Method for producing coagulant aluminium salts

Patent metadata

Field	Value
Publication number	US-2023416104-A1
Application number	US-202118036987-A
Country	US
Kind code	A1
Filing date	Nov 25, 2021
Priority date	Nov 26, 2020
Publication date	Dec 28, 2023
Grant date	—

Abstract

The invention relates to a method for producing coagulant aluminium salts. Raw material comprising at least one aluminium oxide compound is mixed with a process acid or a base to form a reaction mixture, which is heated to a reaction temperature of at least 100° C. at a reaction pressure. The aluminium oxide compound is allowed to react with the process acid or the base. The aluminium oxide compound is selected from a group consisting of amorphous aluminium oxide, γ-aluminium oxide, η-aluminium oxide, χ-aluminium oxide, or any of their mixtures. The reaction pressure is at least 2 bar(g).

First claim

1 . A method for producing a coagulant aluminium salt, the method comprising
obtaining raw material comprising at least one aluminium oxide compound, mixing the raw material comprising the at least one aluminium oxide compound with a process acid or a base to form a reaction mixture, heating the reaction mixture to a reaction temperature of at least 100° C. at a reaction pressure, maintaining the reaction mixture at the reaction temperature and reaction pressure for a reaction time, and allowing the at least one aluminium oxide compound to react with the process acid or the base, and cooling the reaction mixture,
wherein the at least one aluminium oxide compound is selected from a group consisting of amorphous aluminium oxide, γ-aluminium oxide, η-aluminium oxide, χ-aluminium oxide, and any of their mixtures and wherein the reaction pressure is at least 2 bar(g).

2 . The method according to claim 1 , wherein the raw material comprising the at least one aluminium oxide compound is mixed with a process acid, wherein the reaction mixture has a pH, which is preferably lower than 2, more preferably lower than 1.

3 . The method according to claim 1 , wherein the process acid is selected from hydrogen chloride (HCl), sulfuric acid (H 2 SO 4 ), nitric acid (HNO 3 ), or a combination thereof.

4 . The method according to claim 1 , wherein the raw material comprising the at least one aluminium oxide compound is mixed with a base selected from sodium hydroxide (NaOH), potassium hydroxide (KOH), lithium hydroxide (LiOH), or any combination thereof, wherein the reaction mixture preferably has a pH higher than 10, more preferably higher than 12.

5 . The method according to claim 1 , wherein the reaction mixture has an aluminium concentration of at least 1 weight-%, preferably at least 3 weight-%, more preferably at least 4.5 weight-%, of the total weight of the reaction mixture.

6 . The method according to claim 1 , wherein the reaction mixture is heated to the reaction temperature of at least 120° C., preferably at least 140° C., more preferably at least 150° C.

7 . The method according to claim 1 , wherein the reaction pressure is at least 2.3 bar(g), preferably at least 2.5 bar(g).

8 . The method according to claim 7 , wherein the reaction pressure is in a range of 2-5 bar(g), preferably 2.3-4.8 bar(g), more preferably 2.5-4.5 bar(g).

9 . The method according to claim 1 , wherein the reaction time is in a range of 0.5-5 hours, preferably 1-4 hours, more preferably 1-2 hours.

10 . The method according to claim 1 , wherein the amount of undissolved material after the reaction of the aluminium oxide compound with the process acid or the base is less than 5 weight-%, preferably less than 3 weight-%, more preferably less than 1 weight-%, even more preferably less than 0.5 weight-%.

11 . The method according to claim 1 , wherein the raw material comprising the at least one aluminium oxide compound originates from an aluminium-containing material heat-treated at a temperature lower than 750° C., preferably lower than 450° C., more preferably lower than 300° C.

12 . The method according to claim 11 , wherein the aluminium-containing material originates from a mineral selected from gibbsite, bayerite, boehmite, diaspore, or any combination thereof.

13 . The method according to claim 1 , wherein the raw material comprising the at least one aluminium oxide compound is a by-product from an industrial aluminium oxide production process, such as a production of aluminium oxide desiccant, aluminium oxide catalyst, or aluminium oxide adsorbent.

14 . (canceled)

Assignees

• Kemira Oyj

Inventors

• Honkanen Tapio
• Strickland Forrest
• Penttinen Matias
• Azarnoush Fazlollah

Classifications

• C01F7/743 Primary

  Preparation from silicoaluminious materials, e.g. clays or bauxite · CPC title

• C01F7/66

  Nitrates, with or without other cations besides aluminium · CPC title

• C01F7/56

  Chlorides (containing fluorine C01F7/52) · CPC title