Lithium nickel-based composite oxide as a positive electrode active material for rechargeable lithium-ion batteries

Patent metadata

Field	Value
Publication number	US-2024132373-A1
Application number	US-202218277393-A
Country	US
Kind code	A1
Filing date	Feb 24, 2022
Priority date	Feb 25, 2021
Publication date	Apr 25, 2024
Grant date	—

Abstract

Positive electrode active material for solid-state batteries, comprising Li, M′, and oxygen, wherein M′ comprises:
Ni in a content x between 50.0 mol % and 75.0 mol %, Co in a content y between 0.0 mol % and 40.0 mol %, Mn in a content z between 0.0 mol % and 40.0 mol %, dopants in a content a between 0.0 mol % and 2.0 mol %, Zr in a content b between 0.1 mol % and 5.0 mol %, wherein x+y+z+a+b is 100.0 mol %,

wherein

Zr
A

=

b

(

x
+
y
+
z
+
b

)

,

wherein the positive electrode active material has a Zr content Zr B is expressed as molar fraction compared to the sum of molar fractions of Co, Mn, Ni, and Zr all as measured by XPS analysis,

wherein Zr B /Zr A >50.0,

the positive electrode active material comprising secondary particles having a plurality of primary particles

said primary particles having an average diameter between 170 nm and 340 nm.

First claim

1 - 17 . (canceled)

18 . A positive electrode active material for solid-state batteries, wherein the positive electrode active material comprises Li, M′, and oxygen, wherein M′ comprises:
Ni in a content x between 50.0 mol % and 75.0 mol %, relative to M′;
Co in a content y between 0.0 mol % and 40.0 mol %, relative to M′;
Mn in a content z between 0.0 mol % and 40.0 mol %, relative to M′,
D in a content a between 0.0 mol % and 2.0 mol %, relative to M′, wherein D comprises at least one element of the group consisting of: Al, B, Ba, Ca, Cr, Fe, Mg, Mo, Nb, S, Si, Sr, Ti, Y, V, W, and Zn, and,
Zr in a content b between 0.1 mol % and 5.0 mol %, relative to M′,
wherein x, y, z, a, and b are measured by ICP,
wherein x+y+z+a+b is 100.0 mol %,

wherein the positive electrode active material has a Zr content ZrA defined as

b

(

x
+
y
+
z
+
b

)

,

wherein the positive electrode active material has a Zr content Zr B , wherein Zr B is determined by XPS analysis, wherein Zr B is expressed as molar fraction compared to the sum of molar fractions of Co, Mn, Ni, and Zr, as measured by XPS analysis,
wherein the ratio Zr B /Zr A >50.0,
wherein the positive electrode active material comprises secondary particles having a plurality of primary particles,
wherein said primary particles have an average diameter of between 170 nm to 340 nm as determined by measuring primary particle size in an image taken by SEM.

19 . Positive electrode active material according to claim 18 , wherein the ratio Zr B /Zr A is at least 80.

20 . Positive electrode active material according to claim 18 , wherein the ratio Zr B /Zr A is at most 500.

21 . Positive electrode active material according to claim 18 , wherein x≥55.0 mol % .

22 . Positive electrode active material according to claim 18 , wherein x≤72.0 mol %.

23 . Positive electrode active material according to claim 18 , wherein 0 mol %≤y≤20 mol %.

24 . Positive electrode active material according to claim 18 , wherein b is at least 0.10 mol % and at most 1.00 mol %, relative to M′.

25 . Positive electrode active material according to claim 18 , wherein the secondary particle median size D50 is at least 2.0 μm and at most 15.0 μm, as determined by laser diffraction particle size analysis.

26 . Positive electrode active material according to claim 18 , wherein the carbon content is at least 600 ppm and at most 3000 ppm, as determined by carbon analyzer.

27 . Positive electrode active material according to claim 18 , wherein the Zr thickness is at least 10 nm, as determined by TEM-EDS measurement.

28 . A method for the manufacturing of a positive electrode active material for solid-state batteries, wherein the positive electrode active material is the positive electrode active material according to claim 18 , comprising the consecutive steps of
preparing a lithium transition metal-based oxide compound, mixing said lithium transition metal-based oxide compound with a source of Zr, thereby obtaining a mixture, and heating the mixture in an oxidizing atmosphere in a furnace at a temperature between 350° C. and less than 500° C., for a time between 1 hour and 20 hours so as to obtain the positive electrode active material.

29 . The method according to claim 28 , wherein the method comprises a further step, before heating said mixture, of drying said mixture.

30 . The method according to claim 28 , wherein the method comprises a further step, before heating said mixture, of drying said mixture by means of vacuum heating.

31 . A solid-state battery comprising the positive electrode active material according to claim 18 .

32 . Solid-state battery according to claim 31 , wherein said solid-state battery comprises a sulfide based solid electrolyte comprising Li, P, and S.

33 . An electric vehicle or a hybrid electric vehicle comprising the battery according to claim 32 .

Assignees

• Umicore Nv

Inventors

• Paulsen Jens Martin
• Kumakura Shinichi
• Yang Taehyeon
• Yang Hyejeong
• Kang Jihoon
• Oh Jindoo
• Hyoung Jooeun

Classifications

• C01P2006/80

  Compositional purity · CPC title

• C01P2006/40

  Electric properties · CPC title

• C01G53/50

  of the type (MnO2)n-, e.g. Li(NixMn1-x)O2 or Li(MyNixMn1-x-y)O2 · CPC title

• C01G53/44 Primary

  containing manganese · CPC title

• H01M10/0562

  Solid materials · CPC title