Metal organic framework-derived carbon aerogel, preparation method thereof and application in lithium ion batteries
US-12183924-B2 · Dec 31, 2024 · US
US2024097130A1 · US · A1
| Field | Value |
|---|---|
| Publication number | US-2024097130-A1 |
| Application number | US-202118256611-A |
| Country | US |
| Kind code | A1 |
| Filing date | Jan 12, 2021 |
| Priority date | Jan 12, 2021 |
| Publication date | Mar 21, 2024 |
| Grant date | — |
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A lithium secondary battery includes: a positive electrode film formed on a transparent substrate having flexible electron conductivity and containing a substance capable of performing a redox reaction with lithium ions; a transparent electrolyte having lithium ion conductivity; and a negative electrode film formed on a transparent substrate having flexible electron conductivity and containing an organic radical species capable of performing a redox reaction with lithium ions.
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1 . A lithium secondary battery comprising: a positive electrode film formed on a transparent substrate having flexible electron conductivity and containing a substance capable of performing a redox reaction with lithium ions; a transparent electrolyte having lithium ion conductivity; and a negative electrode film formed on a transparent substrate having flexible electron conductivity and containing an organic radical species capable of performing a redox reaction with lithium ions. 2 . The lithium secondary battery according to claim 1 , wherein the organic radical species of the negative electrode film contains at least one selected from the group consisting of anthraquinone and phthalimide. 3 . The lithium secondary battery according to claim 1 , wherein in a case where a lithium source is contained in the negative electrode film, the substance of the positive electrode film contains at least one organic radical species selected from the group consisting of 2,2,6,6-tetramethylpiperidine 1-oxyl (TEMPO) and a 2,2,6,6-tetramethylpiperidine 1-oxyl (TEMPO) derivative. 4 . A method for manufacturing a lithium secondary battery, comprising: a step of forming a positive electrode film formed on a transparent substrate having flexible electron conductivity and containing a substance capable of performing a redox reaction with lithium ions; a step of forming a negative electrode film formed on a transparent substrate having flexible electron conductivity and containing an organic radical species capable of performing a redox reaction with lithium ions; and a step of forming a transparent electrolyte film having lithium ion conductivity. 5 . The method for manufacturing a lithium secondary battery according to claim 4 , further comprising: a step of charging a battery cell using the positive electrode film, the electrolyte, and the negative electrode film to add a lithium source of the substance to the negative electrode film; and a step of replacing the positive electrode film of the battery cell with another positive electrode film containing at least one organic radical species selected from the group consisting of 2,2,6,6-tetramethylpiperidine 1-oxyl (TEMPO) and a 2,2,6,6-tetramethylpiperidine 1-oxyl (TEMPO) derivative. 6 . The lithium secondary battery according to claim 2 , wherein in a case where a lithium source is contained in the negative electrode film, the substance of the positive electrode film contains at least one organic radical species selected from the group consisting of 2,2,6,6-tetramethylpiperidine 1-oxyl (TEMPO) and a 2,2,6,6-tetramethylpiperidine 1-oxyl (TEMPO) derivative.
of organic compounds · CPC title
by coating on an electrolyte layer · CPC title
Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof · CPC title
Processes of manufacture · CPC title
Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries · CPC title
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