Binder composition for secondary battery

Patent metadata

Field	Value
Publication number	US-2024186517-A1
Application number	US-202017799286-A
Country	US
Kind code	A1
Filing date	Sep 25, 2020
Priority date	Jun 17, 2020
Publication date	Jun 6, 2024
Grant date	—

Abstract

An aqueous binder composition for a positive electrode of a secondary battery electrode, comprising a copolymer and a dispersion medium, wherein the copolymer comprises a structural unit (a) derived from a carboxylic acid group-containing monomer, a structural unit (b) derived from an amide group-containing monomer and a structural unit (c) derived from a nitrile group-containing monomer, with an improved binding capability. In addition, battery cells comprising the cathode prepared using the binder composition disclosed herein exhibits exceptional electrochemical performance.

First claim

1 . A binder composition for a secondary battery electrode comprising a copolymer and a dispersion medium, wherein the copolymer comprises a structural unit (a) derived from a carboxylic acid group-containing monomer, a structural unit (b) derived from an amide group-containing monomer and a structural unit (c) derived from a nitrile group-containing monomer.

2 . The binder composition according to claim 1 , wherein the carboxylic acid group-containing monomer is selected from the group consisting of acrylic acid, methacrylic acid, crotonic acid, 2-butyl crotonic acid, cinnamic acid, maleic acid, maleic anhydride, fumaric acid, itaconic acid, itaconic anhydride, tetraconic acid, 2-ethylacrylic acid, isocrotonic acid, cis-2-pentenoic acid, trans-2-pentenoic acid, angelic acid, tiglic acid, 3,3-dimethyl acrylic acid, 3-propyl acrylic acid, trans-2-methyl-3-ethyl acrylic acid, cis-2-methyl-3-ethyl acrylic acid, 3-isopropyl acrylic acid, trans-3-methyl-3-ethyl acrylic acid, cis-3-methyl-3-ethyl acrylic acid, 2-isopropyl acrylic acid, trimethyl acrylic acid, 2-methyl-3,3-diethyl acrylic acid, 3-butyl acrylic acid, 2-butyl acrylic acid, 2-pentyl acrylic acid, 2-methyl-2-hexenoic acid, trans-3-methyl-2-hexenoic acid, 3-methyl-3-propyl acrylic acid, 2-ethyl-3-propyl acrylic acid, 2,3-diethyl acrylic acid, 3,3-diethyl acrylic acid, 3-methyl-3-hexyl acrylic acid, 3-methyl-3-tert-butyl acrylic acid, 2-methyl-3-pentyl acrylic acid, 3-methyl-3-pentyl acrylic acid, 4-methyl-2-hexenoic acid, 4-ethyl-2-hexenoic acid, 3-methyl-2-ethyl-2-hexenoic acid, 3-tert-butyl acrylic acid, 2,3-dimethyl-3-ethyl acrylic acid, 3,3-dimethyl-2-ethyl acrylic acid, 3-methyl-3-isopropyl acrylic acid, 2-methyl-3-isopropyl acrylic acid, trans-2-octenoic acid, cis-2-octenoic acid, trans-2-decenoic acid, α-acetoxyacrylic acid, β-trans-aryloxyacrylic acid, α-chloro-β-E-methoxyacrylic acid, methyl maleic acid, dimethyl maleic acid, phenyl maleic acid, bromo maleic acid, chloromaleic acid, dichloromaleic acid, fluoromaleic acid, difluoro maleic acid, nonyl hydrogen maleate, decyl hydrogen maleate, dodecyl hydrogen maleate, octadecyl hydrogen maleate, fluoroalkyl hydrogen maleate, maleic anhydride, methyl maleic anhydride, dimethyl maleic anhydride, acrylic anhydride, methacrylic anhydride, methacrolein, methacryloyl chloride, methacryloyl fluoride, methacryloyl bromide and combinations thereof.

3 . The binder composition according to claim 1 , wherein the proportion of structural unit (a) derived from a carboxylic acid group-containing monomer in the copolymer is from about 7% to about 25% by mole, based on the total number of moles of monomeric units in the copolymer in the binder composition.

4 . The binder composition according to claim 1 , wherein the amide group-containing monomer is selected from the group consisting of methacrylamide, N-methyl methacrylamide, N-ethyl methacrylamide, N-n-propyl methacrylamide, N-isopropyl methacrylamide, N-n-butyl methacrylamide, N-isobutyl methacrylamide, N,N-dimethyl acrylamide, N,N-dimethyl methacrylamide, N,N-diethyl acrylamide, N,N-diethyl methacrylamide, N-methylol methacrylamide, N-(methoxymethyl)methacrylamide, N-(ethoxymethyl)methacrylamide, N-(propoxymethyl)methacrylamide, N-(butoxymethyl)methacrylamide, N,N-dimethyl methacrylamide, N,N-dimethylaminopropyl methacrylamide, N,N-dimethylaminoethyl methacrylamide, N,N-dimethylol methacrylamide, diacetone methacrylamide, methacryloyl morpholine and combinations thereof.

5 . The binder composition according to claim 1 , wherein the proportion of structural unit (b) derived from an amide group-containing monomer in the copolymer is from about 4% to about 17% by mole, based on the total number of moles of monomeric units in the copolymer in the binder composition.

6 . The binder composition according to claim 1 , wherein the nitrile group-containing monomer is selected from the group consisting of acrylonitrile, α-halogenoacrylonitrile, α-alkylacrylonitrile, α-chloroacrylonitrile, α-bromoacrylonitrile, α-fluoroacrylonitrile, methacrylonitrile, α-ethylacrylonitrile, α-isopropylacrylonitrile, α-n-hexylacrylonitrile, α-methoxyacrylonitrile, 3-methoxyacrylonitrile, 3-ethoxyacrylonitrile, α-acetoxyacrylonitrile, α-phenylacrylonitrile, α-tolylacrylonitrile, α-(methoxyphenyl)acrylonitrile, α-(chlorophenyl)acrylonitrile, α-(cyanophenyl)acrylonitrile, vinylidene cyanide and combinations thereof.

7 . The binder composition according to claim 1 , wherein the proportion of structural unit (c) derived from a nitrile group-containing monomer in the copolymer is from about 65% to about 80% by mole, based on the total number of moles of monomeric units in the copolymer in the binder composition.

8 . The binder composition according to claim 1 , wherein the dispersion medium is water.

9 . The binder composition according to claim 8 , wherein the dispersion medium further comprise a hydrophilic solvent selected from the group consisting of ethanol, isopropanol, n-propanol, tert-butanol, n-butanol, dimethylacetamide (DMAc), dimethylformamide (DMF), N-methylpyrrolidone (NMP), methyl ethyl ketone (MEK), ethyl acetate (EA), butyl acetate (BA) and combinations thereof.

10 . The binder composition according to claim 1 , wherein the proportion of the sum of structural unit (a) derived from a carboxylic acid group-containing monomer and structural unit (b) derived from an amide group-containing monomer in the copolymer is from about 18% to about 35% by mole, based on the total number of moles of monomeric units in the copolymer in the binder composition.

11 . The binder composition according to claim 1 , wherein the molar ratio of the structural unit (c) derived from a nitrile group-containing monomer to the sum of the structural unit (a) derived from a carboxylic acid group-containing monomer and structural unit (b) derived from an amide group-containing monomer in the copolymer is from about 1.5 to about 4.

12 . The binder composition according to claim 1 , wherein the molar ratio of the sum of the structural unit (c) derived from a nitrile group-containing monomer and structural unit (a) derived from a carboxylic acid group-containing monomer to the structural unit (b) derived from an amide group-containing monomer in the copolymer is from about 5 to about 15.

13 . The binder composition according to claim 1 , wherein the pH of the binder composition is from about 7 to about 9.

14 . The binder composition according to claim 1 , wherein the viscosity of the binder composition is from about 10,000 mPa·s to about 50,000 mPa·s.

15 . The binder composition according to claim 1 , wherein the electrolyte swelling of the binder composition is from about 2% to about 4%.

16 . The binder composition according to claim 1 , wherein the adhesive strength between the binder composition and a current collector is from about 2 N/cm to about 4 N/cm.

17 . The binder composition according to claim 1 , wherein the solid content of the binder composition is from about 12% to about 18% by weight, based on the total weight of the binder composition.

18 . An electrode for a secondary battery, comprising an electrode active material, a conductive agent and the binder composition according to claim 1 .

19 . The electrode according to claim 18 , wherein the peeling strength between a current collector and an electrode layer is in the range from about 1.0 N/cm to about 8.0 N/cm.

Assignees

• Guangdong Haozhi Tech Co Limited Li Tian
• Grst Int Ltd

Inventors

• Ho Kam Piu
• Jiang Yingkai
• Qiu Hongke

Classifications

• C08K2003/2203

  of lithium · CPC title

• C08F220/48

  with nitrogen-containing monomers · CPC title

• C09J11/04

  inorganic · CPC title

• C09J133/26

  Homopolymers or copolymers of acrylamide or methacrylamide · CPC title

• H01M10/0525

  Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries · CPC title