer is disposed between the anode current collector and the solid electrolyte layer; a cathode layer disposed on the solid electrolyte layer such that the solid electrolyte layer is disposed between the lithium inducing layer and the cathode layer; and a cathode current collector disposed on the cathode layer such that the cathode layer is disposed between the solid electrolyte layer and the cathode current collector, wherein the lithium inducing layer comprises a plurality of intermediate layers, wherein the plurality of intermediate layers comprises a first layer comprising a carbon material and a second layer comprising a metal capable of alloying with lithium, and wherein the second layer is disposed on at least one surface of the first layer.

2 . The all-solid-state battery of claim 1 , further comprising:
a lithium precipitation layer disposed between the anode current collector and the lithium inducing layer when charged.

3 . The all-solid-state battery of claim 2 , wherein a volume of the first layer is reduced by a volume that is expanded by the lithium precipitation layer.

4 . The all-solid-state battery of claim 1 , wherein the all-solid-state battery has a volume change of 1% or less between State of Charge (SOC) 100 and SOC 0 .

5 . The all-solid-state battery of claim 1 , wherein the lithium inducing layer is disposed between the anode current collector and the solid electrolyte layer so that the second layer of the plurality of intermediate layers faces the solid electrolyte layer and the first layer of the plurality of intermediate layers faces the anode current collector.

6 . The all-solid-state battery of claim 1 , wherein the carbon material of the first layer of the plurality of intermediate layers comprises carbon nanotubes, vapor-grown carbon fibers, carbon nanofibers, or any combination thereof.

7 . The all-solid-state battery of claim 1 , wherein the carbon material of the first layer of the plurality of intermediate layers does not react electrochemically with lithium ions during charging.

8 . The all-solid-state battery of claim 1 , wherein the metal of the second layer of the plurality of intermediate layers comprises aluminum, zinc, indium, silver, gold, magnesium, silicon, bismuth, germanium, platinum, antimony, or any combination thereof.

9 . The all-solid-state battery of claim 1 , wherein the second layer of the plurality of intermediate layers is deposited on the first layer of the plurality of intermediate layers.

10 . The all-solid-state battery of claim 1 , wherein at least a portion of the metal in the second layer of the plurality of intermediate layers is configured to form an alloy with lithium ions when the all-solid-state battery is charged.

11 . The all-solid-state battery of claim 1 , wherein a weight per unit area of the metal of the second layer of the plurality of intermediate layers is in a range of 0.05 mg/cm 2 to 0.30 mg/cm 2 .

12 . The all-solid-state battery of claim 1 , wherein the plurality of intermediate layers has a ratio (A/B) of a weight (A) of the metal of the second layer of the plurality of intermediate layers per unit area and a weight (B) of the carbon material of the first layer of the plurality of intermediate layers per unit area in a range of 0.1 to 1.

13 . The all-solid-state battery of claim 1 , wherein the plurality of intermediate layers has a thickness of 6 μm or less.

14 . The all-solid-state battery of claim 1 , wherein the lithium inducing layer has a thickness in a range of 10 μm to 20 μm.

15 . The all-solid-state battery of claim 1 , wherein an operation temperature of the all-solid-state battery is 40° C. or less.

16 . The all-solid-state battery of claim 1 , wherein lithium metal is not present in the first layer when the all-solid-state battery is charged.

Assignees

• Hyundai Motor Co Ltd
• Kia Corp

Inventors

• Kim Seon Hwa
• Choi Hong Suk
• Kang Hee Soo
• Lim Jae Min
• Kim Sang Wan

Classifications

• H01M10/0585

  of accumulators having only flat construction elements, i.e. flat positive electrodes, flat negative electrodes and flat separators · CPC title

• H01M10/0562 Primary

  Solid materials · CPC title

• H01M10/052 Primary

  Li-accumulators · CPC title

• H01M2300/0094

  in the form of layered products, e.g. coatings · CPC title

• H01M2300/0068

  inorganic · CPC title