Use of fluoropolymer film as release film in a method for shaping composite material

Patent metadata

Field	Value
Publication number	US-2024208110-A1
Application number	US-202218556633-A
Country	US
Kind code	A1
Filing date	Apr 21, 2022
Priority date	Apr 23, 2021
Publication date	Jun 27, 2024
Grant date	—

Abstract

The present invention relates to the use of a single layer fluoropolymer film selected from ethylene tetrafluoroethylene film and polytetrafluoroethylene film as release film in a method for shaping a composite material.

First claim

1 . Use of a single layer fluoropolymer film selected from ethylene tetrafluoroethylene film and polytetrafluoroethylene film, as release film in a method for shaping a composite material, wherein the method comprises:
(a) placing a substantially planar composite material between an upper fluoropolymer film and a lower fluoropolymer film by creating a pocket between the upper fluoropolymer film and the lower fluoropolymer film which houses the composite material, (b) bringing the upper fluoropolymer film and the lower fluoropolymer film into intimate contact with the composite material, thereby forming a layered structure, wherein the composite material is held stationary between the upper fluoropolymer film and the lower fluoropolymer film until heat or force is applied to the layered structure; (c) optionally pre-heating the layered structure in a heating apparatus at a temperature sufficient to either lower the viscosity of the composite material or soften the upper fluoropolymer film and the lower fluoropolymer film; (d) positioning the layered structure in a press tool comprising a male mold and a corresponding female mold separated by a gap, wherein the male mold and the female mold each independently have a non-planar molding surface, (e) compressing the layered structure between the male mold and the female mold by closing the gap between the male mold and the female mold; and (f) maintaining the male mold and the female mold in a closed position until a viscosity of the layered structure reaches a level sufficient to maintain a molded shape.

2 . The use of claim 1 , wherein the single layer fluoropolymer film has
a melt temperature (T melt ) no less than about 240° C., a thickness (t) in a range of about 10 microns to about 200 microns, An Elastic Modulus (E) in a range of about 300 to about 950 MPa, a Tensile Strength (σ) in a range of about 30 to about 90 MPa, and elongation at break (ε) in a range of about 400 to about 700% in either longitudinal or transverse directions at a rate of about 8 mm/s, under ambient conditions.

3 . The use of claim 1 , wherein the upper fluoropolymer film and the lower fluoropolymer film are the same film.

4 . The use of claim 1 , wherein the single layer fluoropolymer film comprises ethylene tetrafluoroethylene film.

5 . The use of claim 1 , wherein the single layer fluoropolymer film comprises polytetrafluoroethylene film.

6 . The use of claim 4 , wherein the ethylene tetrafluoroethylene film has
a melt temperature (T melt ) no less than about 240° C., a thickness (t) in a range of about 30 microns to about 100 microns an Elastic Modulus (E) in a range of about 500 to about 900 MPa a Tensile Strength (σ) in a range of about 45 to about 90 MPa and an elongation at break (ε) in a range of about 400 to about 700% in either longitudinal or transverse directions at a rate of about 8 mm/s, under ambient conditions.

7 . The use of claim 5 , wherein the polytetrafluoroethylene film has
a melt temperature (T melt ) no less than about 300° ° C., a thickness (t) in a range of about 30 microns to about 100 microns, an Elastic Modulus (E) in a range of about 300 to about 500 MPa, preferably of about 350 to about 450 MPa, a Tensile Strength (σ) in a range of about 30 to about 55 MPa, preferably of about 35 to about 50 MPa, and an elongation at break (ε) in a range of about 400 to about 700%, in either longitudinal or transverse directions at a rate of about 8 mm/s, under ambient conditions.

8 . The use of claim 1 , wherein step (e) comprises partially closing the gap between the male mold and the female mold such that a smaller gap is formed between the molds, which smaller gap is subsequently closed after a specific time or viscosity is reached.

9 . The use of claim 1 , wherein the male mold and the female mold are maintained at a temperature above ambient temperature.

10 . The use of claim 9 , wherein the male mold and the female mold are maintained at a temperature above 100° C.

11 . The use of claim 1 , wherein step (e) comprises closing the gap between the male mold and the female mold at a speed of between about 0.7 mm/s and about 400 mm/s, while maintaining the male mold and the female mold at a temperature above a softening point of the composite material.

12 . The use of claim 1 , wherein the upper film and the lower film are held together by a structural frame comprising a top frame, a center frame and a bottom frame, wherein:
the lower film is held between the bottom frame and the center frame; and the upper film is held between the center frame and the top frame.

13 . The use of claim 12 , wherein the center frame supplies a source of vacuum to the assembly.

14 . The use of claim 1 , wherein the upper film and the lower film are held together by a structural frame comprising a top frame and a bottom frame, wherein both the lower film and the upper film are held between the bottom frame and the top frame.

15 . The use of claim 1 , wherein the layered structure is positioned in the press tool and in the optional heating apparatus by automated means.

16 . The use of claim 1 , wherein the substantially planar composite material comprises structural fibers of a material selected from aramid, high-modulus polyethylene (PE), polyester, poly-p-phenylene-benzobisoxazole (PBO), carbon, glass, quartz, alumina, zirconia, silicon carbide, basalt, natural fibers and combinations thereof.

17 . The use of claim 1 , wherein the composite material comprises a binder or matrix material selected from thermoplastic polymers, thermoset resins, and combinations thereof.

Assignees

• Solvay

Inventors

• Key Ross A
• Goffin Anne-Lise

Classifications

• B32B2307/748

  Releasability · CPC title

• B32B2307/54

  Yield strength; Tensile strength · CPC title

• B32B2307/51

  Elastic · CPC title

• B32B2307/30

  having particular thermal properties · CPC title

• B32B2262/106

  Carbon fibres, e.g. graphite fibres · CPC title