Non-aqueous electrolyte for lithium secondary battery and lithium secondary battery comprising same

Patent metadata

Field	Value
Publication number	US-2023361345-A1
Application number	US-202118044366-A
Country	US
Kind code	A1
Filing date	Oct 8, 2021
Priority date	Nov 6, 2020
Publication date	Nov 9, 2023
Grant date	—

Abstract

Provided are a non-aqueous electrolyte for a lithium secondary battery and a lithium secondary battery including same, in which the non-aqueous electrolyte comprises: a non-aqueous organic solvent; a lithium salt; and a first additive represented by Chemical Formula 1 and a second additive represented by Chemical Formula 2 in a ratio of 0.5:1 to 10:1 by weight.

First claim

1 . A non-aqueous electrolyte for a lithium secondary battery, comprising:
a non-aqueous organic solvent; a lithium salt; and a first additive represented by Chemical Formula 1 and a second additive represented by Chemical Formula 2, wherein a mixing ratio of the first additive and the second additive is 0.5:1 to 10:1 by weight:

(in Chemical Formula 1,
R 1 to R 8 are each independently a hydrogen atom, a substituted or unsubstituted C1 to C30 alkyl group, a substituted or unsubstituted C2 to C30 alkenyl group, a substituted or unsubstituted C2 to C30 alkynyl group, a substituted or unsubstituted C3 to C30 cycloalkyl group, a substituted or unsubstituted C3 to C30 cycloalkenyl group, a substituted or unsubstituted C3 to C30 cycloalkynyl group, or a substituted or unsubstituted C6 to C30 aryl group;)

(in Chemical Formula 2, A is a substituted or unsubstituted aliphatic a chain or (—C 2 H 4 —O—C 2 H 4 —) n , and n is an integer of 1 to 10.)

2 . The non-aqueous electrolyte for a lithium secondary battery of claim 1 , wherein the R 1 to R 8 are each independently a hydrogen atom, a substituted or unsubstituted C1 to C10 alkyl group, a substituted or unsubstituted C2 to C10 alkenyl group, a substituted or unsubstituted C2 to C10 alkynyl group, a substituted or unsubstituted C3 to C10 cycloalkyl group, a substituted or unsubstituted C3 to C10 cycloalkenyl group, a substituted or unsubstituted C3 to C10 cycloalkynyl group, or a substituted or unsubstituted C6 to C10 aryl group.

3 . The non-aqueous electrolyte for a lithium secondary battery of claim 1 , wherein the mixing ratio of the first additive and the second additive is 0.5:1 to 5:1 by weight.

4 . The non-aqueous electrolyte for a lithium secondary battery of claim 1 , wherein an amount the first additive is 0.25 wt % or more and less than 10 wt % when amounts of the non-aqueous organic solvent and the lithium salt are to be 100 wt %.

5 . The non-aqueous electrolyte for a lithium secondary battery of claim 4 , wherein an amount of the first additive is 0.5 wt % to 5 wt %, when amounts of the non-aqueous organic solvent and the lithium salt are to be 100 wt %.

6 . The non-aqueous electrolyte for a lithium secondary battery of claim 1 , wherein an amount of the second additive is 0.1 wt % or more and less than 10 wt %, when amounts of the non-aqueous organic solvent and the lithium salt is to be 100 wt %.

7 . The non-aqueous electrolyte for a lithium secondary battery of claim 6 , wherein an amount of the second additive may be 0.1 wt % to 5 wt %, when amounts of the non-aqueous organic solvent and the lithium salt is to be 100 wt %.

8 . The non-aqueous electrolyte for a lithium secondary battery of claim 1 , wherein the non-aqueous organic solvent includes a propionate-based solvent.

9 . The non-aqueous electrolyte for a lithium secondary battery of claim 8 , wherein the propionate-based solvent is methyl propionate, ethyl propionate, propyl propionate, or combinations thereof.

10 . The non-aqueous electrolyte for a lithium secondary battery of claim 8 , wherein an amount of the propionate-based solvent is 30 volume % to 80 volume % based on the total volume of the non-aqueous organic solvent.

11 . A lithium secondary battery, comprising:
a non-aqueous electrolyte of claim 1 ; a positive electrode; and a negative electrode. amount exhibited lower reduction effects in thickness increase ratio at high temperature storage, than Examples. While this invention has been described in connection with what is presently considered to be practical example embodiments, it is to be understood that the invention is not limited to the disclosed embodiments, but, on the contrary, is intended to cover various modifications and equivalent arrangements included within the spirit and scope of the appended claims. Therefore, the aforementioned embodiments should be understood to be examples but not limiting the present invention in any way.

Assignees

• Samsung Sdi Co Ltd

Inventors

• Park Hyejin
• Koh Sujeong
• Kim Dahyun
• Kim Myunghoon
• Kim Sanghyung
• Kim Sanghoon
• Oh Seungryong

Classifications

• H01M10/0567 Primary

  characterised by the additives · CPC title

• H01M10/0569

  characterised by the solvents · CPC title

• H01M10/052

  Li-accumulators · CPC title

• H01M2300/0042

  Four or more solvents · CPC title

• Y02E60/10

  Energy storage using batteries · CPC title