Method for producing polytetrafluoroethylene and composition containing polytetrafluoroethylene

Patent metadata

Field	Value
Publication number	US-2023303731-A1
Application number	US-202318198340-A
Country	US
Kind code	A1
Filing date	May 17, 2023
Priority date	Nov 19, 2020
Publication date	Sep 28, 2023
Grant date	—

Abstract

A method for producing a polytetrafluoroethylene, which includes polymerizing tetrafluoroethylene in an aqueous medium in the presence of a polymer (1) to obtain the polytetrafluoroethylene, wherein the polymer (1) is a polymer of a monomer (1) represented by the general formula (1): CF 2 ═CF(—O—Rf-A), has a weight average molecular weight of 1.4×10 4 or more, wherein a content of a polymerization unit (1) based on the monomer (1) is 40 mol % or more based on all polymerization units constituting the polymer (1), and a content of a dimer and a trimer of the monomer (1) is 1.0% by mass or less based on the polymer (1).

First claim

What is claimed is:

1 . A method for producing a polytetrafluoroethylene, comprising:
polymerizing tetrafluoroethylene in an aqueous medium in the presence of a polymer (1) to obtain the polytetrafluoroethylene, wherein the polymer (1) is a polymer of a monomer (1) represented by the general formula (1), and has a weight average molecular weight of 1.4×10 4 or more, wherein a content of a polymerization unit (1) based on the monomer (1) is 40 mol % or more based on all polymerization units constituting the polymer (1), and a content of a dimer and a trimer of the monomer (1) is 1.0% by mass or less based on the polymer (1),
CF 2 ═CF(—O—Rf-A)  (1)

wherein Rf is a fluorine-containing alkylene group having 1 to 40 carbon atoms or a fluorine-containing alkylene group having 2 to 100 carbon atoms and having an ether bond or a keto group; and A is —COOM, —SO 3 M, —OSO 3 M, or —C(CF 3 ) 2 CM, wherein M is H, a metal atom, NR 7 4 , imidazolium optionally having a substituent, pyridinium optionally having a substituent, or phosphonium optionally having a substituent, and R 7 is H or an organic group.

2 . The production method according to claim 1 , wherein A is —COOM.

3 . The production method according to claim 1 , wherein a modifying monomer is further polymerized.

4 . The production method according to claim 1 , which comprises:
polymerizing the monomer (1) to obtain a crude composition containing the polymer of the monomer (1); and removing the dimer and the trimer of the monomer (1) contained in the crude composition from the crude composition to obtain the polymer (1) in which the content of the dimer and the trimer of the monomer (1) is 1.0% by mass or less based on the polymer (1).

5 . A composition comprising a polytetrafluoroethylene having an aspect ratio of a primary particle of less than 2.00 and a polymer (1) of a monomer (1) represented by the general formula (1),
wherein the polymer (1) has a weight average molecular weight of 1.4×10 4 or more; and a content of a polymerization unit (1) based on the monomer (1) is 40 mol % or more based on all polymerization units constituting the polymer (1),
CF 2 ═CF(—O—Rf-A)  (1)

wherein Rf is a fluorine-containing alkylene group having 1 to 40 carbon atoms or a fluorine-containing alkylene group having 2 to 100 carbon atoms and having an ether bond or a keto group; and A is —COOM, —SO 3 M, —OSO 3 M, or —C(CF 3 ) 2 CM, wherein M is H, a metal atom, NR 7 4 , imidazolium optionally having a substituent, pyridinium optionally having a substituent, or phosphonium optionally having a substituent, and R 7 is H or an organic group.

6 . The composition according to claim 5 , wherein A is —COOM.

7 . The composition according to claim 5 , wherein the polytetrafluoroethylene contains tetrafluoroethylene unit and a modifying monomer unit.

8 . The composition according to claim 5 , wherein a content of a dimer and a trimer of the monomer (1) in the polymer (1) is 1.0% by mass or less based on the polymer (1).

9 . A composition comprising a polytetrafluoroethylene having an aspect ratio of a primary particle of less than 2.00 and a polymer (2) of a monomer (2) represented by the general formula (2),
wherein the polymer (2) has a weight average molecular weight of 1.4×10 4 or more; the polymer (2) has an ion-exchange capacity of 2.2 meq/g or more; and a content of a polymerization unit (2) based on the monomer (2) is 40 mol % or more based on all polymerization units constituting the polymer (2),
CX 2 ═CY(—O—Rf-A)  (2)

wherein X is the same or different and is H or F; Y is H, F, an alkyl group, or a fluorine-containing alkyl group; Rf is a fluorine-containing alkylene group having 1 to 40 carbon atoms or a fluorine-containing alkylene group having 2 to 100 carbon atoms and having an ether bond or a keto group; and A is —COOM, —SO 3 M, —OSO 3 M, or —C(CF 3 ) 2 CM, wherein M is H, a metal atom, NR 7 4 , imidazolium optionally having a substituent, pyridinium optionally having a substituent, or phosphonium optionally having a substituent, and R 7 is H or an organic group.

10 . The composition according to claim 9 , wherein A is —COOM.

11 . The composition according to claim 9 , wherein the polytetrafluoroethylene contains tetrafluoroethylene unit and a modifying monomer unit.

12 . The composition according to claim 9 , wherein a content of a dimer and a trimer of the monomer (2) in the polymer (2) is 1.0% by mass or less based on the polymer (2).

Assignees

• Daikin Ind Ltd

Inventors

• Nanba Yoshinori
• Kato Taketo
• Ichikawa Kenji
• Yamanaka Taku

Classifications

• C08F6/22

  Coagulation · CPC title

• C08F6/003

  from polymer solutions, suspensions, dispersions or emulsions without recovery of the polymer therefrom · CPC title

• C08L27/18

  Homopolymers or copolymers or tetrafluoroethene · CPC title

• C08F116/14

  Monomers containing only one unsaturated aliphatic radical · CPC title

• C08F2/26 Primary

  anionic · CPC title