Devices comprising carbon-based material and fabrication thereof

Patent metadata

Field	Value
Publication number	US-2024162413-A1
Application number	US-202318455693-A
Country	US
Kind code	A1
Filing date	Aug 25, 2023
Priority date	Aug 31, 2016
Publication date	May 16, 2024
Grant date	—

Abstract

Energy storage devices are disclosed. In some embodiments, the energy storage devices comprise a positive electrode comprising a carbon-based material comprising porous carbon sheet(s). Fabrication processes for manufacturing the energy storage devices are disclosed.

First claim

What is claimed is:

1 . An energy storage device comprising:
a. a negative electrode comprising:
i. a plurality of porous graphene sheets comprising graphene oxide, reduced graphene oxide, graphite oxide, or a combination thereof, wherein a portion of edges of a portion of the plurality of porous graphene sheets are oxidized and comprise an oxygen content of about 0.5% to about 10%,
ii. a first binder, and
iii. a conductive additive;
b. a positive electrode comprising:
i. an active material, and
ii. a second binder; and
c. a separator between the negative electrode and the positive electrode.

2 . The energy storage device of claim 1 , wherein at least one of the first binder and the second binder comprises polyvinyl fluoride, polyvinylidene fluoride, polytetrafluoroethylene, polychlorotrifluoroethylene, perfluoroalkoxy polymer, fluorinated ethylene-propylene, polyethylenetetrafluoroethylene, polyethylenechlorotrifluoroethylene, perfluorinated plastomer, a fluorocarbon, chlorotrifluoroethylenevinylidene fluoride, a fluoroelastomer, tetrafluoroethylene-propylene, perfluoropolyether, perfluorosulfonic acid, perfluoropolyoxetane, P(VDF-trifluoroethylene), P(VDF-tetrafluoroethylene), or any combination thereof.

3 . The energy storage device of claim 1 , wherein the conductive additive comprises carbon black, acetylene black, furnace black, vapor-grown carbon fibers, carbon nanotubes, or any combination thereof.

4 . The device of claim 1 , wherein the active material comprises, graphene, lithium iron phosphate, lithium nickel cobalt aluminum oxide, lithium nickel manganese cobalt oxide, lithium cobalt oxide, lithium manganese oxide, lithium titanate, lithium sulfur, or any combination thereof.

5 . The device of claim 1 , having a storage capacity of at least 800 mAh.

6 . The device of claim 1 , having a cycle life of at least about 500 cycles, about 600 cycles, about 700 cycles, about 800 cycles, about 900 cycles, or at least about 1000 cycles.

7 . The device of claim 1 , having an equivalent series resistance of about 10 milliohms to about 100 milliohms, about 20 milliohms to about 80 milliohms, about 20 milliohms to about 100 milliohms, or about 60 milliohms to about 100 milliohms.

8 . The device of claim 1 , wherein the separator has a permeability greater than or equal to about 150 sec/100 mL.

9 . The device of claim 1 , wherein carboxylic acid functional groups are bonded only to one or both of a top sheet or a bottom sheet of the porous graphene sheets.

10 . The device of claim 1 , wherein the porous graphene sheets comprise about 2 to about 10 porous graphene sheets.

11 . The device of claim 1 , wherein each of the porous graphene sheets comprises a plurality of pores, wherein a portion of the plurality of pores have a pore size of about 1 nanometer (nm) to about 10 nm.

12 . A method of providing an energy storage device, the method comprising:
a. mixing an active material into a binder and a solvent to form a slurry, wherein the active material comprises a plurality of porous graphene sheets comprising graphene oxide, reduced graphene oxide, graphite oxide, or a combination thereof, wherein a portion of edges of a portion of the plurality of porous graphene sheets are oxidized and comprise an oxygen content of about 0.5% to about 10%; b. roll coating the slurry onto a foil; c. drying the slurry on the foil; d. roll pressing the slurry on the foil; e. slitting the slurry on the foil to form an electrode.

13 . The method of claim 12 , wherein the oxygen content is less than about 5%.

14 . The method of claim 12 , wherein the oxygen content is less than about 2%.

15 . The method of claim 12 , wherein the binder comprises polyvinyl fluoride, polyvinylidene fluoride, polytetrafluoroethylene, polychlorotrifluoroethylene, perfluoroalkoxy polymer, fluorinated ethylene-propylene, polyethylenetetrafluoroethylene, polyethylenechlorotrifluoroethylene, perfluorinated plastomer, a fluorocarbon, chlorotrifluoroethylenevinylidene fluoride, a fluoroelastomer, tetrafluoroethylene-propylene, perfluoropolyether, perfluorosulfonic acid, perfluoropolyoxetane, P(VDF-trifluoroethylene), P(VDF-tetrafluoroethylene), or any combination thereof.

16 . The method of claim 12 , wherein the active material further comprises a lithiated metal compound.

17 . The method of claim 12 , wherein the plurality of porous graphene sheets is a single layer of graphene.

18 . The method of claim 12 , wherein a portion of the plurality of porous graphene sheets has an average pore size of about 1 nm to about 10 nm.

19 . The method of claim 12 , further comprising applying a metal tab to the electrode.

20 . The method of claim 12 , further comprising forming the porous graphene sheets using a non-Hummer's method, wherein the non-Hummer's method comprises:
chemically oxidizing graphite to form graphene oxide; exfoliating the graphene oxide; purifying the graphene oxide; and chemically reducing the graphene oxide to form the porous graphene sheets.

Assignees

• Univ California

Inventors

• El-Kady Maher F
• Kaner Richard B
• Kowal Matthew

Classifications

• H01M4/133 Primary

  Electrodes based on carbonaceous material, e.g. graphite-intercalation compounds or CFx · CPC title

• H01G11/36 Primary

  Nanostructures, e.g. nanofibres, nanotubes or fullerenes · CPC title

• H01G11/38

  Carbon pastes or blends; Binders or additives therein · CPC title

• H01G11/86

  specially adapted for electrodes (carbonisation or activation of carbon for the manufacture of electrodes H01G11/34) · CPC title

• H01M4/0409

  by a doctor blade method, slip-casting or roller coating · CPC title