Protective layer on anode-facing surface of separator for mitigating polysufide shuttling in lithium-based batteries

Patent metadata

Field	Value
Publication number	US-2024204355-A1
Application number	US-202218083405-A
Country	US
Kind code	A1
Filing date	Dec 16, 2022
Priority date	Dec 16, 2022
Publication date	Jun 20, 2024
Grant date	—

Abstract

The presently described inventive concepts relate to unique configurations of lithium-sulfur batteries particularly adept for mitigating or even eliminating detrimental effects associated with polysulfide shuttling. Surprisingly, implementing a polymeric non-porous, ionically conductive, electrically non-conductive protective layer on the anode-facing surface of the separator yield unexpected improvements to battery performance including but not limited to substantially improved operational lifetime. Notably, these improvements are observed and significant even relative to configurations implementing an otherwise identical protective layer on the cathode-facing surface of the separator. The resulting batteries are characterized by light weight, high ionic conductivity, robust mechanical strength, and retaining high Columbic efficiency (e.g., at least 80% of peak) for over 250 charge cycles.

First claim

What is claimed is:

1 . A lithium-sulfur battery, comprising:
an anode; a cathode; a separator positioned between the anode and the cathode; and a protective layer coating an anode-facing surface of the separator, wherein the protective layer is configured to mitigate polysulfide shuttling within the lithium-sulfur battery.

2 . The lithium-sulfur battery as recited in claim 1 , wherein the protective layer comprises a non-porous polymeric network.

3 . The lithium-sulfur battery as recited in claim 1 , wherein the protective layer is ionically conductive to lithium ions.

4 . The lithium-sulfur battery as recited in claim 1 , wherein the protective layer is electrically non-conductive.

5 . The lithium-sulfur battery as recited in claim 1 , wherein the protective layer is non-porous.

6 . The lithium-sulfur battery as recited in claim 1 , wherein the protective layer is formed to a thickness in a range from about 1 nm to about 20 microns.

7 . The lithium-sulfur battery as recited in claim 1 , wherein the protective layer comprises a polymeric component and an ion-transporting component embedded in the polymeric component.

8 . The lithium-sulfur battery as recited in claim 7 , wherein the polymeric component comprises: poly(ethylene oxide) (PEO), polypropylene, polyvinylidene fluoride (PVDF), polyvinylidene fluoride-co-hexafluoropropylene (PVDF-HFP), polyacrylonitrile (PAN), poly(methyl)methacrylate) (PMMA), or any combination thereof.

9 . The lithium-sulfur battery as recited in claim 7 , wherein the ion-transporting component comprises one or more materials configured to facilitate lithium-ion transport.

10 . The lithium-sulfur battery as recited in claim 9 , wherein the ion-transporting component is selected from the group consisting of lithium bis(trifluoromethanesulfonyl)imide (LiTFSI)m lithium perchlorate (LiClO 4− ), and lithium hexafluorophosphate (LiPF 6 ).

11 . The lithium-sulfur battery as recited in claim 7 , wherein the polymeric component and the ion-transporting component are present in a range from about a 20:1 molar ratio of the polymeric component to the ion-transporting component to about an 8:1 molar ratio of the polymeric component to the ion-transporting component.

12 . The lithium-sulfur battery as recited in claim 7 , wherein the polymeric component comprises one or more polymers characterized by a molecular weight in a range from about 100,000 g/mol to about 4,000,000 g/mol.

13 . The lithium-sulfur battery as recited in claim 1 , wherein the protective layer is formed only on the anode-facing surface of the separator.

14 . The lithium-sulfur battery as recited in claim 1 , wherein a cathode-facing surface of the separator is characterized by absence of any protective coating formed thereon which is configured to mitigate lithium polysulfide shuttling within the lithium-sulfur battery.

15 . The lithium-sulfur battery as recited in claim 1 , wherein a cathode-facing surface of the separator is characterized by absence of any protective coating formed thereon which is configured to mitigate lithium polysulfide shuttling within the lithium-sulfur battery.

16 . The lithium-sulfur battery as recited in claim 1 , wherein the lithium-sulfur battery is characterized by an operational life cycle of over at least 250 cycles.

17 . The lithium-sulfur battery as recited in claim 1 , wherein the cathode is characterized by a loading of active material of at least about 5 mg/cm 2 or more.

18 . A method, comprising
forming a protective layer on one surface of a separator layer of a lithium-sulfur battery; and positioning the separator layer between an anode layer and a cathode layer of the lithium-sulfur battery, wherein the separator layer is arranged such that the protective layer faces the anode layer of the lithium-sulfur battery.

19 . The method as recited in claim 18 , wherein the protective layer comprises a polymeric component and an ion-transporting component embedded in the polymeric component; and
wherein the polymeric component comprises: poly(ethylene oxide) (PEO), polypropylene, polyvinylidene fluoride (PVDF), polyvinylidene fluoride-co-hexafluoropropylene (PVDF-HFP), polyacrylonitrile (PAN), poly(methyl)methacrylate) (PMMA), or any combination thereof.

20 . The method as recited in claim 18 , wherein the protective layer comprises a polymeric component and an ion-transporting component embedded in the polymeric component; and
wherein the ion-transporting component is selected from the group consisting of lithium bis(trifluoromethanesulfonyl)imide (LiTFSI)m lithium perchlorate (LiClO 4− ), and lithium hexafluorophosphate (LiPF 6 ).

Assignees

• Lyten Inc

Inventors

• Bashiri Parisa
• Mikolajczak Celina
• Ganguli Babu

Classifications

• H01M50/417

  Polyolefins · CPC title

• H01M50/451

  comprising layers of only organic material and layers containing inorganic material · CPC title

• H01M50/457

  comprising three or more layers · CPC title

• H01M10/052

  Li-accumulators · CPC title

• H01M50/426

  Fluorocarbon polymers · CPC title