Optical structure and method of manufacturing it

Patent metadata

Field	Value
Publication number	US-2024118471-A1
Application number	US-202017768050-A
Country	US
Kind code	A1
Filing date	Oct 15, 2020
Priority date	Oct 17, 2019
Publication date	Apr 11, 2024
Grant date	—

Abstract

An optical structure comprising at least one stack having a central filter ( 1 ) and two sandwiching optical elements ( 2,3 ) between which the central filter ( 1 ) is interposed, wherein the central filter ( 1 ) is in a matrix material. The matrix material being doped with at least one doping agent, the central filter ( 1 ) and the two optical elements ( 2,3 ) on either side thereof being assembled by bonding layers ( 4 a, 4 b ) of a material based on the same matrix material as that of the central filter, the optical elements ( 2,3 ) on either side of the central filter ( 1 ) and the bonding layers ( 4 a, 4 b ) each having a refractive index equal to that of the material of the central filter or only differing from this refractive index within a range of plus or minus 0.05, preferably within a range of plus or minus 0.02.

First claim

1 . Optical structure comprising at least one stack comprising a central filter and two sandwiching optical elements between which the central filter is interposed, wherein the central filter is in a matrix material, the matrix material being doped with at least one doping agent, the central filter and the two sandwiching optical elements on either side thereof being assembled by bonding layers of a material based on the same matrix material as the matrix material of the central filter, the optical sandwiching elements on either side of the central filter and the bonding layers each having a refractive index equal to that of the material of the central filter or only differing from this refractive index within a range of plus or minus 0.05, preferably within a range of plus or minus 0.02.

2 . Optical structure according to claim 1 , wherein the sandwiching optical elements between which the central filter is interposed are in an undoped material based on the same matrix material as the matrix material of the central filter.

3 . Optical structure according to claim 1 , wherein the sandwiching optical elements between Which the central filter is interposed are in an undoped material of fused silica glass.

4 . Optical structure according to claim 1 , wherein the matrix material of the central filter and of the bonding layers ( 4 a, 4 b ) is selected within the following group of materials: methyltrimethoxysilane, methyltriethoxysilane, ethyltriethoxysilane, dimethyldimethoxysilane, phenyltrimethoxysilane, dimethyldiethoxysilane, (3-Glycidyloxypropyl)triethoxysilane, (3-Glycidoxypropyl) methyldimethoxysilane, 2-(3,4-Epoxycyclohexyl)ethyltrimethoxysilane, 2-(3,4-Epoxycyclohexyl)ethylmethyl)dimethoxysilane, diethoxymethylsilane, phenyltriethoxysilane, vinyltriethoxysilane, (3-Glycidyloxypropyl)trimethoxysilane, (3-Glycidoxypropyl) methyldiethoxysilane, 2-(3,4-Epoxycyclohexyl) ethyl(methyl)diethoxysilane and 2-(3,4-Epoxycyclohexyl)ethyltriethoxysilane, and their mixtures, advantageously methyltriethoxysilane, ethyltriethoxysilane and their mixtures.

5 . Optical structure according to claim 4 , wherein the matrix material of the bonding layers is methyltriethoxysilane, with a concentration of methyltriethoxysilane in its solvent higher than 80% in weight, advantageously between 82 to 90% in weight.

6 . Optical structure according to claim 1 , wherein the at least one doping agent is a visible and/or Near infra-Red photochromic and/or optical power limiting agent.

7 . Optical structure according to claim 1 , wherein at least a front face of the optical structure is covered with an anti-reflective layer.

8 . Optical structure according to claim 1 , wherein a stack comprising the central filter and the two sandwiching optical elements between which the central filter is interposed, is sandwiched between a front silica glass and another silica glass, wherein at least the front silica glass is covered with an anti-reflective layer.

9 . Optical structure according to claim 1 , wherein the central filter and the sandwiching optical elements between which the central filter is interposed are each between 0.5 mm and 10 mm thick, advantageously between 0.75 mm and 3 mm.

10 . Optical structure according to claim 1 , wherein the at least one doping agent is such that the optical structure has a transmitted energy lower than 3 μJ for an energy input of 50 J/cm 2 .

11 . Optical structure according to claim 1 , wherein the at least one doping agent is such that the optical structure limits transmitted energy to lower than 3.5 μJ.

12 . Optical structure according to claim 1 , wherein the at least one doping agent is such that the optical structure limits transmitted energy to lower than 3.5 μJ for an energy input of 0 to 100 J/cm 2 .

13 . Optical structure according to claim 1 , wherein the at least one doping agent has a doping concentration of 0.1 to 500 mM.

14 . A method of manufacturing an optical structure according to claim 1 , wherein the central filter and the two sandwiching optical elements on either side thereof are bonded at a temperature between 45° C. to 120° C., advantageously between 50° C. and 70° C., and under a pressure of between 0.1 to 30 Kg/cm 2 , advantageously between 5 and 20 Kg/cm 2 .

15 . A method according to claim 14 , in which the central filter and the two sandwiching optical elements on either side thereof are bonded using a temperature-regulating press.

Assignees

• Univ Calaude Bernard Lyon 1
• Centre Nat Rech Scient
• Ecole Normale Superieure Lyon

Inventors

• Parola Stéphane
• Lopes Cesar
• Chateau Denis
• Chaput Frederic

Classifications

• G02B5/285 Primary

  comprising deposited thin solid films (G02B5/281 - G02B5/289 take precedence; multilayered film filters for fibre optic multiplexing G02B6/29361) · CPC title

• G02B1/11

  Anti-reflection coatings · CPC title

• G02F1/3523 Primary

  Non-linear absorption changing by light, e.g. bleaching · CPC title

• G02B5/283

  designed for the ultraviolet · CPC title

• G02F2203/52

  Optical limiters · CPC title