Electrolytic copper foil and electrode and lithium-ion cell comprising the same

Patent metadata

Field	Value
Publication number	US-2023420688-A1
Application number	US-202217940425-A
Country	US
Kind code	A1
Filing date	Sep 8, 2022
Priority date	Jun 28, 2022
Publication date	Dec 28, 2023
Grant date	—

Abstract

Provided are an electrolytic copper foil, an electrode and a lithium-ion cell comprising the same. The electrolytic copper foil has a first surface and a second surface opposite the first surface. An absolute difference of the FWHM of the characteristic peaks of (111) planes of the first surface and the second surface analyzed by GIXRD is less than 0.14, the first and the second surfaces each have a nanoindentation hardness of 0.3 GPa to 3.0 GPa, and the yield strength of the electrolytic copper foil is more than 230 MPa. By controlling the absolute difference of the FWHM of the characteristic peaks of (111) plane of these two surfaces, the nanoindentation hardness of these two surfaces and the yield strength, the electrolytic copper foil can have improved tolerance to the repeated charging and discharging and reduced warpage, thereby improving the yield rate and value of the lithium-ion cell.

First claim

What is claimed is:

1 . An electrolytic copper foil, comprising a first surface and a second surface opposite the first surface, wherein an absolute difference of a full width at half maximum (FWHM) of a characteristic peak of (111) plane of the first surface and an FWHM of a characteristic peak of (111) plane of the second surface analyzed by grazing incidence X-ray diffraction (GIXRD) is less than 0.14, the first surface and the second surface each have a nanoindentation hardness more than or equal to 0.3 GPa and less than or equal to 3.0 GPa, and a yield strength of the electrolytic copper foil is more than 230 MPa.

2 . The electrolytic copper foil as claimed in claim 1 , wherein the FWHM of the characteristic peak of (111) plane of the first surface and the FWHM of the characteristic peak of (111) plane of the second surface are each independently 0.10 to 0.38.

3 . The electrolytic copper foil as claimed in claim 1 , wherein the FWHM of the characteristic peak of (111) plane of the first surface and the FWHM of the characteristic peak of (111) plane of the second surface are each independently 0.13 to 0.38.

4 . The electrolytic copper foil as claimed in claim 1 , wherein an absolute difference of the nanoindentation hardness of the first surface and the nanoindentation hardness of the second surface of the electrolytic copper foil is 1.0 GPa or less.

5 . The electrolytic copper foil as claimed in claim 2 , wherein an absolute difference of the nanoindentation hardness of the first surface and the nanoindentation hardness of the second surface of the electrolytic copper foil is 1.0 GPa or less.

6 . The electrolytic copper foil as claimed in claim 3 , wherein an absolute difference of the nanoindentation hardness of the first surface and the nanoindentation hardness of the second surface of the electrolytic copper foil is 1.0 GPa or less.

7 . The electrolytic copper foil as claimed in claim 1 , wherein the absolute difference of the FWHM of the characteristic peak of (111) plane of the first surface and the FWHM of the characteristic peak of (111) plane of the second surface is 0.135 or less.

8 . The electrolytic copper foil as claimed in claim 7 , wherein the absolute difference of the FWHM of the characteristic peak of (111) plane of the first surface and the FWHM of the characteristic peak of (111) plane of the second surface is more than or equal to 0.010 and less than or equal to 0.135.

9 . The electrolytic copper foil as claimed in claim 1 , wherein the yield strength of the electrolytic copper foil is more than or equal to 240 MPa.

10 . The electrolytic copper foil as claimed in claim 2 , wherein the yield strength of the electrolytic copper foil is more than or equal to 240 MPa.

11 . The electrolytic copper foil as claimed in claim 3 , wherein the yield strength of the electrolytic copper foil is more than or equal to 240 MPa.

12 . The electrolytic copper foil as claimed in claim 4 , wherein the yield strength of the electrolytic copper foil is more than or equal to 240 MPa.

13 . The electrolytic copper foil as claimed in claim 5 , wherein the yield strength of the electrolytic copper foil is more than or equal to 240 MPa.

14 . The electrolytic copper foil as claimed in claim 6 , wherein the yield strength of the electrolytic copper foil is more than or equal to 240 MPa.

15 . The electrolytic copper foil as claimed in claim 7 , wherein the yield strength of the electrolytic copper foil is more than or equal to 240 MPa.

16 . The electrolytic copper foil as claimed in claim 8 , wherein the yield strength of the electrolytic copper foil is more than or equal to 240 MPa.

17 . The electrolytic copper foil as claimed in claim 1 , wherein the yield strength of the electrolytic copper foil is more than or equal to 240 MPa and less than or equal to 500 MPa.

18 . The electrolytic copper foil as claimed in claim 4 , wherein the yield strength of the electrolytic copper foil is more than or equal to 240 MPa and less than or equal to 500 MPa.

19 . An electrode of a lithium-ion cell, comprising the electrolytic copper foil as claimed in claim 1 .

20 . A lithium-ion cell, comprising the electrode as claimed in claim 9 .

Assignees

• Chang Chun Petrochemical Co Ltd

Inventors

• Chuang Ting-Mu
• Lin Sung-Shiuan
• Lai Yao-Sheng
• Chou Jui-Chang

Classifications

• H01M4/661 Primary

  Metal or alloys, e.g. alloy coatings (H01M4/669 take precedence) · CPC title

• H01M2004/021

  Physical characteristics, e.g. porosity, surface area · CPC title

• H01M10/0525

  Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries · CPC title

• Y02E60/10

  Energy storage using batteries · CPC title

• H01M10/052

  Li-accumulators · CPC title