Compound

Patent metadata

Field	Value
Publication number	US-2024124308-A1
Application number	US-202318485372-A
Country	US
Kind code	A1
Filing date	Oct 12, 2023
Priority date	Oct 18, 2022
Publication date	Apr 18, 2024
Grant date	—

Abstract

A compound represented by one of the formulae:BaaMobOc  (1),MOdPeOf  (2) orBagMohPiOj  (3)wherein for formula (1) the ratio of a:b is from 1:100 to 100:1,wherein for formula (2) the ratio of d:e is from 1:100 to less than 1:1 or from greater than 1:1 to 100:1,wherein for formula (3) the ratio of g:h is from 1:100 to less than 1.5:1,wherein for formula (3) the ratio of g:i is from 1:100 to 100:1,wherein for formula (3) the ratio of h:i is from 1:100 to less than 1:2, or from greater than 1:2 to less than 2:1, or from greater than 2:1 to 100:1, andwherein the molybdenum present within the compound is in the 5+ oxidation state.

First claim

1 . A compound represented by one of the formulae:
Ba a Mo b O c   (1),
MO d P e O f   (2) or
Ba g Mo h P i O j   (3)
wherein for formula (1) the ratio of a:b is from 1:100 to 100:1, wherein for formula (2) the ratio of d:e is from 1:100 to less than 1:1 or from greater than 1:1 to 100:1, wherein for formula (3) the ratio of g:h is from 1:100 to less than 1.5:1, wherein for formula (3) the ratio of g:i is from 1:100 to 100:1, wherein for formula (3) the ratio of h:i is from 1:100 to less than 1:2, or from greater than 1:2 to less than 2:1, or from greater than 2:1 to 100:1, and wherein the molybdenum present within the compound is in the 5+ oxidation state.

2 . The compound according to claim 1 , wherein for formula (1) the ratio of a:b is from 1:50 to 50:1, preferably from 1:50 to 1:1.5 or from 1.5:1 to 50:1, more preferably from 1:40 to 1:1.8 or from 1.8:1 to 40:1, even more preferably from 1:30 to 1:2 or from 2:1 to 30:1.

3 . The compound according to claim 1 , wherein for formula (2) the ratio of d:e is from 1:50 to 0.95:1 or from 1.05:1 to 50:1, preferably the ratio of d:e is from 1:30 to 0.9:1 or from 1.1:1 to 30:1, more preferably the ratio of d:e is from 1:30 to 0.8:1 or from 1.2:1 to 30:1.

4 . The compound according to claim 1 , wherein for formula (3) the ratio of g:h is from 1:50 to 1.45:1, preferably from 1:50 to 1.4:1, more preferably from 1:40 to 1.3:1, even more preferably from 1:30 to 1.2:1.

5 . The compound according to claim 1 , wherein for formula (3) the ratio of g:i is from 1:50 to 50:1, preferably from 1:20 to 10:1, more preferably from 1:18 to 2:1, even more preferably from 1:16 to 1.5:1.

6 . The compound according to claim 1 , wherein for formula (3) the ratio of h:i is from 1:50 to 1:2.05, or from 1:1.95 to 1.95:1, or from 2.05:1 to 50:1; preferably from 1:30 to 1:2.05, or from 1:1.95 to 1.95:1, or from 2.05:1 to 30:1; more preferably from 1:10 to 1:2.1, or from 1:1.9 to 1.9:1, or from 2.1:1 to 10:1; even more preferably from 1:3 to 1:2.1, or from 1:1.9 to 1.9:1, or from 2.1:1 to 3:1; most preferably from 1:3 to 1:2.15, or from 1:1.85 to 1.85:1, or from 2.15:1 to 3:1.

7 . The compound according to claim 1 , wherein
for formula (1) the ratio of a:b is from 1:40 to 1:1.8 or from 1.8:1 to 40:1, for formula (2) the ratio of d:e is from 1:30 to 0.9:1 or from 1.1:1 to 30:1, and for formula (3) the ratio of g:h is from 1:40 to 1.3:1, the ratio of g:i is from 1:18 to 2:1, and the ratio of h:i is from 1:3 to 1:2.1, or from 1:1.9 to 1.9:1, or from 2.1:1 to 3:1.

8 . The compound according to claim 1 , wherein for formula (1), a=at least 1, preferably a=1 to 100, more preferably a=1 to 50, even more preferably a=1 to 20, even more preferably a=1 to 10 or a=2 to 10, and/or
wherein for formula (1), b=at least 2, preferably b=2 to 50, more preferably b=2 to 15, even more preferably b=2 to 10 or b=3 to 10.

9 . The compound according to claim 1 , wherein for formula (1), a=1 to 10, b=2 to 10 and c=4 to 20.

10 . The compound according to claim 1 , wherein the compound represented by formula (1) is selected from BaMo 2 O 6 , Ba 2 Mo 6 O 17 , Ba 4 Mo 2 O 9 , and Ba 6 Mo 2 O 11 , or a compositional equivalent of any of these compounds.

11 . The compound according to claim 1 , wherein for formula (2), d=at least 1, preferably d=1 to 100, more preferably d=1 to 50, even more preferably d=1 to 10, even more preferably d=1 to 6 or d=2 to 6, and/or
wherein for formula (2), e=at least 1, preferably e=1 to 100, more preferably e=1 to 50, even more preferably e=1 to 10, even more preferably e=1 to 8 or e=2 to 8, and/or wherein for formula (2), d=1 to 6, e=1 to 8 and f=9 to 20.

12 . The compound according to claim 1 , wherein the compound represented by formula (2) is selected from MoP 3 O 10 , Mo 3 PO 10 , and Mo 4 P 2 O 15 , or a compositional equivalent of any of these compounds.

13 . The compound according to claim 1 , wherein for formula (3), g=at least 1, preferably g=1 to 100, more preferably g=1 to 50, even more preferably g=1 to 10, even more preferably g=1 to 8 or g=1 to 6, and/or
wherein for formula (3), h=at least 1, preferably h=1 to 100, more preferably h=1 to 50, even more preferably h=1 to 10, even more preferably h=1 to 8 or h=2 to 8, and/or wherein for formula (3), i=at least 1, preferably i=1 to 100, more preferably i=1 to 50, even more preferably i=1 to 20, even more preferably i=1 to 15.

14 . The compound according to claim 1 , wherein for formula (3), g=1 to 8, h=1 to 8, i=1 to 15 and j=6 to 60.

15 . The compound according to claim 1 , wherein the compound represented by formula (3) is selected from BaMoPO 6 , BaMo 4 P 4 O 21 , Ba 5 Mo 8 P 12 O 55 , or a compositional equivalent of any of these compounds.

16 . A coated glass article comprising:
a glass substrate and a coating on the glass substrate, wherein the coating comprises a first layer based on a compound represented by one of the formulae:
Ba a Mo b O c   (1),

MO d P e O f   (2) or

Ba g Mo h P i O j   (3)

wherein for formula (1) the ratio of a:b is from 1:100 to 100:1, wherein for formula (2) the ratio of d:e is from 1:100 to 100:1, wherein for formula (3) the ratio of g:h is from 1:100 to 100:1, wherein for formula (3) the ratio of g:i is from 1:100 to 100:1, wherein for formula (3) the ratio of h:i is from 1:100 to 100:1, and wherein the molybdenum present within the compound is in the 5+ oxidation state.

17 . The coated glass article according to claim 16 , wherein for formula (1) the ratio of a:b is from 1:50 to 50:1, preferably the ratio of a:b is from 1:10 to 10:1, more preferably the ratio of a:b is from 1:5 to 5:1, and/or
wherein for formula (2) the ratio of d:e is from 1:50 to 50:1, preferably the ratio of d:e is from 1:10 to 10:1, and/or wherein for formula (3) the ratio of g:h is from 1:50 to 50:1, preferably from 1:50 to 10:1, more preferably from 1:50 to 2:1, even more preferably from 1:50 to 1.2:1, and/or wherein for formula (3) the ratio of g:i is from 1:40 to 40:1, preferably from 1:30 to 20:1, more preferably from 1:20 to 10:1, even more preferably from 1:18 to 3:1, and/or wherein for formula (3) the ratio of h:i is from 1:50 to 1:50, preferably from 1:30 to 30:1, more preferably from 1:10 to 10:1, even more preferably from 1:5 to 5:1, most preferably from 1:3 to 3:1.

18 . The coated glass article according to claim 16 , wherein the coating further comprises
one or more lower layer between the glass substrate and the first layer, and one or more upper layer located further from the glass substrate than the first layer.

19 . A method of manufacturing the compound according to claim 1 , comprising:
i) for compounds represented by formula (1), providing a Ba-containing precursor, a Mo-containing precursor and an O-containing precursor, wherein at least two of said precursors may be the same precursor, and reacting said precursors to form a compound represented by formula (1), or ii) for compounds represented by formula (2), providing a Mo-containing precursor, a P-containing precursor and an O-containing precursor, wherein at least two of said precursors may be the same precursor, and reacting said precursors to form a compound represented by formula (2), or iii) for compounds represented by formula (3), providing a Ba-containing precursor, a Mo-containing precursor, a P-containing precursor and an O-containing precursor, wherein at least two of said precursors may be the same precursor, and reacting said precursors to form a compound represented by

Assignees

• Pilkington Group Ltd

Inventors

• Sanderson Kevin
• Colley Anna
• Hodgkinson John
• Strickler David
• Dahal Lila
• Ranjan Vikash
• Rosseinsky Matthew
• Dyer Matthew
• Zeng Dihao
• Han Guopeng
• Alaria Jonathon
• Manning Troy
• Beesley Thomas
• Krowitz Anna

Classifications

• C01B25/45 Primary

  containing plural metal, or metal and ammonium · CPC title

• C01B25/37

  Phosphates of heavy metals · CPC title

• C03C17/245

  by deposition from the vapour phase · CPC title

• C09D1/00

  Coating compositions, e.g. paints, varnishes or lacquers, based on inorganic substances · CPC title

• C03C2217/228

  Other specific oxides · CPC title