Flash recycling of batteries

Patent metadata

Field	Value
Publication number	US-2024120506-A1
Application number	US-202218264646-A
Country	US
Kind code	A1
Filing date	Feb 8, 2022
Priority date	Feb 8, 2021
Publication date	Apr 11, 2024
Grant date	—

Abstract

Method and system for flash recycling of batteries, including lithium-ion batteries, other metal (sodium, potassium, zinc, magnesium, and aluminum)-ion batteries, metal batteries, batteries having all metal oxide cathodes, and batteries having graphite-containing anodes. The method and system include a solvent-free and water-free flash Joule heating (FJH) method performed upon a mixture that includes materials from the batteries done in millisecond for recycling the materials. In some embodiments, the FJH method is combined with magnetic separation to recover lithium, cobalt, nickel, and manganese with high yields up to 98%. In some embodiments, the FJH method is followed by rinsing with dilute acid, such a 0.01 M HCl. In other embodiments, the FJH method is utilized to purify the graphite in the battery, such as for use in the anode of the battery.

First claim

1 . A method of recovering metal, wherein the method comprises:
(a) forming a mixture comprising a cathode material, wherein the cathode material is prepared from one or more batteries; (b) applying a voltage across the mixture to obtain metals and cathode waste from the cathode material, wherein
(i) the voltage is applied in one or more voltage pulses, and
(ii) duration of each of the one or more voltage pulses is for a duration period; and
(c) magnetically separating the metal and the cathode waste.

2 . The method of claim 1 , wherein the metal comprises cathode metal selected from the group consisting of lithium, cobalt, nickel, manganese, iron, and combinations thereof.

3 . The method of claim 1 , wherein the metal comprises cathode metal selected from the group consisting of be metal oxides, metal salts, metal carbonates, metal phosphates, and combinations thereof.

4 . The method of claim 3 , wherein the cathode metal comprises metal oxide.

5 . The method of claim 4 , wherein the metal oxide comprises cobalt oxide.

6 . The method of claim 3 , wherein the cathode metal comprises metal carbonate.

7 . The method of claim 6 , wherein the metal carbonate comprises lithium carbonate.

8 . The method of claim 3 , wherein the cathode metal comprises metal phosphate.

9 . The method of claim 8 , wherein the metal phosphate comprises iron phosphate.

10 . (canceled)

11 . The method of claim 1 , wherein the one or more batteries comprise one or more lithium-ion batteries.

12 . The method of claim 11 , wherein the one or more lithium-ion batteries comprise lithium-ion batteries each having a lithium cobalt oxide (LCO) cathode or a lithium nickel-manganese-cobalt oxide (NMC) cathode.

13 . The method of claim 12 , wherein each of the one or more lithium-ion batteries each comprise an LCO cathode.

14 . The method of claim 12 , wherein each the one or more lithium-ion batteries each comprise an NMC cathode.

15 - 18 . (canceled)

19 . The method of claim 1 , wherein the mixture further comprises a conductive additive.

20 - 56 .

57 . The method of claim 1 , wherein the method preserves the 3D layer structure of the cathodes in the cathode material.

58 . The method of claim 1 , wherein the method preserves the 3D morphology of the cathodes in the cathode material.

59 . The method of claim 1 , wherein the method destroys the 3D morphology of the cathodes in the cathode material.

60 . The method of claim 1 further comprising a cooling step, wherein the cooling step cools the metals and the cathode waste before the step of magnetically separating the metals and the cathode waste.

61 - 62 . (canceled)

63 . The method of claim 1 , wherein the method further comprises, after the step of mechanical separating, applying a second voltage across the cathode waste, wherein
(a) the second voltage is applied in one or more second voltage pulses; and (b) duration of each of the one or more second voltage pulses is for a second duration period.

64 . (canceled)

65 . The method of claim 63 , wherein
(a) the applying of the second voltage across the cathode waste obtains further metals and a reduced portion of the cathode waste, and (b) the method further comprises magnetically separating the additional metals and the reduced portion of the cathode waste.

66 . The method of claim 65 , wherein the further metals and reduced portion of the cathode waste are at a weight ratio of at least 1:1.

67 - 85 . (canceled)

86 . A system for performing the method of recovering metal utilizing the method of claim 1 , wherein the system comprises:
(a) a source of the mixture comprising the cathode material; (b) a cell operably connected to the source such that the mixture can be flowed into the cell and held under compression; (c) electrodes operatively connected to the cell; (d) a flash power supply for applying a voltage across the mixture to obtain metals and cathode waste from the cathode material; (e) a magnet in operable contact with the metals and cathode waste, wherein the magnet is operable for magnetically separating the metals and the cathode waste.

87 . The system of claim 86 , wherein the mixture further comprises a conductive additive.

88 - 97 . (canceled)

98 . A method of recovering metal, wherein the method comprises:
(a) forming a mixture comprising a cathode material, wherein the cathode material is prepared from one or more batteries comprising cathodes; (b) applying a voltage across the mixture to obtain metals and cathode waste from the cathode material, wherein
(i) the voltage is applied in one or more voltage pulses,
(ii) duration of each of the one or more voltage pulses is for a duration period,
(iii) the method destroys 3D morphology of the cathodes in the cathode material; and
(c) extracting the metal from the cathode waste using an aqueous solution.

99 . The method of claim 98 , wherein the metals are selected from the group consisting of lithium, cobalt, nickel, manganese, copper, and iron.

100 . The method of claim 99 , where the metals are in the form of one or more metal salts.

101 . The method of claim 100 , wherein the one or more metal salts are in the form one or more oxides.

102 . The method of claim 98 , wherein the aqueous solution comprises an acid.

103 - 107 . (canceled)

108 . The method of claim 98 , wherein the one or more batteries comprising cathodes comprises cathodes selected from the group consisting of LCO lithium cobalt oxide (LCO) cathodes and NMC lithium nickel-manganese-cobalt oxide (NMC) cathodes.

109 - 145 . (canceled)

Assignees

• Univ Rice William M

Inventors

• Tour James Mitchell
• Chen Weiyin
• Luong Duy X
• Kittrell Carter

Classifications

• H01M6/52 Primary

  Reclaiming serviceable parts of waste cells or batteries {, e.g. recycling} · CPC title

• C25C1/08

  of nickel or cobalt · CPC title

• H01M10/54 Primary

  Reclaiming serviceable parts of waste accumulators · CPC title

• Y02P10/20

  Recycling · CPC title

• Y02W30/84

  Recycling of batteries or fuel cells · CPC title