Co-production of hydrogen, carbon, electricity, and aluminum products with carbon dioxide capture

Patent metadata

Field	Value
Publication number	US-2024101431-A1
Application number	US-202217954746-A
Country	US
Kind code	A1
Filing date	Sep 28, 2022
Priority date	Sep 28, 2022
Publication date	Mar 28, 2024
Grant date	—

Abstract

A hydrocarbon feed stream is exposed to heat in an absence of oxygen to the convert the hydrocarbon feed stream into a solids stream and a gas stream. The gas stream is separated into an exhaust gas stream and a first hydrogen stream. The carbon is separated from the solids stream to produce a carbon stream. Electrolysis is performed on a water stream to produce an oxygen stream and a second hydrogen stream. A solid carbon block is formed. Alumina is smelted using the solid carbon block to produce aluminum. At least a portion of the oxygen of the oxygen stream and a second portion of the carbon of the carbon stream are combined to generate power and a carbon dioxide stream. At least a portion of the aluminum and a third portion of the carbon of the carbon stream are combined and heated to produce aluminum carbide.

First claim

What is claimed is:

1 . A method comprising:
exposing a hydrocarbon feed stream comprising a hydrocarbon to heat in an absence of oxygen to convert the hydrocarbon feed stream into a solids stream and a gas stream, the solids stream comprising carbon, the gas stream comprising hydrogen; separating the gas stream into an exhaust gas stream and a first hydrogen stream comprising at least a portion of the hydrogen from the gas stream; separating the carbon from the solids stream to produce a carbon stream; performing electrolysis on a water stream comprising water to produce an oxygen stream and a second hydrogen stream, the oxygen stream comprising oxygen, the second hydrogen stream comprising hydrogen; forming a solid carbon block, wherein forming the solid carbon block comprises:
combining a spent carbon anode, pitch derived from coal, and a first portion of the carbon of the carbon stream to form a mixture;
heating the mixture at a temperature greater than about 1,000 degrees Celsius (° C.) for a specified time duration to melt and homogenize the mixture; and
solidifying the molten mixture to form the solid carbon block;
smelting alumina to produce aluminum, wherein smelting the alumina comprises:
dissolving alumina in molten cryolite to form an electrolyte solution;
submerging at least a portion of the solid carbon block in the electrolyte solution; and
providing an electric current to the solid carbon block, thereby reducing the alumina to form aluminum and oxygen, wherein the oxygen reacts with at least a portion of the carbon of the solid carbon block to form carbon dioxide;
combining at least a portion of the oxygen of the oxygen stream and a second portion of the carbon of the carbon stream to generate power and a carbon dioxide stream comprising carbon dioxide, wherein a first portion of the generated power is used to perform electrolysis on the water stream, a second portion of the generated power is used to heat the mixture, and a third portion of the generated power is used to provide the electric current to the solid carbon block; and combining and heating at least a portion of the aluminum and a third portion of the carbon of the carbon stream to produce aluminum carbide.

2 . The method of claim 1 , wherein the hydrocarbon feed stream comprises one or more C1-C22 alkanes, one or more C1-C22 alkenes, or any combination thereof.

3 . The method of claim 2 , wherein the hydrocarbon feed stream comprises hydrogen.

4 . The method of claim 3 , wherein the oxygen and the carbon are combined by a direct carbon fuel cell comprising a solid oxide, and the oxygen and the carbon are combined by the direct carbon fuel cell at an operating temperature in a range of from about 550 degrees Celsius (° C.) to about 900° C.

5 . The method of claim 4 , comprising transferring, by a first waste heat recovery heat exchanger, heat from the gas stream to a buffer fluid.

6 . The method of claim 5 , comprising transferring, by a second waste heat recovery heat exchanger, heat from the buffer fluid to the hydrocarbon feed stream prior to exposing the hydrocarbon feed stream to heat in the absence of oxygen.

7 . The method of claim 5 , comprising generating power by a Rankine cycle using the heat transferred from the gas stream to the buffer stream, wherein generating power by the Rankine cycle comprises:
transferring heat from the buffer fluid to a working fluid in a boiler to vaporize the working fluid into a vaporized working fluid; flowing and expanding the vaporized working fluid through a turbine to generate power; condensing the vaporized working fluid into a condensed working fluid; and circulating the condensed working fluid to the boiler.

8 . The method of claim 4 , comprising transferring, by a first waste heat recovery heat exchanger, heat from the carbon dioxide stream to a buffer fluid.

9 . The method of claim 8 , comprising transferring, by a second waste heat recovery heat exchanger, heat from the buffer fluid to the hydrocarbon feed stream prior to exposing the hydrocarbon feed stream to heat in the absence of oxygen.

10 . The method of claim 4 , comprising sequestering, within a subterranean formation, the carbon dioxide stream generated by the direct carbon fuel cell and the carbon dioxide formed from smelting the alumina, such that the carbon dioxide stream and the carbon dioxide are not released to the atmosphere.

11 . A system comprising:
a hydrocarbon feed stream comprising a hydrocarbon; a pyrolysis chamber configured to receive the hydrocarbon feed stream and expose the hydrocarbon feed stream to heat in an absence of oxygen to convert the hydrocarbon feed stream into a solids stream comprising carbon and a gas stream comprising hydrogen; a gas separation unit configured to receive the gas stream from the pyrolysis chamber and separate the hydrogen from the gas stream to produce an exhaust gas stream and a first hydrogen stream comprising at least a portion of the hydrogen from the gas stream; a carbon separation unit configured to receive the solids stream from the pyrolysis chamber and separate the carbon from the solids stream to produce a carbon stream; a water stream comprising water; an electrolysis unit configured to receive the water stream and electrical power, the electrolysis unit configured to use the electrical power to perform electrolysis on the water stream to produce an oxygen stream comprising oxygen and a second hydrogen stream comprising hydrogen; a carbon anode production unit configured to receive a first portion of the carbon stream from the carbon separation unit, the carbon anode production unit configured to combine a spent carbon anode, pitch derived from coal, and the first portion of the carbon stream to form a mixture, the carbon anode production unit configured to heat the mixture at a temperature greater than about 1,000 degrees Celsius (° C.) for a specified time duration to melt and homogenize the mixture, the carbon anode production unit configured to solidify the molten mixture to form a solid carbon block; an alumina smelting unit configured to receive the solid carbon block from the carbon anode production unit, the alumina smelting unit configured to dissolve alumina in molten cryolite to form an electrolyte solution, wherein the solid carbon block is at least partially submerged in the electrolyte solution, the alumina smelting unit configured to provide an electric current to the solid carbon block, thereby reducing the alumina to form aluminum and oxygen, wherein the oxygen reacts with at least a portion of the carbon of the solid carbon block to form carbon dioxide; a power generation unit configured to receive at least a portion of the oxygen stream from the electrolysis unit and a second portion of the carbon stream from the carbon separation unit, the power generation unit comprising a direct carbon fuel cell configured to combine the oxygen from the portion of the oxygen stream and the carbon from the portion of the carbon stream to generate power and a carbon dioxide stream comprising carbon dioxide, wherein a first portion of the power generated by the power generation unit is provided to the electrolysis unit to perform electrolysis on the water stream, a second portion of the power generated by the power generation unit is provided to the carbon anode production unit to heat the mixture, and a third portion of the power generated by the power generation unit is provided to the alumina smelting unit to provide the electric current to the solid carbon block; and an aluminum carbide production unit configured to receive at least a portion of the aluminum from the alumina smelting unit and a thi

Assignees

• Saudi Arabian Oil Co

Inventors

• Hurtado Perez Omar David
• Katikaneni Sai P

Classifications

• C01B32/914 Primary

  Carbides of single elements · CPC title

• B01J6/008

  Pyrolysis reactions (of hydrocarbons C10G9/00) · CPC title

• C01B32/05

  Preparation or purification of carbon not covered by groups C01B32/15, C01B32/20, C01B32/25, C01B32/30 · CPC title

• C25C3/125

  based on carbon · CPC title

• C25C3/18 Primary

  Electrolytes · CPC title