Method of calcining a raw material to obtain a cementitious material

Patent metadata

Field	Value
Publication number	US-2024018039-A1
Application number	US-202118256349-A
Country	US
Kind code	A1
Filing date	Dec 15, 2021
Priority date	Dec 18, 2020
Publication date	Jan 18, 2024
Grant date	—

Abstract

A method of calcining a raw material to obtain a cementitious material, includes providing a flow of raw material containing a metal carbonate, such as CaCO3 to a calcination system, introducing the flow of raw material into a first thermal reactor and at least partially decarbonating the raw material in the first thermal reactor by subjecting the raw material to a first heat treatment at a first temperature of at least 650° C. in order to obtain an at least partly decarbonated material and CO2, wherein the first thermal reactor is heated by electrical energy, and obtaining the cementitious material as a result of the first heat treatment.

First claim

1 . A method of calcining a raw material to obtain a cementitious material, comprising:
providing a flow of raw material containing a metal carbonate to a calcination system, introducing the flow of raw material into a first thermal reactor and at least partially decarbonating the raw material in the first thermal reactor by subjecting the raw material to a first heat treatment at a first temperature of at least 650° C. in order to obtain an at least partly decarbonated material and CO 2 , wherein the first thermal reactor is heated by electrical energy, optionally introducing the at least partly decarbonated material into a second thermal reactor and subjecting the at least partly decarbonated material to a second heat treatment at a second temperature lying above the first temperature, and obtaining the cementitious material as a result of the first and optionally the second heat treatment.

2 . The method according to claim 1 , wherein the flow of raw material is preheated before being introduced into the first thermal reactor, wherein preheating is carried out by bringing a heat exchanging fluid into a heat exchanging relationship with the raw material, while the heat exchanging fluid is cooled.

3 . The method according to claim 2 , wherein an exhaust gas is withdrawn from the first thermal reactor, and said exhaust gas is used as said heat exchanging fluid to preheat the raw material.

4 . The method according to claim 3 , wherein preheating the raw material comprises introducing the exhaust gas into a heat exchanger and preheating the raw material in said heat exchanger.

5 . The method according to claim 2 , wherein an exhaust gas is withdrawn from the first thermal reactor, and the heat exchanging fluid is heated by bringing the exhaust gas into a heat exchanging relationship with the heat exchanging fluid, while the exhaust gas is cooled.

6 . The method according to claim 2 , wherein the cementitious material is introduced into a cooling device, in which the cooled heat exchanging fluid is used to cool the cementitious material, while the cooled heat exchanging fluid is re-heated.

7 . The method according to claim 6 , wherein the re-heated heat exchanging fluid that is withdrawn from the cooling device is used to provide thermal energy to the first or second heat treatment.

8 . The method according to claim 7 , wherein the re-heated heat exchanging fluid that is withdrawn from the cooling device is heated before being used for providing thermal energy to the first or second thermal reactor.

9 . The method according to claim 7 , wherein the re-heated heat exchanging fluid that is withdrawn from the cooling device is introduced into the second thermal reactor to provide thermal energy to the second heat treatment and wherein the heat exchanging fluid is withdrawn from the second thermal reactor and introduced into the first thermal reactor to provide thermal energy to the first heat treatment.

10 . The method according to claim 9 , wherein the heat exchanging fluid that is withdrawn from the second thermal reactor is heated before being introduced into the first thermal reactor.

11 . The method according to claim 8 , wherein the heating of the heat exchanging fluid is performed by means of a heating device that transforms electrical energy into thermal energy.

12 . The method according to claim 1 , wherein the second thermal reactor is heated by electrical energy and/or by combusting a renewable fuel and/or by combusting hydrogen.

13 . The method according to claim 1 , wherein the raw material consists of or comprises clay and/or a recycled concrete material and/or a recycled plasterboard material.

14 . The method according to claim 1 , wherein the metal carbonate is CaCO 3 .

15 . The method according to claim 3 , wherein said exhaust gas contains at least 80 vol. % CO 2 .

16 . The method according to claim 5 , wherein said exhaust gas contains at least 80 vol. % CO 2 .

17 . The method according to claim 7 , wherein the re-heated heat exchanging fluid that is withdrawn from the cooling device is used to provide thermal energy to the first or second heat treatment by introducing the re-heated heat exchanging fluid into the first or second thermal reactor.

18 . The method according to claim 5 , wherein the cementitious material is introduced into a cooling device, in which the cooled exhaust gas is used to cool the cementitious material, while the cooled exhaust gas is re-heated.

19 . The method according to claim 18 , wherein the re-heated exhaust gas that is withdrawn from the cooling device is used to provide thermal energy to the first or second heat treatment.

20 . The method according to claim 19 , wherein the re-heated exhaust gas that is withdrawn from the cooling device is used to provide thermal energy to the first or second heat treatment by introducing the re-heated exhaust gas into the first or second thermal reactor.

21 . The method according to claim 19 , wherein the re-heated exhaust gas that is withdrawn from the cooling device is heated before being used for providing thermal energy to the first or second thermal reactor.

22 . The method according to claim 19 , wherein the re-heated exhaust gas that is withdrawn from the cooling device is introduced into the second thermal reactor to provide thermal energy to the second heat treatment and wherein the exhaust gas is withdrawn from the second thermal reactor and introduced into the first thermal reactor to provide thermal energy to the first heat treatment.

23 . The method according to claim 22 , wherein the exhaust gas that is withdrawn from the second thermal reactor is heated before being introduced into the first thermal reactor.

24 . The method according to claim 21 , wherein the heating of the exhaust gas is performed by means of a heating device that transforms electrical energy into thermal energy.

Assignees

• Holcim Technology Ltd

Inventors

• Stoffel Beat
• Bucher Ernst
• Boes Karl-Heinz
• Weber Mirko

Classifications

• Y02P40/18

  Carbon capture and storage [CCS] · CPC title

• C04B7/46 Primary

  electric · CPC title

• C04B7/432

  Preheating without addition of fuel · CPC title

• C04B7/475

  using the waste heat, e.g. of the cooled clinker, in an other way than by simple heat exchange in the cement production line, e.g. for generating steam · CPC title

• C04B7/4453 Primary

  using plasmas or radiations · CPC title