Producing polyolefin products

Patent metadata

Field	Value
Publication number	US-2024076427-A1
Application number	US-202318140165-A
Country	US
Kind code	A1
Filing date	Apr 27, 2023
Priority date	Feb 11, 2014
Publication date	Mar 7, 2024
Grant date	—

Abstract

Catalyst systems and methods for making and using the same. A method of methylating a catalyst composition while substantially normalizing the entiomeric distribution is provided. The method includes slurrying the organometallic compound in dimethoxyethane (DME), and adding a solution of RMgBr in DME, wherein R is a methyl group or a benzyl group, and wherein the RMgBr is greater than about 2.3 equivalents relative to the organometallic compound. After the addition of the RMgBr, the slurry is mixed for at least about four hours. An alkylated organometallic is isolated, wherein the methylated species has a meso/rac ratio that is between about 0.9 and about 1.2.

First claim

What is claimed is:

1 . A polyolefin polymer comprising ethylene and an alpha-olefin having 4 to 20 carbon atoms, wherein the polefin polymer is formed using a catalyst blend comprising a first catalyst compound and second catalyst compounds that are co-supported forming a supported catalyst system, wherein the first catalyst compound comprises the following formula:
(C 5 H a R 1 b )(C 5 H c R 2 d )HfX 2
wherein each R 1 is independently H, a hydrocarbyl group, a substituted hydrocarbyl group, or a heteroatom group; each R 2 is independently H, a hydrocarbyl group, a substituted hydrocarbyl group, or a heteroatom group; a and c are ≥3; a+b=c+d=5; at least one R 1 and at least one R 2 is a hydrocarbyl or substituted hydrocarbyl group; and each X is independently a leaving group selected from a labile hydrocarbyl, substituted hydrocarbyl, or heteroatom group; and the second catalyst compounds comprises a mixture of enantiomers:

wherein the ratio of the meso enantiomer to the rac enantiomer is at least about 3, wherein each R 3 is independently H, a hydrocarbyl group, a substituted hydrocarbyl group, or a heteroatom group; R 4 is a hydrocarbyl group, a substituted hydrocarbyl group, or a heteoatom group; each R 5 is independently H, a hydrocarbyl group, a substituted hydrocarbyl group, or a heteroatom group; and each X is independently a leaving group selected from a labile hydrocarbyl, a substituted hydrocarbyl, a heteroatom group, or a divalent radical that links to an R 3 , R 4 , or R 5 group.

2 . The polyoefin polymer of claim 1 , wherein the meso enantiomer is about 19 parts in the mixture, and the rac enantiomer is about 1 part in the mixture.

3 . The polyoefin polymer of claim 1 , wherein the second catalyst compounds comprise a compound with the following formula:

4 . The polyoefin polymer of claim 1 , wherein the second catalyst compounds comprise at least one compound with the following formula:

5 . The polyoefin polymer of claim 1 , wherein the second catalyst compounds comprise at least one compound with the following formula:

wherein each R 4A is independently a methyl, ethyl, propyl, pentyl, hexyl, octyl, nonyl, dodecyl, phenethyl, or other hydrocarbyl.

6 . The polyoefin polymer of claim 1 , wherein the second catalyst compounds comprise at least one compound with the following formula:

7 . The polyoefin polymer of claim 1 , wherein for the first catalyst compound the adjacent groups R 1 and R 2 groups form a ring.

8 . The polyoefin polymer of claim 1 , wherein for the second catalyst compounds R 3 , R 4 , and R 5 are the same.

9 . The polyoefin polymer of claim 1 , wherein for the second catalyst compounds R 3 , R 4 , and R 5 are different.

Assignees

• Univation Tech Llc

Inventors

• Rix Francis C
• Todd Alexander D
• Harlan C Jeff

Classifications

• C08F210/16 Primary

  Copolymers of ethene with alpha-alkenes, e.g. EP rubbers · CPC title

• C07F17/00

  Metallocenes · CPC title

• C08F2/00

  Processes of polymerisation · CPC title

• C08F2/34

  Polymerisation in gaseous state · CPC title

• C08F4/6432

  Component of C08F4/64 containing at least two different metals · CPC title