Methods for purifying and recycling lead from spent lead-acid batteries

Patent metadata

Field	Value
Publication number	US-2024021905-A1
Application number	US-202318474362-A
Country	US
Kind code	A1
Filing date	Sep 26, 2023
Priority date	Jun 20, 2014
Publication date	Jan 18, 2024
Grant date	—

Abstract

The present disclosure relates to methods by which lead from spent lead-acid batteries may be extracted, purified, and used in the construction of new lead-acid batteries. A method includes: (A) forming a mixture including a carboxylate source and a lead-bearing material; (B) generating a first lead salt precipitate in the mixture as the carboxylate source reacts with the lead-bearing material; (C) increasing the pH of the mixture to dissolve the first lead salt precipitate; (D) isolating a liquid component of the mixture from one or more insoluble components of the mixture; (E) decreasing the pH of the liquid component of the mixture to generate a second lead salt precipitate; and (F) isolating the second lead salt precipitate from the liquid component of the mixture. Thereafter, the isolated lead salt precipitate may be converted to leady oxide for use in the manufacture of new lead-acid batteries.

First claim

1 . A recycled lead-acid battery made by a process comprising:
processing a spent lead-acid battery to generate a lead-bearing material; forming a mixture containing a carboxylate source and the lead-bearing material; generating a lead-salt precipitate in the mixture as the carboxylate source reacts with the lead-bearing material; treating the lead salt precipitate with a calcination method producing a leady oxide; and forming a new lead-acid battery using the leady oxide formed from the method.

2 . The recycled lead-acid battery of claim 1 , wherein the lead salt precipitate is heated to a temperature less than 450 degrees Celsius.

3 . The recycled lead-acid battery of claim 2 , wherein the lead salt precipitate is heated to a temperature between 275 degrees Celsius and 400 degrees Celsius.

4 . The recycled lead-acid battery of claim 2 , wherein the lead salt precipitate is heated to a temperature proximate to 330 degrees Celsius. The recycled lead-acid battery of claim 1 , wherein the calcination includes a presence of a first and a second oxidant.

6 . The recycled lead-acid battery of claim 5 , wherein the second oxidant is at least one of an air, an oxygen-enriched air, and a gas stream containing oxygen bearing compounds.

7 . The recycled lead-acid battery of claim 1 , wherein the calcination includes a presence of an oxygen reducer.

8 . The recycled lead-acid battery of claim 7 , wherein the oxygen reducer is at least one of a methane, a coke, a propane, and a natural gas.

9 . The recycled lead-acid battery of claim 1 , wherein the calcination includes dopants for a promotion of a crystal structure for the production of the leady oxide and a free lead.

10 . The recycled lead-acid battery of claim 1 , wherein treating the lead salt precipitate with a base producing the leady oxide.

11 . A method for production of a recycled lead-acid battery comprising:
forming a mixture containing a lead-bearing material from a spent lead-acid battery and a carboxylate source; reacting the carboxylate source reacts with the lead-bearing material to generate a lead-salt precipitate; treating the lead salt precipitate with a calcination method; producing a leady oxide from the calcination method; and forming a new lead-acid battery using the leady oxide formed from the method.

12 . The method of claim 11 , further comprising heating lead salt precipitate to a temperature less than 450 degrees Celsius.

13 . The method of claim 12 , further comprising heating lead salt precipitate to a temperature between 275 degrees Celsius and 400 degrees Celsius.

14 . The method of claim 12 , further comprising heating lead salt precipitate to a temperature proximate to 330 degrees Celsius.

15 . The method of claim 11 , further comprising incorporating a first and a second oxidant.

16 . The method of claim 15 , further comprising incorporating at least one of an air, an oxygen-enriched air, and a gas stream containing oxygen bearing compounds as the second oxidant.

17 . The method of claim 11 , further comprising incorporating an oxygen reducer.

18 . The method of claim 17 , further comprising incorporating at least one of a methane, a coke, a propane, and a natural gas as the oxygen reducer.

19 . The method of claim 11 , further comprising including dopants for a promotion of a crystal structure for a production of the leady oxide and a free lead.

20 . The method of claim 11 , further comprising treating the lead salt precipitate with a base producing the leady oxide.

Assignees

• Cps Tech Holdings Llc

Inventors

• Spence Matthew A

Classifications

• H01M10/54 Primary

  Reclaiming serviceable parts of waste accumulators · CPC title

• B01J8/008

  Details of the reactor or of the particulate material; Processes to increase or to retard the rate of reaction (B01J8/0285, B01J8/067, B01J8/087, B01J8/1836 take precedence) · CPC title

• B01J6/001

  Calcining · CPC title

• B01J6/002

  using rotating drums · CPC title

• C22B13/04

  by wet processes · CPC title