Cobalt-Based Single-Atom Dehydrogenation Catalysts Having High Selectivity and Regenerability and Method for Producing Corresponding Olefins from Paraffins Using the Same
US-2024367157-A1 · Nov 7, 2024 · US
US2023381749A1 · US · A1
| Field | Value |
|---|---|
| Publication number | US-2023381749-A1 |
| Application number | US-202118032990-A |
| Country | US |
| Kind code | A1 |
| Filing date | Nov 1, 2021 |
| Priority date | Nov 3, 2020 |
| Publication date | Nov 30, 2023 |
| Grant date | — |
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There is provided a dehydrogenation catalyst for producing olefins from alkane gases, in which a metal active component is supported on an alumina carrier containing boron. There is provided a method for preparing a dehydrogenation catalyst for producing olefins from alkane gases. The method includes impregnating alumina in a boron-containing solution and calcining it to provide a boron-alumina carrier; providing a solution containing the metal active component; impregnating the boron-alumina solution in the solution containing the metal active component and drying it; and calcining the boron-alumina carrier on which the metal active component is supported at 700° C. to 900° C.
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1 . A dehydrogenation catalyst for producing olefins from alkane gases, in which a metal active component is supported on an alumina carrier containing boron. 2 . The dehydrogenation catalyst of claim 1 , wherein the boron is supported in an amount of 0.1 to 2 wt % based on the alumina. 3 . The dehydrogenation catalyst of claim 2 , wherein the boron is supported in an amount of 0.5 to 2 wt % based on the carrier. 4 . The dehydrogenation catalyst of claim 1 , wherein the metal active component essentially includes cobalt. 5 . The dehydrogenation catalyst of claim 4 , wherein the cobalt is supported in an amount of 1 to 5 wt % based on the alumina. 6 . The dehydrogenation catalyst of claim 4 , wherein the metal active component further includes platinum. 7 . The dehydrogenation catalyst of claim 6 , wherein the platinum is supported in an amount of 0.001 to 0.05 wt % based on the alumina. 8 . A method for preparing a dehydrogenation catalyst for producing olefins from alkane gases, the method comprising the steps of: impregnating alumina in a boron-containing solution and calcining it to provide a boron-alumina carrier; providing a solution containing the metal active component; impregnating the boron-alumina solution in the solution containing the metal active component and drying it; and calcining the boron-alumina carrier on which the metal active component is supported at 700° C. to 900° C. 9 . The method of claim 8 , wherein the boron-alumina carrier is calcined at 400 to 600° C. 10 . The method of claim 8 , wherein the boron is supported in an amount of 0.1 to 2 wt % based on the alumina. 11 . The method of claim 10 , wherein the boron is supported in an amount of 0.5 to 2 wt % based on the carrier. 12 . The method of claim 8 , wherein the metal active component essentially includes cobalt. 13 . The method of claim 12 , wherein the cobalt is supported in an amount of 1 to 5 wt % based on the alumina. 14 . The method of claim 12 , wherein the metal active component further includes platinum. 15 . The method of claim 14 , wherein the platinum is supported in an amount of 0.001 to 0.05 wt % based on the alumina. 16 . A continuous reaction-regeneration olefin production method including the catalyst of claim 1 . 17 . The continuous reaction-regeneration olefin production method of claim 16 , wherein the reaction temperature is 560 to 640° C. 18 . The continuous reaction-regeneration olefin production method of claim 16 , wherein alkane, which is a raw material in the olefin production method, has a flow rate (weight hour space velocity) of 4 to 16 h −1 .
characterised by their crystalline properties, e.g. semi-crystalline (catalysts comprising carbon B01J21/18; molecular sieves B01J29/00) · CPC title
characterised by their physical properties · CPC title
Cobalt · CPC title
Operations & Transport · mapped topic
Operations & Transport · mapped topic
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