Solvent based recycling process of polyolefins

Patent metadata

Field	Value
Publication number	US-2024191052-A1
Application number	US-202218555295-A
Country	US
Kind code	A1
Filing date	Apr 13, 2022
Priority date	Apr 15, 2021
Publication date	Jun 13, 2024
Grant date	—

Abstract

A solvent based recycling process for recycling waste polymer material, the waste polymer material comprising at least one polyolefin, the process comprising the steps of obtaining the waste polymer material comprising the at least one polyolefin; contacting the waste polymer material with at least one dissolving solvent yielding a slurry stream of polymer solution and undissolved solids; screening the slurry stream yielding the undissolved solids and a stream of the polymer solution; vapor-liquid separating the stream of the polymer solution into a polymer-lean vapor stream and a polymer-rich condensed stream; recovering the at least one polyolefin from the polymer-rich condensed stream; wherein the at least one dissolving solvent has a boiling point temperature at 1 bar of equal to or more than 70° C.

First claim

1 . A solvent-based recycling process for recycling waste polymer material ( 1 ), the waste polymer material ( 1 ) comprising at least one polyolefin ( 2 ), the process comprising the steps of
a) obtaining the waste polymer material ( 1 ) comprising the at least one polyolefin ( 2 ); b) contacting the waste polymer material ( 1 ) with at least one dissolving solvent ( 3 ) yielding a slurry stream ( 4 ) of polymer solution ( 5 ) and undissolved solids ( 6 ); c) screening the slurry stream ( 4 ) yielding the undissolved solids ( 6 ) and a stream of the polymer solution ( 5 ); d) vapor-liquid separating the stream of polymer solution ( 5 ) into a polymer-lean vapor stream ( 9 ) and a polymer-rich condensed stream ( 10 ); e) recovering the at least one polyolefin ( 2 ) from the polymer-rich condensed stream ( 10 ); wherein the at least one dissolving solvent ( 3 ) has a boiling point temperature at 1 bar of equal to or more than 70° C.

2 . The solvent based recycling process according to claim 1 , wherein the process further comprises subsequently to step c) and preceding step d) the step of:
c″) liquid-liquid separating the stream of the polymer solution ( 5 ) into a polymer-lean stream ( 7 ) and a polymer-rich stream ( 8 ), wherein the polymer-rich stream ( 8 ) is fed to step d).

3 . The solvent based recycling process according to claim 2 , wherein step c) comprises the step of solid-liquid separating the undissolved solids ( 6 ) from the polymer solution ( 5 ).

4 . The solvent based recycling process according to claim 1 , the process further comprising a homogenization step c′) carried out subsequently to step c) a preceding step c″) receiving the polymer solution ( 5 ) and yielding a homogenized polymer solution ( 5 ′), wherein the homogenized polymer solution ( 5 ′) is fed to step c″).

5 . The solvent based recycling process according to claim 1 , wherein the process further comprises subsequently to step a) and preceding step b) the step of:
a′) extracting the waste polymer material ( 1 ) with at least one extracting solvent ( 3 e ) or melting the waste polymer material ( 1 ).

6 . The solvent based recycling process according to claim 5 , wherein the step a′) is melting the waste polymer material ( 1 ) yielding a molten waste material ( 1 a ).

7 . The solvent based recycling process according to claim 6 , wherein in step a′) the molten waste material ( 1 a ) is mixed with the dissolving solvent ( 3 ) in a mixing device.

8 . The solvent based recycling process according to claim 1 , wherein step c″) is carried out at least twice so that the polymer-lean stream ( 7 1 ) of a first step c″ 1 ) is fed to a second step c″ 2 ).

9 . The solvent based recycling process according to claim 1 , wherein step d) is carried out at least twice in that the polymer-rich condensed stream ( 10 ) of a first step d′) is fed to a second step d″).

Assignees

• Borealis Ag

Inventors

• Al-Haj Ali Mohammad
• Ajellal Noureddine
• Sattar Mubashar
• Elovainio Erno
• Sleijster Henry

Classifications

• C08J2323/02

  not modified by chemical after treatment · CPC title

• C08J2300/30

  Polymeric waste or recycled polymer · CPC title

• B01D11/028

  Flow sheets · CPC title

• B01D5/0057

  in combination with other processes · CPC title

• C08J11/08 Primary

  using selective solvents for polymer components · CPC title