Concerted mineral carbonation and selective leaching of laterites

Patent metadata

Field	Value
Publication number	US-2023407436-A1
Application number	US-202118249144-A
Country	US
Kind code	A1
Filing date	Oct 14, 2021
Priority date	Oct 14, 2020
Publication date	Dec 21, 2023
Grant date	—

Abstract

Processes are provided for treating mineralized silicates by selective leaching of Ni and Co values carried out in concert with sequestration of gaseous CO2 as mineral carbonates. These processes may be applied to extract Ni and Co values from disparate laterite ores.

First claim

1 . A process for extracting values from a mineralized silicate material, wherein the mineralized silicate material comprises a total amount of each of a mineralized nickel, a mineralized cobalt, a mineralized iron and a mineralized magnesium, wherein the process comprises:
a) heating the mineralized silicate material in an aqueous H 2 CO 3(a) /HCO 3 − buffered extraction medium in the presence of a gaseous carbon dioxide supply and a selective Ni/Co ligand; b) providing extraction conditions to:
i) selectively leach nickel and cobalt from the silicate material into the extraction medium in the form of complexes with the selective Ni/Co ligand, to form solubilized Ni complexes and solubilized Co complexes; and,
ii) react magnesium and iron in the silicate material with dissolved carbon dioxide provided by the carbon dioxide supply to form a solid carbonate product comprising a solid magnesium carbonate and a solid iron carbonate; and,
c) in a solid liquid separation, separating the solid magnesium carbonate and the solid iron carbonate from the solubilized Ni complexes and the solubilized Co complexes, to form a Ni/Co pregnant leach solution; wherein providing extraction conditions comprises: providing the Ni/Co ligand in a molar ratio to the total amount of mineralized Ni in the mineralized silicate material of greater than 1:1, so as to extract at least 50%, 60%, 70% 80% or 90% of the total amount of mineralized Ni and Co in the mineralized silicate material into the Ni/Co pregnant leach solution, and so that less than 20%, 15% or 10% of the total amount of the mineralized Fe and Mg in the mineralized silicate material is leached into the Ni/Co pregnant leach solution.

2 . The process of claim 1 , wherein the mineralized silicate material comprises a non-hydrated nickel-containing olivine material.

3 . The process of claim 1 , further comprising calcining a hydrated mineral feedstock to provide the mineralized silicate material.

4 . The process of claim 3 , wherein the hydrated mineral feedstock is a laterite material, optionally a lateritic nickel ore.

5 . The process of claim 4 , wherein the laterite material comprises a saprolite-type ore and/or a limonite-type ore.

6 . The process of claim 3 , wherein the hydrated mineral feedstock comprises a serpentine material of formula (Fe, Mg, Ni, Co) 3 Si 2 O 5 (OH) 4 ) and/or a montmorillonite material of formula (Na, Ca)(Fe, Mg, Ni, Co) 2 (Si, Al) 4 O 10 (OH) 2 nH 2 O).

7 . The process of claim 3 , wherein calcining is carried out at a calcining temperature of 600° C.-800° C.

8 . The process of claim 3 , wherein calcining is in the presence of a calcining atmosphere comprising a CO—CO 2 gas, a CO—N 2 gas or a CO—CO 2 —N 2 gas.

9 . The process of claim 3 , wherein the hydrated mineral feedstock comprises goethite and/or hematite and/or magnetite, and calcination is carried in a reductive calcining atmosphere so as to convert at least some of the goethite and/or hematite and/or magnetite materials to wustite materials.

10 . The process of claim 9 , wherein the reductive calcining atmosphere comprises CO in an amount of from 3˜15 (v/v) % in a CO—N 2 calcining gas or 10˜40 (v/v) % in a CO—CO 2 calcining gas mixtures.

11 . The process of claim 1 , wherein the selective Ni/Co ligand is a Ni and Co chelating agent.

12 . The process of claim 1 , wherein the selective Ni/Co ligand is trisodium nitrilotriacetate (NTA) or ethylenediaminetetraacetic acid (EDTA).

13 . The process of claim 1 , wherein the molar ratio of the selective Ni/Co ligand to the total amount of mineralized Ni in the mineralized silicate material is less than or equal to 50:1, or 40:1, 36:1 or 12:1.

14 . The process of claim 1 , wherein the solid magnesium carbonate comprises magnesite and/or the solid iron carbonate comprises siderite.

15 . The process of claim 1 , wherein the mineralized silicate material is present in the aqueous H 2 CO 3(a) /HCO 3 − buffered extraction medium at a pulp density of 0.1-50 (wt) %, or 0.5-30 (wt) % or 0.5-5 (wt) %.

16 . The process of claim 1 , wherein the mineralized silicate material has a P 80 =5-150 μm, or P 80 =10-100 μm, or P 80 =15-50 μm, or P 80 =20-30 μm

17 . The process of claim 1 , wherein the dissolved CO 2 from the carbon dioxide supply is reacted to form the solid carbonate product so that at least 50, 100, 150, 200 or 250 kg CO 2 are consumed per tonne of mineralized silicate material.

18 . The process of claim 1 , wherein the mineral carbonation (MC) efficiency is greater than 10%, 20%, 30%, 40%, 50%, 60% or 70%. wherein MC efficiency is the amount of CO 2 in the CO 2 gas supply that forms the carbonate product as a percentage of the theoretical maximum amount of CO 2 that the silicate material could react with to form carbonates of iron, magnesium, and calcium.

19 . The process of claim 1 , further comprising recovering Ni and Co values from the Ni/Co pregnant leach solution to form a Ni/Co depleted barren solution, and recirculating the Ni/Co depleted barren solution to the aqueous buffered extraction medium.

Assignees

• Univ British Columbia

Inventors

• Dreisinger David
• Wang Fei

Classifications

• C22B23/0461 Primary

  by chemical methods · CPC title

• C22B23/005

  Preliminary treatment of ores, e.g. by roasting or by the Krupp-Renn process · CPC title

• C22B3/44

  by chemical processes (treatment or purification of solutions by liquid-liquid extraction C22B3/26, by ion-exchange extraction C22B3/42) · CPC title

• C22B3/22

  by physical processes, e.g. by filtration, by magnetic means {, or by thermal decomposition} (treatment or purification of solutions by liquid-liquid extraction C22B3/26) · CPC title

• C01F5/24

  Magnesium carbonates · CPC title