High purity iron-bearing materials and systems and methods of production thereof

Patent metadata

Field	Value
Publication number	US-2023339770-A1
Application number	US-202318306812-A
Country	US
Kind code	A1
Filing date	Apr 25, 2023
Priority date	Apr 25, 2022
Publication date	Oct 26, 2023
Grant date	—

Abstract

The present disclosure is directed to high-purity iron materials and systems and methods of producing such high-purity iron materials based on cost-effective transformation of low-cost iron feedstocks. In general, the methods of production using the systems described herein may include acid leaching low-purity iron ores to create an iron-rich acid solution, which may be purified to remove residual soluble impurities and hydrolyzed to produce high purity iron oxide powder. The high purity iron oxide powder may be reduced to form high purity iron metal suitable for a variety of end-uses, including use in batteries.

First claim

What is claimed is:

1 . An iron metal having an apparent density of less than 3 g/cc and silica content less than 0.5 wt %.

2 . An iron oxide material having silica content less than 0.5 wt %.

3 . A method of producing iron-containing material, the method comprising:
direct reducing an iron oxide material having silica content less than 0.5 wt % into an iron material having an apparent density of less than 3 g/cc and silica content less than 0.5 wt %.

4 . The method of claim 3 , wherein the iron oxide material is a powder.

5 . The method of claim 3 , further comprising hydrolyzing a solution of iron in an acidic lixiviant to form the iron oxide material.

6 . The method of claim 5 , wherein hydrolyzing the solution to form the iron oxide material includes spray roasting the solution to form the iron oxide material.

7 . The method of claim 5 , wherein hydrolyzing the solution to form the iron oxide material includes fluidized bed hydrolysis of the solution to form the iron oxide material.

8 . The method of claim 5 , wherein hydrolyzing the solution includes adding steam.

9 . The method of claim 5 , wherein hydrolyzing the solution includes adding water to the solution to maintain a concentration of the iron in the solution below a saturation level of iron in the acidic lixiviant.

10 . The method of claim 5 , further comprising dissolving an iron-bearing material in the acidic lixiviant to form the solution of iron in the acidic lixiviant.

11 . The method of claim 10 , wherein dissolving the iron-bearing material in the acidic lixiviant includes recycling the acidic lixiviant separated from the iron in hydrolysis of the solution of iron in the acidic lixiviant.

12 . The method of claim 10 , wherein dissolving the iron-bearing material includes heating the solution to at least 40° C.

13 . The method of claim 10 , wherein dissolving the iron-bearing material includes directing energy into the solution, wherein the energy is one or more of ultrasonic, mechanical microwave irradiation, or UV light irradiation.

14 . The method of claim 10 , wherein the iron-bearing material is a feedstock of particles having an average particle size of 20-500 microns.

15 . The method of claim 10 , wherein the acidic lixiviant includes hydrochloric acid.

16 . The method of claim 10 , wherein the iron-bearing material includes one or more of iron ore, scrap metal, mining tailings, mineral processing tailings, end-of-life battery electrodes, or end-of-life batteries.

17 . The method of claim 10 , further comprising removing at least a portion of one or more soluble impurities from the solution of iron in the acidic lixiviant, wherein the solution of iron in the acidic lixiviant is hydrolyzed with the one or more soluble impurities removed from the solution.

18 . The method of claim 17 , wherein the soluble impurities include one or more of silicon, aluminum, calcium, magnesium, chromium, titanium, manganese, vanadium, or copper.

19 . The method of claim 5 , further comprising fabricating a component of a battery, wherein the component includes the iron material.

20 . The method of claim 5 , further comprising fabricating steel including the iron material.

Assignees

• Form Energy Inc

Inventors

• Woodford William Henry
• Conry Thomas
• Luyima Alex

Classifications

• C22B3/10

  Hydrochloric acid {, other halogenated acids or salts thereof} · CPC title

• C23G1/36

  Regeneration of waste pickling liquors · CPC title

• C01G49/02 Primary

  Oxides; Hydroxides {(C01G49/0018 takes precedence)} · CPC title

• C21B13/14

  Multi-stage processes {processes carried out in different vessels or furnaces} · CPC title

• C01P2006/80

  Compositional purity · CPC title