Anode active material comprising transition metal oxide, anode using same, and preparation method for anode active material

Patent metadata

Field	Value
Publication number	US-2024124320-A1
Application number	US-202318524284-A
Country	US
Kind code	A1
Filing date	Nov 30, 2023
Priority date	Jun 11, 2021
Publication date	Apr 18, 2024
Grant date	—

Abstract

An anode active material comprising a transition metal oxide is provided. A method for preparing the anode active material may comprise the steps of preparing a first transition metal oxide source and a second transition metal oxide source; providing the first transition metal oxide source and the second transition metal oxide source for a secondary alcohol to prepare a base source; providing a hydrolysis catalyst for the base source and inducing a sol-gel reaction to prepare a transition metal oxide precursor; and subjecting the transition metal oxide precursor to heat treatment in a nitrogen environment to prepare an anode active material containing a transition metal oxide.

First claim

1 . A method for preparing an anode active material, the method comprising:
preparing a first transition metal oxide source and a second transition metal oxide source; providing the first transition metal oxide source and the second transition metal oxide source for a secondary alcohol to prepare a base source; providing a hydrolysis catalyst for the base source and inducing a sol-gel reaction to prepare a transition metal oxide precursor; and subjecting the transition metal oxide precursor to heat treatment in a nitrogen environment to prepare an anode-active material containing a transition metal oxide.

2 . The method of claim 1 , wherein the transition metal oxide precursor is subjected to heat treatment at a temperature higher than 550° C.

3 . The method of claim 1 , wherein surface roughness, crystallinity, carbon atom content, and pore size of particles of the anode active material being generated are controlled by a temperature at which the transition metal oxide precursor is subjected to heat treatment.

4 . The method of claim 1 , wherein the hydrolysis catalyst is acetone, in which distilled water is further provided to the acetone and thus a sol-gel reaction of the base source is induced by the distilled water.

5 . The method of claim 1 , wherein the secondary alcohol is any one of ethylene glycol, diethylene glycol, or triethylene glycol, in which a size of particles of the anode active material is controlled to a nano-size by the secondary alcohol and a carbon atom is provided on a surface and an inside of the particles of the anode active material.

6 . The method of claim 1 , wherein:
the first transition metal oxide source is titanium butoxide, and the second transition metal oxide source is niobium ethoxide.

7 . A lithium secondary battery comprising:
an anode electrode including the anode active material according to claim 6 ; a cathode electrode disposed on the anode electrode and including lithium; and an electrolyte between the anode electrode and the cathode electrode, wherein a battery has a negative fading property in which a capacity of the battery increases as a number of charge/discharge cycles increases during charging/discharging.

8 . A method for preparing an anode electrode, the method comprising:
preparing an anode active material according to the method for preparing the anode active material according to claim 1 ; stirring the anode active material and a polymer binder to prepare a slurry; and coating the slurry on a current collector to prepare an anode electrode.

9 . An anode active material comprising:
a nano-sized particle in which two transition metal atoms and an oxygen atom have tetragonal and rutile crystal structures, in which a carbon atom is provided on a surface and an inside of the particle and a pore is provided in the particle.

10 . The anode active material of claim 9 , wherein:
the transition metal atoms are Ti and Nb, and a chemical composition of the particle is TiNbO 4 .

11 . The anode active material of claim 10 , wherein a size of the particle is 200 nm to 300 nm.

12 . A method for preparing an anode active material, wherein:
a surface roughness of particles of an anode active material being generated increases as a temperature for heat treatment of a transition metal oxide precursor increases; a grain size of the particles of the anode active material being generated increases and thus crystallinity of the particles of the anode active material increases, as the temperature for heat treatment of the transition metal oxide precursor increases; a carbon atom content of the particles of the anode active material being generated decreases as the temperature for heat treatment of the transition metal oxide precursor increases; and a pore size of the particles of the anode active material being generated increases as the temperature for heat treatment of the transition metal oxide precursor increases.

13 . The method of claim 12 , wherein an oxygen vacancy decreases due to a decrease in a carbon atom content of the particles of the anode active material being generated as the temperature for heat treatment of the transition metal oxide precursor increases.

Assignees

• Iucf Hyu Erica Campus

Inventors

• Bang Jin Ho
• Bak Sang Eun
• Abbas Muhammad Awais

Classifications

• C01G33/00 Primary

  Compounds of niobium · CPC title

• B01J31/0209

  Esters of carboxylic or carbonic acids · CPC title

• C01P2002/30

  Three-dimensional structures · CPC title

• C01P2004/62

  Submicrometer sized, i.e. from 0.1-1 micrometer · CPC title

• C01G33/006 Primary

  Compounds containing niobium, with or without oxygen or hydrogen, and containing two or more other elements · CPC title