Niobium-titanium oxide, active material, electrode, secondary battery, battery pack, and vehicle

Patent metadata

Field	Value
Publication number	US-2024088385-A1
Application number	US-202318169982-A
Country	US
Kind code	A1
Filing date	Feb 16, 2023
Priority date	Sep 8, 2022
Publication date	Mar 14, 2024
Grant date	—

Abstract

In general, according to one embodiment, a niobium-titanium oxide is provided. The niobium-titanium oxide satisfies Formulae (1) to (3) below in an L*a*b* color space according to Japanese Industrial Standard JIS Z 8722:2009:
95.0≤ L *≤100  (1)

−1.0≤ a *≤1.0  (2)

−1.0≤ b *≤6.0  (3).

First claim

What is claimed is:

1 . A niobium-titanium oxide satisfying Formulae (1) to (3) below in an L*a*b* color space according to Japanese Industrial Standard JIS Z 8722:2009:
95.0≤ L*≤ 100.0  (1)
−1.0≤ a*≤ 1.0  (2)
−1.0≤ b*≤ 6.0  (3).

2 . The niobium-titanium oxide according to claim 1 , comprising a primary particle containing the niobium-titanium oxide,
wherein the primary particle contains, as an element A, at least one selected from the group consisting of Fe, Cr, W, and Mo, the primary particle includes a surface layer defined as a region having a depth of 20 nm from a surface of the primary particle and a center-of-gravity portion present on an inside of the surface layer, and the primary particle has a gradient in which an amount of the element A increases from the center-of-gravity portion toward the surface layer.

3 . The niobium-titanium oxide according to claim 2 , wherein in the surface layer, a ratio AA/AM between a content AA of the element A and a total amount AM of niobium atoms and titanium atoms satisfies 0.02≤AA/AM≤0.10, and
in the center-of-gravity portion, the ratio AA/AM between the content AA of the element A and the total amount AM of niobium atoms and titanium atoms satisfies 0.001≤AA/AM≤0.01.

4 . The niobium-titanium oxide according to claim 1 , wherein in thermogravimetric analysis in air, a weight increase of the niobium-titanium oxide in a range of 200° C. to 500° C. is in a range of 100 ppm to 10000 ppm.

5 . The niobium-titanium oxide according to claim 1 , comprising a primary particle containing the niobium-titanium oxide,
wherein the primary particle contains nitrogen atoms, the primary particle includes a surface layer defined as a region having a depth of 20 nm from a surface of the primary particle and a center-of-gravity portion present on an inside of the surface layer, and the primary particles have a gradient in which an amount of nitrogen atoms increases from the center-of-gravity portion toward the surface layer.

6 . The niobium-titanium oxide according to claim 5 , wherein in the surface layer, a ratio AN/AM between a content AN of nitrogen atoms and a total amount AM of niobium atoms and titanium atoms satisfies 0.01≤AN/AM≤0.3, and
in the center-of-gravity portion, the ratio AN/AM between the content AN of nitrogen atoms and the total amount AM of niobium atoms and titanium atoms satisfies 0.0001≤AN/AM≤0.001.

7 . The niobium-titanium oxide according to claim 1 , comprising a Nb 2 TiO 7 phase as a main phase.

8 . The niobium-titanium oxide according to claim 2 , wherein, on a surface of the primary particle, an amorphous phase containing niobium and titanium is present with a thickness in a range of 0 nm to 2 nm.

9 . The niobium-titanium oxide according to claim 1 , comprising a monoclinic Nb 2 TiO 7 phase, wherein the monoclinic Nb 2 TiO 7 phase is at least one selected from the group consisting of a composite oxide represented by a general formula Li x Ti 1−y M1 y Nb 2−z M2 z O 7+δ and a composite oxide represented by a general formula Li x Ti 1−y M3 y+z Nb 2−z O 7−δ ,
where the M1 is at least one selected from the group consisting of Zr, Si, and Sn, the M2 is at least one selected from the group consisting of V, Ta, and Bi, and the M3 is at least one selected from the group consisting of Mg, Fe, Ni, Co, W, Ta, and Mo, and
the x satisfies 0≤x≤5, the y satisfies 0≤y<1, the z satisfies 0≤z<2, and the δ satisfies −0.3≤δ≤0.3.

10 . The niobium-titanium oxide according to claim 1 , wherein an amount of adsorbed moisture according to a Karl Fischer method is 800 ppm or less.

11 . An active material comprising the niobium-titanium oxide according to claim 1 .

12 . An electrode comprising an active material-containing layer,
wherein the active material-containing layer contains the active material according to claim 11 .

13 . A secondary battery comprising:
a positive electrode; a negative electrode; and an electrolyte, wherein the negative electrode is the electrode according to claim 12 .

14 . A battery pack comprising the secondary battery according to claim 13 .

15 . The battery pack according to claim 14 , further comprising:
an external power distribution terminal; and a protective circuit.

16 . The battery pack according to claim 14 , comprising a plurality of the secondary battery, wherein the secondary batteries are electrically connected in series, in parallel, or in combination of series and parallel.

17 . A vehicle comprising the battery pack according to claim 14 .

18 . The vehicle according to claim 17 , comprising a mechanism configured to convert kinetic energy of the vehicle into regenerative energy.

Assignees

• Toshiba Kk

Inventors

• Murata Yoshiaki
• Ueda Kakuya
• Harada Yasuhiro
• Ise Kazuki
• Takami Norio

Classifications

• H01M2004/027

  Negative electrodes · CPC title

• C01P2006/40

  Electric properties · CPC title

• C01P2004/04

  obtained by TEM, STEM, STM or AFM · CPC title

• H01M2004/021

  Physical characteristics, e.g. porosity, surface area · CPC title

• B60L50/64

  Constructional details of batteries specially adapted for electric vehicles · CPC title