Hydrogenation catalyst with improved sulfur resistance and method for producing same

Patent metadata

Field	Value
Publication number	US-2024058795-A1
Application number	US-202118259785-A
Country	US
Kind code	A1
Filing date	Nov 29, 2021
Priority date	Dec 30, 2020
Publication date	Feb 22, 2024
Grant date	—

Abstract

The present invention relates to a hydrogenation catalyst with improved sulfur resistance and a method for producing the same. More specifically, the present invention comprises cerium and copper to enhance resistance to sulfur, that is, resistance to sulfur poisoning, thereby extending the lifespan and improving activity of the catalyst, which is be used in the hydrogenation of petroleum resin.

First claim

1 . A hydrogenation catalyst comprising: 40 to 80 parts by weight of nickel, 0.01 to 5 parts by weight of copper and 0.05 to 5 parts by weight of cerium as catalyst activation components; and 10 to 30 parts by weight of silica as a carrier.

2 . The hydrogenation catalyst as claimed in claim 1 , wherein nickel, copper and cerium are present in the form of metals or oxide thereof.

3 . The hydrogenation catalyst as claimed in claim 1 , wherein nickel has a particle size of 3 nm to 8 nm.

4 . The hydrogenation catalyst as claimed in claim 1 , wherein the catalyst has a BET specific surface area of 150 m 2 /g to 300 m 2 /g.

5 . The hydrogenation catalyst as claimed in claim 1 , wherein the catalyst has a total pore volume of 0.2 m 3 /g to 0.4 m 3 /g.

6 . The hydrogenation catalyst as claimed in claim 1 , wherein the catalyst has an average pore size of 5 nm to 10 nm.

7 . The hydrogenation catalyst as claimed in claim 1 , wherein the catalyst has an average particle size (d 50 ) of 3 μm to 100 μm.

8 . A method for producing a hydrogenation catalyst, comprising:
preparing a first solution by dissolving a nickel precursor in a solvent so as to have a weight concentration (g/L) of nickel in the range of 25 to 100 in the first solution; preparing a second solution by adding a copper precursor and a cerium precursor to the first solution so as to have a weight concentration (g/L) of copper in the range of 0.01 to 5 and a weight concentration (g/L) of cerium in the range of 0.05 to 5 in the second solution; preparing a third solution by adding a silica carrier to the second solution and dispersing the silica carrier therein so as to have a weight concentration (g/L) of silica in the range of 5 to 30 in the third solution; placing the third solution in a precipitation bottle, followed by stirring and heating the third solution to a temperature of 50° C. to 120° C.; preparing a catalyst by adding a pH regulator to the third solution to precipitate and deposit the precursors on the silica carrier; washing and filtering the catalyst, followed by drying the filtered catalyst; and activating the dried catalyst through reduction of the dried catalyst.

9 . The method for producing a hydrogenation catalyst as claimed in claim 8 , further comprising: passivating the activated catalyst.

10 . The method for producing a hydrogenation catalyst as claimed in claim 9 , wherein passivation of the activated catalyst is performed in a nitrogen mixed gas containing 0.1 vol % to 20 vol % of oxygen.

11 . The method for producing a hydrogenation catalyst as claimed in claim 9 , wherein passivation of the activated catalyst is performed through immersion of the activated catalyst in an organic solvent or in a solution containing a petroleum resin in an organic solvent.

12 . A petroleum resin hydrogenation method comprising: bringing a petroleum resin into contact with hydrogen in the presence of the hydrogenation catalyst as claimed in claim 1 .

13 . The petroleum resin hydrogenation method as claimed in claim 12 , wherein the petroleum resin is polymerized from a raw material comprising at least one selected from among C5, C8 and C9 petroleum fractions, by-products, and combinations thereof.

14 . The petroleum resin hydrogenation method as claimed in claim 12 , wherein the petroleum resin comprises a material selected from the group consisting of an olefin group, an aromatic group and combinations thereof.

15 . The petroleum resin hydrogenation method as claimed in claim 12 , wherein the petroleum resin has a sulfur content of 1 ppmw to 300 ppmw.

16 . The petroleum resin hydrogenation method as claimed in claim 12 , wherein the petroleum resin has an APHA value of 30 or less after hydrogenation of the petroleum resin.

17 . A petroleum resin hydrogenated by the petroleum resin hydrogenation method as claimed in claim 12 .

Assignees

• Hanwha Solutions Corp

Inventors

• Lee Young Hee
• Park Woo Jin
• Jeon Bong Sik
• Jung Eui Geun

Classifications

• C10G49/04

  containing nickel, cobalt, chromium, molybdenum, or tungsten metals, or compounds thereof · CPC title

• B01J35/393

  Metal or metal oxide crystallite size · CPC title

• B01J35/45

  Nanoparticles · CPC title

• B01J35/40

  characterised by dimensions, e.g. grain size (in a colloidal state B01J35/23; crystallite size B01J35/77) · CPC title

• B01J23/83 Primary

  with rare earths or actinides · CPC title