Hydrogen peroxide production device and use thereof

Patent metadata

Field	Value
Publication number	US-2023312376-A1
Application number	US-202217837016-A
Country	US
Kind code	A1
Filing date	Jun 9, 2022
Priority date	Mar 31, 2022
Publication date	Oct 5, 2023
Grant date	—

Abstract

A gas diffusion electrode includes a carbon fiber tube, a support layer, and a catalyst layer. The carbon fiber tube is straight and functions as a substrate. The support layer includes a carbon black-polytetrafluoroethylene (PTFE) coating, and is disposed on the substrate. The catalyst layer includes carbon black, anhydrous ethanol, and PTFE, and is disposed on the support layer. The gas diffusion electrode has a diameter of 3-20 mm and a length of 50-500 mm.

First claim

The invention claimed is:

1 . A gas diffusion electrode, comprising a carbon fiber tube, a support layer, and a catalyst layer; wherein the carbon fiber tube is straight and functions as a substrate; the support layer comprises a carbon black-polytetrafluoroethylene (PTFE) coating, and is disposed on the substrate; the catalyst layer comprises carbon black, anhydrous ethanol, and PTFE, and is disposed on the support layer; and the gas diffusion electrode has a diameter of 3-20 mm and a length of 50-500 mm.

2 . A hydrogen peroxide production device, comprising a plurality of hydrogen peroxide production units connected to each other; wherein each hydrogen peroxide production unit comprises a cathode, an insulating sleeve, and an anode from inside to outside; and the cathode is the gas diffusion electrode of claim 1 .

3 . The device of claim 2 , wherein the anode is a titanium substrate comprising an iridium dioxide coating.

4 . The device of claim 3 , wherein a distance between the anode and the cathode is 1-30 mm.

5 . The device of claim 4 , wherein the insulating sleeve has a thickness of 1-30 mm, and comprises an organic silica, an organic plastic, or an inorganic ceramic material.

6 . The device of claim 2 , further comprising a power supply, an electro-Fenton reactor, an air compressor, a water pump, a tank, an air pipe, and a conduit; wherein the plurality of hydrogen peroxide production units are connected to each other and disposed in the electro-Fenton reactor; the electro-Fenton reactor comprises a top part and a bottom part; a water inlet is disposed on the bottom part and an overflow outlet is disposed on the top part; one end of the air pipe is connected to the electro-Fenton reactor; another end of the air pipe is connected to the air compressor; one end of the water pump is connected to the water inlet; another end of the water pump is connected to the tank; and the tank is connected to the overflow outlet through the conduit.

7 . A method of preparing hydrogen peroxide using the hydrogen peroxide production device of claim 6 , the method comprising: turning on the air compressor to aerate the electro-Fenton reactor; turning on the water pump to pump a sodium sulfate solution into the electro-Fenton reactor until the sodium sulfate solution covers the plurality of hydrogen peroxide production units; controlling the current of the hydrogen peroxide production device, so that a solid, liquid and gas three-phase interface is formed on the catalyst layer of the gas diffusion electrode, to produce hydrogen peroxide.

8 . The method of claim 7 , wherein the hydrogen peroxide production device is operated at a current density of 10-200 mA/cm 2 and a voltage of 2.0-4.0 V; and the air compressor offers an air flow rate of 10-150 L/min.

9 . The method of claim 8 , wherein a concentration of the sodium sulfate solution is 0.05-0.15 M.

10 . A method for wastewater treatment using the hydrogen peroxide production device of claim 6 , the method comprising:
1) turning on the air compressor to aerate the electro-Fenton reactor; preparing a wastewater sample containing an organic pollutant, sodium sulfate anhydrous, and Fe 2+ ; turning on the water pump to pump the wastewater sample into the electro-Fenton reactor until the wastewater sample covers the plurality of hydrogen peroxide production units; controlling the current of the hydrogen peroxide production device, so that a solid, liquid and gas three-phase interface is formed on the catalyst layer of the gas diffusion electrode, to produce hydrogen peroxide; 2) generating hydroxyl radicals from hydrogen peroxide to mineralize the organic pollutant; and discharging an effluent into the tank via the overflow outlet; and 3) recycling the effluent produced in 2) to the electro-Fenton reactor through a circulation process.

11 . The method of claim 10 , wherein in 1), the hydrogen peroxide production device is operated at a current density of 10-200 mA/cm 2 and a voltage of 2.0-4.0 V; and the air compressor offers an air flow rate of 10-150 L/min.

Assignees

• Univ Nanjing Sci & Tech

Inventors

• Han Weiqing
• Wei Kajia
• Shi Kaiqiang
• Liu Xiaodong
• Sun Xiuyun
• Li Jiansheng
• Shen Jinyou

Classifications

• C02F1/46109 Primary

  Electrodes · CPC title

• C25B1/30

  Peroxides · CPC title

• C25B11/032

  Gas diffusion electrodes · CPC title

• C25B11/065

  Carbon · CPC title

• C02F1/4672

  by electrooxydation · CPC title