Methods of recovering lithium from a lithium-containing material, and related systems

Patent metadata

Field	Value
Publication number	US-2024055680-A1
Application number	US-202118257786-A
Country	US
Kind code	A1
Filing date	Dec 15, 2021
Priority date	Dec 16, 2020
Publication date	Feb 15, 2024
Grant date	—

Abstract

A method of recovering lithium from a lithium-containing material comprises introducing a lithium-containing material to an electrochemical cell, transporting lithium ions from the lithium-containing material through a cation exchange membrane to a catholyte within a cathode chamber of the electrochemical cell, reacting the lithium ions with bicarbonate ions in the cathode chamber to form lithium carbonate, and removing the lithium carbonate from the catholyte. Related methods of recovering lithium from lithium-containing, materials, and related systems are disclosed.

First claim

1 . A method of removing lithium from a lithium-containing material, the method comprising:
introducing a lithium-containing material to an electrochemical cell; transporting lithium ions from the lithium-containing material through a cation exchange membrane to a catholyte within a cathode chamber of the electrochemical cell; reacting the lithium ions with bicarbonate ions in the cathode chamber to form lithium carbonate; and removing the lithium carbonate from the catholyte.

2 . The method of claim 1 , wherein introducing a lithium-containing material to an electrochemical cell comprises introducing a leachate from a leaching process for leaching one or more metals from a lithium-ion battery to the electrochemical cell.

3 . The method of claim 2 , further comprising removing one or more of nickel, cobalt, and manganese from the leachate prior to introducing the lithium-containing material to the electrochemical cell.

4 . The method of claim 1 , wherein transporting lithium ions from the lithium-containing material through a cation exchange membrane comprises transporting the lithium ions from the lithium-containing material through a monovalent cation exchange membrane.

5 . The method of claim 1 , further comprising deprotonating a switchable polarity solvent in the cathode chamber to form water.

6 . The method of claim 1 , further comprising reacting a deprotonated switchable polarity solvent with carbon dioxide and water to form the bicarbonate ions and a protonated switchable polarity solvent external to the cathode chamber.

7 . The method of claim 6 , further comprising introducing the bicarbonate ions and the protonated switchable polarity solvent to the catholyte.

8 . The method of claim 1 , further comprising introducing a switchable polarity solvent comprising a tertiary amine to the cathode chamber.

9 . The method of claim 1 , further comprising oxidizing manganese ions in an anode chamber of the electrochemical cell.

10 . The method of claim 1 , wherein removing the lithium carbonate from the catholyte comprises passing the catholyte through a filter to remove the lithium carbonate from the catholyte.

11 . A method of recovering lithium from a lithium-containing material, the method comprising:
providing a catholyte comprising a protonated switchable polarity solvent in a cathode chamber of an electrochemical cell; transporting lithium ions from a lithium-containing material through a cation exchange membrane into the cathode chamber; reacting the lithium ions with bicarbonate ions to form lithium carbonate in the cathode chamber; reacting the protonated switchable polarity solvent with hydroxide ions to form a deprotonated switchable polarity solvent and water; and contacting the deprotonated switchable polarity solvent with carbon dioxide and water to protonate the deprotonated switchable polarity solvent and produce bicarbonate ions.

12 . The method of claim 11 , wherein providing a catholyte comprising a protonated switchable polarity solvent in a cathode chamber of an electrochemical cell comprises providing the protonated switchable polarity solvent contacted by the carbon dioxide to the cathode chamber.

13 . The method of claim 11 , wherein providing a catholyte comprising a protonated switchable polarity solvent in a cathode chamber comprises providing the protonated switchable polarity solvent to a cathode chamber comprising one or more of platinum, nickel, gold, iridium oxide, titanium, and carbon to the cathode chamber.

14 . The method of claim 11 , further comprising providing the bicarbonate ions to the cathode chamber.

15 . The method of claim 11 , further comprising reacting hydroxide ions at an anode of the electrochemical cell to form oxygen and water.

16 . The method of claim 11 , wherein providing a catholyte comprising a protonated switchable polarity solvent in a cathode chamber of an electrochemical cell comprises providing a catholyte comprising a tertiary amine to the cathode chamber.

17 . The method of claim 11 , wherein providing a catholyte comprising a protonated switchable polarity solvent in a cathode chamber of an electrochemical cell comprises providing a catholyte comprising one or more of methyl diethanolamine, diethanolamine, and monoethanolamine to the cathode chamber.

18 . A system for recovering lithium from a lithium-containing, leachate, the system comprising:
an electrochemical cell comprising an anode chamber and a cathode chamber, the cathode chamber configured to receive a catholyte comprising a switchable polarity solvent and bicarbonate ions; and a monovalent cation exchange membrane separating the anode chamber from the cathode chamber.

19 . The system of claim 18 , wherein the switchable polarity solvent is formulated to be protonated within the catholyte.

20 . The system of claim 18 , further comprising a carbon dioxide source configured to protonate the switchable polarity solvent from a deprotonated state to a protonated state.

21 . The system of claim 18 , further comprising:
a center chamber in the electrochemical cell between the anode chamber and the cathode chamber; and a bipolar membrane between the center chamber and the anode chamber.

22 . The system of claim 18 , wherein the catholyte comprises an aqueous phase and an organic phase.

23 . The system of claim 22 , wherein the organic phase comprises an alcohol.

Assignees

• Battelle Energy Alliance Llc

Inventors

• Diaz Aldana Luis A
• Lister Tedd E
• Wilson Aaron D
• Klaehn John R
• Shi Meng

Classifications

• H01M10/54 Primary

  Reclaiming serviceable parts of waste accumulators · CPC title

• C25B1/14

  Alkali metal compounds · CPC title

• C22B7/007 Primary

  by acid leaching · CPC title

• C25B9/19

  with diaphragms · CPC title

• C25B15/083

  Separating products · CPC title