A method for producing syngas using catalytic reverse water gas shift

Patent metadata

Field	Value
Publication number	US-2024002221-A1
Application number	US-202118254230-A
Country	US
Kind code	A1
Filing date	Dec 16, 2021
Priority date	Dec 18, 2020
Publication date	Jan 4, 2024
Grant date	—

Abstract

A method for producing syngas that comprises providing a feed stream comprising H2 and CO2; heating the feed stream in a first heat exchanger to obtain a first heated feed stream; introducing the first heated feed stream into a first RWGS reactor to obtain a first syngas containing stream; cooling the first syngas containing stream in the first heat exchanger against the feed stream to obtain a first cooled syngas stream; separating the first cooled syngas stream in a first gas/liquid separator to obtain a water-enriched stream and a water-depleted syngas stream; heating the water-depleted syngas stream in a second heat exchanger to obtain a heated water-depleted syngas stream; introducing the heated water-depleted syngas stream into a second RWGS reactor to obtain a second syngas containing stream; and cooling the second syngas containing stream in the second heat exchanger against the water-depleted syngas to obtain a cooled syngas product stream.

First claim

1 . A method for producing syngas using a catalytic reverse water gas shift (RWGS) reaction, the method at least comprising the steps of:
a) providing a feed stream comprising at least hydrogen (H 2 ) and carbon dioxide (CO 2 ); b) heating the feed stream provided in step a) in a first heat exchanger thereby obtaining a first heated feed stream; c) introducing the first heated feed stream into a first RWGS reactor and subjecting it to a first catalytic RWGS reaction, thereby obtaining a first syngas containing stream; d) removing the first syngas containing stream obtained in step c) from the first RWGS reactor; e) cooling the first syngas containing stream removed from the first RWGS reactor in step d) in the first heat exchanger against the feed stream provided in step a), thereby obtaining a first cooled syngas stream; f) separating the first cooled syngas stream obtained in step e) in a first gas/liquid separator thereby obtaining a water-enriched stream and a water-depleted syngas stream; g) heating the water-depleted syngas stream obtained in step f) in a second heat exchanger thereby obtaining a heated water-depleted syngas stream; h) introducing the heated water-depleted syngas stream obtained in step g) into a second RWGS reactor and subjecting it to a second catalytic RWGS reaction, thereby obtaining a second syngas containing stream; i) removing the second syngas containing stream obtained in step h) from the second RWGS reactor; and j) cooling the second syngas containing stream removed from the second RWGS reactor in step i) in the second heat exchanger against the water-depleted syngas stream obtained in step f), thereby obtaining a cooled syngas product stream.

2 . The method according to claim 1 , wherein the temperature of the first catalytic RWGS reaction in step c) is kept below 700° C.

3 . The method according to claim 1 , wherein at least one of the first and the second RWGS reactors contains two or more catalyst beds with additional intermediate heating between the two or more catalyst beds.

4 . The method according to claim 1 , wherein at least one of the first and the second RWGS reactors comprises a multi-tubular reactor heated by molten salt circulating around the tubes of the multi-tubular reactor.

5 . The method according to claim 1 , wherein the first syngas containing stream comprises at most 1.0 vol. % methane (CH 4 ).

6 . The method according to claim 1 , wherein the temperature of the second catalytic RWGS reaction in step h) is kept below 700° C.

7 . The method according to claim 1 , wherein the method further comprises the step of separating the cooled syngas product stream obtained in step j) in a second gas/liquid separator, thereby obtaining a water-enriched stream and a water-depleted syngas product stream.

8 . An apparatus ( 1 ) suitable for performing the method for producing syngas according to claim 1 , the apparatus at least comprising:
a first heat exchanger for heat exchanging the feed stream against the first syngas containing stream removed from the first RWGS reactor, to obtain a first heated feed stream and a first cooled syngas stream; a first RWGS reactor to obtain a first syngas containing stream; a first gas/liquid separator for separating the first cooled syngas stream to obtain a water-enriched stream and a water-depleted syngas stream; a second heat exchanger for heat exchanging the water-depleted syngas and the second syngas containing stream removed from the second RWGS reactor, to obtain a heated water-depleted syngas stream and a cooled syngas product stream; a second RWGS reactor to obtain a second syngas containing stream.

9 . The apparatus according to claim 8 , wherein at least one of the first and the second RWGS reactors contains two or more catalyst beds with additional intermediate heating between the two or more catalyst beds.

10 . The apparatus according to claim 8 , further comprising a second gas/liquid separator for separating the cooled syngas product stream to obtain a water-enriched stream and a water-depleted syngas product stream.

11 . The method according to claim 1 , wherein the temperature of the first catalytic RWGS reaction in step c) is kept below 600° C.

12 . The method according to claim 1 , wherein the first syngas containing stream comprises at most 0.1 vol. % methane.

13 . The method according to claim 1 , wherein the temperature of the second catalytic RWGS reaction in step h) is kept below 700° C.

Assignees

• Shell Oil Co

Inventors

• Schoonebeek Ronald Jan
• Bos Alouisius Nicolaas Renée
• Unruh Dominik Johannes Michael
• Van Der Sloot Dennis Patrick

Classifications

• C01B3/02 Primary

  Production of hydrogen; Production of gaseous mixtures containing hydrogen · CPC title

• C01B32/40

  Carbon monoxide · CPC title

• C01B2203/0288

  containing two CO-shift steps · CPC title

• C01B2203/0495

  the impurity being water · CPC title

• C01B2203/1205

  Composition of the feed · CPC title