Light-emitting device and electronic apparatus including the same

Patent metadata

Field	Value
Publication number	US-2024147752-A1
Application number	US-202318476056-A
Country	US
Kind code	A1
Filing date	Sep 27, 2023
Priority date	Oct 18, 2022
Publication date	May 2, 2024
Grant date	—

Abstract

Provided is a light-emitting device including a first electrode, a second electrode facing the first electrode, an emission layer between the first electrode and the second electrode, and an electron transport region between the emission layer and the second electrode, wherein the electron transport region includes an electron injection layer including a first material and a second material, the first material and the second material each independently include an alkali metal, an alkaline earth metal, a transition metal, a post-transition metal, a lanthanide metal, or a combination thereof, the second material does not include Mg, the first material and the second material are different from each other, and a surface energy of the second material is greater than a surface energy of the first material.

First claim

What is claimed is:

1 . A light-emitting device comprising:
a first electrode; a second electrode facing the first electrode; an emission layer between the first electrode and the second electrode; and an electron transport region between the emission layer and the second electrode, wherein the electron transport region comprises an electron injection layer comprising a first material and a second material, the first material and the second material each independently comprise an alkali metal, an alkaline earth metal, a transition metal, a post-transition metal, a lanthanide metal, or a combination thereof, the second material does not comprise Mg, the first material and the second material are different from each other, and a surface energy of the second material is greater than a surface energy of the first material.

2 . The light-emitting device of claim 1 , wherein the electron injection layer is a single layer.

3 . The light-emitting device of claim 1 , wherein the first material is i) an alkali metal, an alkaline earth metal, and/or a lanthanide metal, ii) a halide of an alkali metal, a halide of an alkaline earth metal, and/or a halide of a lanthanide metal, or iii) a combination thereof.

4 . The light-emitting device of claim 1 , wherein the first material is LiF or Yb.

5 . The light-emitting device of claim 1 , wherein the second material comprises a transition metal or a post-transition metal.

6 . The light-emitting device of claim 1 , wherein the second material is Ag, Au, Al, or a combination thereof.

7 . The light-emitting device of claim 1 , wherein the surface energy of the second material is about 0.8 J/m 2 or more.

8 . The light-emitting device of claim 1 , wherein a volume of the first material included in the electron injection layer is greater than a volume of the second material included in the electron injection layer.

9 . The light-emitting device of claim 1 , wherein a volume ratio of the first material to the second material in the electron injection layer is about 0.2:1 to about 4:1.

10 . The light-emitting device of claim 1 , wherein:
the electron injection layer further comprises a third material comprising an alkali metal, an alkaline earth metal, a transition metal, a post-transition metal, a lanthanide metal, or a combination thereof, and the third material is different from the first material and the second material.

11 . The light-emitting device of claim 10 , wherein the third material comprises an alkaline earth metal.

12 . The light-emitting device of claim 10 , wherein the third material is Mg or Ca.

13 . The light-emitting device of claim 10 , wherein a radius of an atom of a metal included in the third material is less than a radius of an atom of a metal included in the first material.

14 . The light-emitting device of claim 10 , wherein a volume of the second material included in the electron injection layer is substantially equal to a volume of the third material included in the electron injection layer.

15 . The light-emitting device of claim 1 , wherein a thickness of the electron injection layer is about 5 Å to about 20 Å.

16 . The light-emitting device of claim 1 , wherein the electron injection layer is formed by co-depositing the first material and the second material.

17 . The light-emitting device of claim 1 , wherein the electron injection layer is in direct contact with the second electrode.

18 . The light-emitting device of claim 1 , further comprising:
a hole transport region between the first electrode and the emission layer, wherein: the hole transport region comprises a hole injection layer, a hole transport layer, an emission auxiliary layer, an electron blocking layer, or a combination thereof.

19 . An electronic apparatus comprising the light-emitting device of claim 1 .

20 . The electronic apparatus of claim 19 , further comprising:
a thin-film transistor electrically connected to the first electrode; and a color filter, a color conversion layer, a touch screen layer, a polarizing layer, or a combination thereof.

Assignees

• Samsung Display Co Ltd

Inventors

• Sung Hyangki
• Kim Dalho
• Han Jongseok
• Park Eunji
• Jeong Heeseong

Classifications

• H10K99/00

  Subject matter not provided for in other groups of this subclass · CPC title

• H10K59/1275

  Electrical connections of the two substrates · CPC title

• H10K59/80521

  characterised by their shape · CPC title

• H10K50/171 Primary

  Electron injection layers · CPC title

• H10K50/86

  Arrangements for improving contrast, e.g. preventing reflection of ambient light · CPC title