Backpressure regulation for membraneless hydrogen electrolyzer

Patent metadata

Field	Value
Publication number	US-2023295821-A1
Application number	US-202217700083-A
Country	US
Kind code	A1
Filing date	Mar 21, 2022
Priority date	Mar 21, 2022
Publication date	Sep 21, 2023
Grant date	—

Abstract

A hydrogen electrolyzer system generates hydrogen and oxygen gases via electrolysis. The hydrogen and oxygen gases are exhausted to hydrogen and oxygen exhaust manifolds, respectively. An absolute pressure in one of the hydrogen or oxygen exhaust manifolds is monitored. A differential pressure between the hydrogen and oxygen exhaust manifolds is monitored. Backpressures in the hydrogen and oxygen exhaust manifolds are controlled based upon the absolute and differential pressures.

First claim

1 . At least one machine-accessible storage medium that provides instructions that, when executed by a controller of a hydrogen electrolyzer system, will cause the hydrogen electrolyzer system to perform operations comprising:
generating hydrogen and oxygen gases via electrolysis; exhausting the hydrogen and oxygen gases to hydrogen and oxygen exhaust manifolds, respectively; monitoring an absolute pressure in one of the hydrogen or oxygen exhaust manifolds; monitoring a differential pressure between the hydrogen and oxygen exhaust manifolds; and controlling backpressures in the hydrogen and oxygen exhaust manifolds based upon the absolute and differential pressures.

2 . The at least one machine-accessible storage medium of claim 1 , wherein the hydrogen electrolyzer system comprises a membraneless electrolyzer.

3 . The at least one machine-accessible storage medium of claim 1 , wherein the hydrogen electrolyzer system includes cathode and anode chambers in which cathode and anode electrodes, respectively, are bathed in a shared electrolytic solution that at least partially fills both of the cathode and anode chambers, wherein the cathode and anode chambers are not separated from each other by an electrolysis membrane.

4 . The at least one machine-accessible storage medium of claim 3 , wherein controlling the backpressures in the hydrogen or oxygen exhaust manifolds comprises:
controlling the differential pressure between the hydrogen and oxygen exhaust manifolds to within less than a threshold height differential of the shared electrolytic solution between the cathode and anode chambers, wherein the threshold height differential maintains both of the cathode and anode electrodes entirely bathed in the shared electrolytic solution during the electrolysis.

5 . The at least one machine-accessible storage medium of claim 1 , wherein controlling the backpressures in the hydrogen and oxygen exhaust manifolds comprises:
regulating the absolute pressure in the one of the hydrogen or oxygen exhaust manifolds with a first control loop; and regulating the differential pressure between the hydrogen and oxygen exhaust manifolds with a second control loop, wherein the first and second control loops are independent of each other during steady state operation of the hydrogen electrolyzer system.

6 . The at least one machine-accessible storage medium of claim 1 , wherein monitoring the absolute pressure in the one of the hydrogen or oxygen exhaust manifolds comprises:
monitoring the absolute pressure in the hydrogen exhaust manifold.

7 . The at least one machine-accessible storage medium of claim 6 , wherein controlling the backpressures in the hydrogen and oxygen exhaust manifolds based upon the absolute and differential pressures comprises:
adjusting a first motorized valve coupled to the hydrogen exhaust manifold that controls a flow of the hydrogen gas from the hydrogen exhaust manifold based upon the absolute pressure; and adjusting a second motorized valve coupled to the oxygen exhaust manifold that controls a flow of the oxygen gas from the oxygen exhaust manifold based upon the differential pressure.

8 . The at least one machine-accessible storage medium of claim 7 , wherein, during steady-state operation of the hydrogen electrolyzer system, the first motorized valve is controlled based upon the absolute pressure without reference to the differential pressure and the second motorized valve is controlled based upon the differential pressure without reference to the absolute pressure.

9 . The at least one machine-accessible storage medium of claim 1 , wherein controlling the backpressures in the hydrogen and oxygen exhaust manifolds based upon the absolute and differential pressures comprises regulating the differential pressure with greater precision than regulating the absolute pressure.

10 . The at least one machine-accessible storage medium of claim 1 , further providing instructions that, when executed by the controller, will cause the hydrogen electrolyzer system to perform further operations, comprising:
holding a first valve configured for discharging the oxygen gas from the oxygen exhaust manifold closed during a startup phase of the hydrogen electrolyzer system while raising the backpressures to steady state operating pressures; bleeding the hydrogen gas from the hydrogen manifold with a second valve configured for discharging the hydrogen gas from the hydrogen exhaust manifold during the startup phase; and transitioning control over the first and second valves to independent control loops when the backpressures reach the stead state operating pressures.

11 . The at least one machine-accessible storage medium of claim 1 , wherein controlling the backpressures in the hydrogen and oxygen exhaust manifolds comprises regulating the backpressures with motorized valves controlled by independent electronic control loops based upon the absolute and differential pressures obtained from electromechanical sensors.

12 - 20 . (canceled)

21 . A method of operation of a hydrogen electrolyzer system, the method comprising:
generating hydrogen and oxygen gases via electrolysis; exhausting the hydrogen and oxygen gases to hydrogen and oxygen exhaust manifolds, respectively; monitoring an absolute pressure in one of the hydrogen or oxygen exhaust manifolds; monitoring a differential pressure between the hydrogen and oxygen exhaust manifolds; and controlling backpressures in the hydrogen and oxygen exhaust manifolds based upon the absolute and differential pressures.

22 . The method of claim 21 , wherein the hydrogen electrolyzer system comprises a membraneless electrolyzer.

23 . The method of claim 21 , wherein the hydrogen electrolyzer system includes cathode and anode chambers in which cathode and anode electrodes, respectively, are bathed in a shared electrolytic solution that at least partially fills both of the cathode and anode chambers, wherein the cathode and anode chambers are not separated from each other by an electrolysis membrane.

24 . The method of claim 23 , wherein controlling the backpressures in the hydrogen or oxygen exhaust manifolds comprises:
controlling the differential pressure between the hydrogen and oxygen exhaust manifolds to within less than a threshold height differential of the shared electrolytic solution between the cathode and anode chambers, wherein the threshold height differential maintains both of the cathode and anode electrodes entirely bathed in the shared electrolytic solution during the electrolysis.

25 . The method of claim 21 , wherein controlling the backpressures in the hydrogen and oxygen exhaust manifolds comprises:
regulating the absolute pressure in the one of the hydrogen or oxygen exhaust manifolds with a first control loop; and regulating the differential pressure between the hydrogen and oxygen exhaust manifolds with a second control loop, wherein the first and second control loops are independent of each other during steady state operation of the hydrogen electrolyzer system.

26 . The method of claim 21 , wherein monitoring the absolute pressure in the one of the hydrogen or oxygen exhaust manifolds comprises:
monitoring the absolute pressure in the hydrogen exhaust manifold.

27 . The method of claim 26 , wherein controlling the backpressures in the hydrogen and oxygen exhaust manifolds based upon the absolute and differential pressures comprises:
adjusting a first motorized valve coupled to the hydrogen exhaust manifold that controls a flow of the hyd

Assignees

• X Dev Llc

Inventors

• Gogoana Radu

Classifications

• C25B1/04 Primary

  by electrolysis of water · CPC title

• C25B15/023 Primary

  Measuring, analysing or testing during electrolytic production · CPC title

• C25B9/17

  Cells comprising dimensionally-stable non-movable electrodes; Assemblies of constructional parts thereof · CPC title

• C25B9/07

  Common duct cells · CPC title

• C25B15/08

  Supplying or removing reactants or electrolytes; Regeneration of electrolytes · CPC title