Organic solar cell for current-voltage test and preparation method thereof

Patent metadata

Field	Value
Publication number	US-2024039474-A1
Application number	US-202318377993-A
Country	US
Kind code	A1
Filing date	Oct 9, 2023
Priority date	Jul 25, 2023
Publication date	Feb 1, 2024
Grant date	—

Abstract

The present invention relates to an organic solar cell for a current-voltage test and a preparation method thereof. The disclosed organic solar cell for the current-voltage test comprises a substrate with a preset ITO pattern, wherein ITO on the substrate with the preset ITO pattern is used as the anode layer, and a hole transport layer, an active layer, an electron transport layer and a cathode layer are stacked successively to form a solar cell. A plurality of cell positions are designed on the substrate in the present invention. Each cell has an independent cathode test site and an anode test site. The distance between the test site of each cell and the cell is kept the same and the distance is short enough; and the cells are distributed evenly on the substrate discretely. The present invention has high substrate utilization rate, high data accuracy and good parallelism.

First claim

What is claimed is:

1 . An organic solar cell for a current-voltage test, comprising a substrate S 0 , an anode layer S 1 , a hole transport layer S 2 , an active layer S 3 , an electron transport layer S 4 and an electrode coating S 5 successively, wherein the substrate S 0 has a preset ITO pattern.

2 . The organic solar cell for the current-voltage test according to claim 1 , wherein the substrate S 0 is made of a square glass material.

3 . The organic solar cell for the current-voltage test according to claim 2 , wherein the ITO coating of the substrate S 0 with the preset ITO pattern is the anode layer Si, and the regions of the ITO coating are a plurality of rectangles N 1 with long sides of L 1 and wide sides of M 1 , and distributed evenly in a plurality of positions on the surface of the substrate discretely.

4 . The organic solar cell for the current-voltage test according to claim 3 , wherein rectangular regions N 2 without the hole transport layer S 2 , the active layer S 3 and the electron transport layer S 4 coating are arranged at a parallel edge of the substrate S 0 perpendicular to the direction of ITO to expose the ITO coating; and the rectangular regions N 2 without the coating are perpendicular to the long side L 1 of the region N 1 of the rectangle ITO and parallel to the wide side M 1 of the region N 1 of the rectangle ITO, and are in one-to-one correspondence with the positions of current-voltage test electrodes.

5 . The organic solar cell for the current-voltage test according to claim 1 , wherein the hole transport layer S 2 is PEDOT: PSS.

6 . The organic solar cell for the current-voltage test according to claim 1 , wherein the active layer S 3 comprises a donor material and an acceptor material, and the donor material comprises PM6, D18 or B1; and the acceptor material comprises Y6, BO-4C1, BTP-eC9, L8-BO or OSe.

7 . The organic solar cell for the current-voltage test according to claim 1 , wherein the electron transport layer S 4 is PDIN, PDINN or PNDIT-F3N.

8 . The organic solar cell for the current-voltage test according to claim 4 , wherein the electrode coating S 5 comprises L-shaped regions N 3 and rectangular regions N 4 which are distributed evenly on the surface of the substrate discretely, and the rectangular regions N 4 are in one-to-one correspondence with the rectangular regions N 1 of the anode layer Si; and
the long side L 4 of the rectangular region N 4 is less than the long side L 1 of the rectangular region N 1 , and the wide side M 4 of the rectangular region N 4 is equal to the wide side M 1 of the rectangular region N 1 ;
the L-shaped region N 3 is composed of a rectangle N 31 and a rectangle N 32 , the wide side M 4 of the rectangular region N 4 <the long side L 311 of N 31 ≤the long side L 321 of N 32 , and the wide side M 311 of N 31 is equal to the wide side M 4 of the rectangular region N 4 ; the wide side M 321 of N 32 ≤the wide side M 1 of the rectangular region N 1 , and the long side L 4 of the rectangular region N 4 <the long side L 321 of N 32 ≤the long side Ll of the rectangular region N 1 .

9 . The organic solar cell for the current-voltage test according to claim 8 , wherein the L-shaped regions N 3 and the rectangular regions N 4 have opposite polarities; and
the L-shaped regions N 3 are cathode layers of the organic solar cell; and the rectangular regions N 4 and the ITO are conducted and jointly used as anodes of the organic solar cell.

10 . The organic solar cell for the current-voltage test according to claim 8 , wherein the long side L 2 of the rectangular region N 2 without the coating is equal to the side length of the substrate S 0 , and the wide side M 2 of the rectangular region N 2 without the coating≤the long side L 4 of the rectangle N 4 .

11 . The organic solar cell for the current-voltage test according to claim 9 , wherein an arrangement region Q 1 of the cell is a region where the anode layer ITO S 1 , the hole transport layer S 2 , the active layer S 3 , the electron transport layer S 4 and the cathode layer N 3 on the substrate S 0 with the preset ITO pattern are overlapped.

12 . A preparation method of the organic solar cell for the current-voltage test in claim 1 , comprising the following steps:
I. cleaning and treating the substrate S 0 with the preset ITO pattern by an ultrasonic cleaning method and an ultraviolet ozone method; II. preparing the hole transport layer S 2 , the active layer S 3 and the electron transport layer S 4 successively on the surface of the substrate S 0 by a spin-coating method, wherein spin-coating area is the size of the substrate S 0 ; III. removing the spin-coating coating from the parallel edge of the surface of the substrate S 0 perpendicular to the direction of ITO to the interior of the surface of the substrate S 0 to form rectangular regions N 2 without the spin-coating coating; IV. evaporating a metallic silver electrode S 5 on the substrate through a vacuum evaporation method of the substrate obtained in step III combined with a mask plate with a preset pattern to obtain the organic solar cell for the current-voltage test.

Assignees

• Beijing Institute Tech

Inventors

• Wang Shanshan
• An Qiaoshi
• Du Jianxin
• Peng Shaochun
• Zhang Jiatao
• Gao Peifeng
• Gao Jianbing
• Jiang Mengyun
• Mao Peng
• Yang Qiwen

Classifications

• H02S50/10 Primary

  Testing of PV devices, e.g. of PV modules or single PV cells (testing of semiconductor devices during manufacturing {H10P74/00}) · CPC title

• H10K30/30

  comprising bulk heterojunctions, e.g. interpenetrating networks of donor and acceptor material domains · CPC title

• H10K30/40

  comprising a p-i-n structure, e.g. having a perovskite absorber between p-type and n-type charge transport layers · CPC title

• H10K30/50

  Photovoltaic [PV] devices · CPC title

• H10K30/82 Primary

  Transparent electrodes, e.g. indium tin oxide [ITO] electrodes · CPC title