Cement-reduced construction composition

Patent metadata

Field	Value
Publication number	US-2023303446-A1
Application number	US-202118023268-A
Country	US
Kind code	A1
Filing date	Aug 25, 2021
Priority date	Aug 26, 2020
Publication date	Sep 28, 2023
Grant date	—

Abstract

A cement-reduced construction composition comprises a) a cementitious binder comprising one or more calcium silicate mineral phases and one or more calcium aluminate mineral phases, and having a Blaine surface area of at least 3800 cm 2 /g, in an amount of 180 to 400 kg per m 3 of the freshly mixed construction composition; b) a fine material having a Dv90 of less than 200 μm, selected from alkali-activatable binders, rock powders and inorganic pigments, or mixtures thereof, in a total amount of 20 to 200 parts by weight, relative to 100 parts by weight of cementitious binder a); c) optionally, an extraneous aluminate source; d) a sulfate source; and e) a polyol in an amount of 0.3 to 2.5 wt.-%, relative to the amount of cementitious binder a). The composition contains available aluminate, calculated as Al(OH) 4 —, from the calcium aluminate mineral phases plus the optional extraneous aluminate source, per 100 g of cementitious binder a), in a total amount of at least 0.08 mol, if the amount of cementitious binder a) is in the range of 180 to less than 220 kg per m 3 of the freshly mixed composition, at least 0.06 mol, if the amount of cementitious binder a) is in the range of 220 to less than 280 kg per m 3 of the freshly mixed composition, and at least 0.05 mol, if the amount of cementitious binder a) is 280 kg or more per m 3 of the freshly mixed composition; and the molar ratio of total available aluminate to sulfate is 0.4 to 2.0. The construction composition further comprises f) an ettringite formation controller comprising (i) glyoxylic acid, a glyoxylic acid salt and/or a glyoxylic acid derivative; and (ii) at least one of (ii-a) a borate source and (ii-b) a carbonate source, wherein the carbonate source is selected from inorganic carbonates having an aqueous solubility of 0.1 g·L −1 or more, organic carbonates, and mixtures thereof; and g) a co-retarder selected from (g-1) α-hydroxy monocarboxylic acids and salts thereof, (g-2) phosphonic acids and salts thereof, (g-3) polycarboxylic acids and salts thereof, and mixtures thereof. The cement-reduced construction composition is a reduced carbon footprint construction composition and exhibits high early strength, high final strength, sufficient open time, high durability, and reduced shrinkage compared to ordinary Portland cement based mixes. Ingredients of the construction composition are abundantly available.

First claim

1 . A cement-reduced construction composition comprising
a) a cementitious binder comprising one or more calcium silicate mineral phases and one or more calcium aluminate mineral phases, and having a Blaine surface area of at least 3800 cm 2 /g, in an amount of 180 to 400 kg per m 3 of the freshly mixed construction composition; b) a fine material having a Dv90 of less than 200 μm, selected from alkali-activatable binders, rock powders and inorganic pigments, or mixtures thereof, in a total amount of 20 to 200 parts by weight, relative to 100 parts by weight of cementitious binder a); c) optionally, an extraneous aluminate source; d) a sulfate source; and e) a polyol in an amount of 0.3 to 2.5 wt.-%, relative to the amount of cementitious binder a); wherein the composition contains available aluminate, calculated as Al(OH) 4 − , from the calcium aluminate mineral phases plus the optional extraneous aluminate source, per 100 g of cementitious binder a), in a total amount of
at least 0.08 mol, if the amount of cementitious binder a) is in the range of 180 to less than 220 kg per m 3 of the freshly mixed composition,
at least 0.06 mol, if the amount of cementitious binder a) is in the range of 220 to less than 280 kg per m 3 of the freshly mixed composition, and
at least 0.05 mol, if the amount of cementitious binder a) is 280 kg or more per m 3 of the freshly mixed composition;
and the molar ratio of total available aluminate to sulfate is 0.4 to 2.0; the construction composition further comprising f) an ettringite formation controller comprising (i) glyoxylic acid, a glyoxylic acid salt and/or a glyoxylic acid derivative; and (ii) at least one of (ii-a) a borate source and (ii-b) a carbonate source, wherein the carbonate source is selected from inorganic carbonates having an aqueous solubility of 0.1 g·L −1 or more at 25° C., organic carbonates, and mixtures thereof; and g) a co-retarder selected from (g-1) α-hydroxy monocarboxylic acids and salts thereof, (g-2) phosphonic acids and salts thereof, (g-3) polycarboxylic acids and salts thereof, and mixtures thereof.

2 . The composition according to claim 1 , wherein the calcium silicate mineral phases and calcium aluminate mineral phases constitute at least 90 wt.-% of the cementitious binder a), and the calcium silicate mineral phases constitute at least 60 wt.-% of the cementitious binder a).

3 . The composition according to claim 1 , wherein the calcium aluminate mineral phases are selected from C3A, C4AF, and C12A7.

4 . The composition according to claim 1 , wherein the cementitious binder a) is Portland cement.

5 . The composition according to claim 1 , wherein the alkali-activatable binder is selected from latent hydraulic binders and pozzolanic binders.

6 . The composition according to claim 1 , wherein the rock powder is a silicate or carbonate rock powder.

7 . The composition according to claim 1 , wherein the inorganic pigment is selected from iron oxides, titanium dioxide, cobalt-chrome-aluminum-spinels, and chrome(III)-oxides.

8 . The composition according to claim 1 , wherein the fine material has a Dv90 of less than 150 μm.

9 . The composition according to claim 1 , wherein the extraneous aluminate source c) is selected from non-calciferous aluminate sources.

10 . The composition according to claim 1 , wherein the sulfate source d) is a calcium sulfate source.

11 . The composition according to claim 1 , wherein the cementitious binder a) has a Blaine surface area of at least 4500 cm 2 /g.

12 . The composition according to claim 1 , wherein the polyol, in a calcium aluminate precipitation test in which a test solution, obtained by supplementing 400 mL of a 1 wt.-% aqueous solution of the polyol with 20 mL of a 1 mol/L NaOH aqueous solution and 50 mL of a 25 mmol/L NaAlO 2 aqueous solution, is titrated with a 0.5 mol/L CaCl 2 ) aqueous solution at 20° C., inhibits precipitation of calcium aluminate up to a calcium concentration of 75 ppm.

13 . The composition according to claim 12 , wherein the polyol is selected from monosaccharides, oligosaccharides, water-soluble polysaccharides, compounds of general formula (P-I) or dimers or trimers of compounds of general formula (P-I):

wherein X is

wherein
R is —CH 2 OH, —NH 2 ,
n is an integer from 1 to 4,
m is an integer from 1 to 8.

14 . The composition according to claim 1 , wherein the glyoxylic acid derivative is a glyoxylic acid polymer.

15 . The composition according to claim 1 , wherein the glyoxylic acid, glyoxylic acid salt and/or glyoxylic acid derivative (i) is present in a total amount of 0.2 to 2 wt.-%, relative to the amount of cementitious binder a).

16 . The composition according to claim 1 , wherein the inorganic carbonate is selected from potassium carbonate, sodium carbonate, sodium bicarbonate, lithium carbonate and magnesium carbonate; and the organic carbonate is selected from ethylene carbonate, propylene carbonate and glycerol carbonate.

17 . The composition according to claim 1 , wherein the carbonate source (ii-b) is present in an amount of 0.3 to 1 wt.-%, relative to the amount of cementitious binder a).

18 . The composition according to claim 1 , wherein the α-hydroxy monocarboxylic acid salt is sodium gluconate.

19 . The composition according to claim 1 , wherein the polycarboxylic acid or a salt thereof (g-3) has a milliequivalent number of carboxyl groups of 3.0 meq/g or higher assuming all the carboxyl groups to be in unneutralized form.

20 . The composition according to claim 1 , wherein the polycarboxylic acid is selected from phosphonoalkyl carboxylic acids, amino carboxylic acids, and polymeric carboxylic acids.

21 . The composition according to claim 1 , wherein the composition additionally comprises
h) at least one aggregate.

22 . The composition according to claim 1 , additionally comprising a dispersant.

23 . The composition according to claim 22 , wherein the dispersant is selected from the group of
comb polymers having a carbon-containing backbone to which are attached pendant cement-anchoring groups and polyether side chains, non-ionic comb polymers having a carbon-containing backbone to which are attached pendant hydrolysable groups and polyether side chains, the hydrolysable groups upon hydrolysis releasing cement-anchoring groups, colloidally disperse preparations of polyvalent metal cations, such as Al 3+ , Fe 3+ or Fe 2+ , and a polymeric dispersant which comprises anionic and/or anionogenic groups and polyether side chains, and the polyvalent metal cation is present in a superstoichiometric quantity, calculated as cation equivalents, based on the sum of the anionic and anionogenic groups of the polymeric dispersant, sulfonated melamine-formaldehyde condensates, lignosulfonates, sulfonated ketone-formaldehyde condensates, sulfonated naphthalene-formaldehyde condensates, phosphonate containing dispersants, phosphate containing dispersants, and mixtures thereof.

24 . The composition according to claim 1 , wherein the construction composition comprises less than 5 wt.-% of cementitious hydration products, relative to the total weight of the construction composition.

Assignees

• Construction Research & Technology Gmbh

Inventors

• Bandiera Massimo
• Schwesig Peter
• Sachsenhauser Bernhard

Classifications

• C04B28/26 Primary

  Silicates of the alkali metals · CPC title

• C04B28/04 Primary

  Portland cements · CPC title

• C04B28/14

  containing calcium sulfate cements {(gypsum-paper plates E04C)} · CPC title

• C04B11/30

  with hydraulic cements, e.g. Portland cements · CPC title

• C04B14/06

  Quartz; Sand · CPC title