Systems and methods for closed-loop recycling of a liquid component of a leaching mixture when recycling lead from spent lead-acid batteries

Patent metadata

Field	Value
Publication number	US-2024194962-A1
Application number	US-202418587852-A
Country	US
Kind code	A1
Filing date	Feb 26, 2024
Priority date	Jun 20, 2014
Publication date	Jun 13, 2024
Grant date	—

Abstract

The present disclosure relates generally to systems and methods for recycling lead-acid batteries, and more specifically, relates to purifying and recycling the lead content from lead-acid batteries. A system includes a reactor that receives and mixes a lead-bearing material waste, a carboxylate source, and a recycled liquid component to form a leaching mixture yielding a lead carboxylate precipitate. The system also includes a phase separation device coupled to the reactor, wherein the phase separation device isolates the lead carboxylate precipitate from a liquid component of the leaching mixture. The system further includes a closed-loop liquid recycling system coupled to the phase separation device and to the reactor, wherein the closed-loop liquid recycling system receives the liquid component isolated by the phase separation device and recycles a substantial portion of the received liquid component back to the reactor as the recycled liquid component.

First claim

1 . A system, comprising:
a reactor that receives and mixes a metal containing composition, a carboxylate source, and a recycled liquid component to form a leaching mixture yielding a metal-salt precipitate; a phase separation device, for an isolation of the metal-salt precipitate from a liquid component of the leaching mixture, coupled to the reactor; a calciner coupled to the phase separation device and configured to receive the metal-salt precipitate isolated by the phase separation device and treat the metal-salt precipitate; and a closed-loop liquid recycling system coupled to the phase separation device, the closed-loop liquid recycling system configured to receive the liquid component from the phase separation device and to position the liquid component within the reactor as the recycled liquid component.

2 . The system of claim 1 , wherein the closed-loop liquid recycling system comprises a purification device that removes at least one impurity from the received liquid component before recycling.

3 . The system of claim 2 , wherein the purification device comprises another reactor and another phase separation device.

4 . The system of claim 1 , wherein the carboxylate source comprises a citric acid, a salt of citric acid, or a combination thereof.

5 . The system of claim 1 , wherein the recycled liquid component is a solution at least 10% saturated in dissolved metal-salt precipitate.

6 . The system of claim 1 , wherein the closed-loop liquid recycling system receives a wash water along with the liquid component from the phase separation device and recycles the wash water along with the liquid component.

7 . The system of claim 1 , comprising a battery processing device that is configured to receive at least one battery and grind the at least one battery to provide for the metal containing composition.

8 . The system of claim 1 , wherein the system includes process controls selected from the group consisting of calcination temperature, time, metal-salt precipitate particle size, amount of residual water in the metal-salt precipitate, rate of heating of the metal-salt precipitate to the calcination temperature, and oxygen temperature in a gas stream.

9 . A method of recycling a battery, comprising:
forming a metal containing mixture from a spent battery, wherein the metal containing mixture includes a liquid component; isolating a metal from the metal containing mixture, such that the metal is removed from the liquid component; recycling the liquid component for use in additional metal containing mixtures, with the liquid component having a high concentration of dissolved metal-salt; treating the isolated metal to form a battery material; and constructing a new battery using the battery material.

10 . The method of claim 9 , further comprising removing a precipitate before recycling the liquid component.

11 . The method of claim 9 , wherein isolating the metal from the liquid component includes using a belt dryer, a filter press, a clarifier, or a cyclone separator.

12 . The method of claim 9 , wherein the metal includes a metal-salt precipitate.

13 . The method of claim 12 , wherein treating comprises oxidizing the metal-salt precipitate into a first oxide, and wherein the first oxide is formed into the battery material.

14 . The method of claim 12 , wherein treating comprises reacting the metal-salt precipitate with a hydroxide to yield a second oxide, and wherein the second oxide is formed into the battery material.

15 . The method of claim 9 , wherein the metal containing mixture further includes a carboxylate source, wherein the carboxylate source comprises citric acid, a salt of citric acid, or a combination thereof.

16 . The method of claim 9 , further comprising using a nanofilter to remove one or more sulfates from the liquid component.

17 . The method of claim 9 , wherein forming the metal containing mixture includes crushing, pulverizing, griding or otherwise physically digesting an entirety of the spent battery.

18 . The method of claim 9 , further comprising adding water or peroxide to the metal containing mixture to encourage a dissolution of the metal.

19 . The method of claim 9 , wherein the metal comprises a first metal and a second metal.

20 . The method of claim 19 , wherein the dissolved metal-salt comprises the first metal and the second metal.

Assignees

• Clarios Germany Gmbh & Co Kg
• Cps Tech Holdings Llc

Inventors

• Meissner Jr Eberhard
• Bauer Juergen
• Spence Matthew A

Classifications

• C22B7/009

  General processes for recovering metals or metallic compounds from spent catalysts (for recovering specific metals C22B11/00 - C22B61/00) · CPC title

• B01J19/2465

  externally, i.e. the mixture leaving the vessel and subsequently re-entering it · CPC title

• B01J19/06

  Solidifying liquids (making microcapsules B01J13/02) · CPC title

• C22B3/04

  by leaching (C22B3/18 takes precedence) · CPC title

• C22B3/02

  Apparatus therefor · CPC title