Process for synthesising hydrocarbons

Patent metadata

Field	Value
Publication number	US-2023295517-A1
Application number	US-202118006504-A
Country	US
Kind code	A1
Filing date	Sep 17, 2021
Priority date	Oct 16, 2020
Publication date	Sep 21, 2023
Grant date	—

Abstract

A process for synthesising hydrocarbons is described comprising the steps of (a) making a synthesis gas comprising hydrogen, carbon monoxide and carbon dioxide from a feedstock in a synthesis gas generation unit, (b) removing carbon dioxide to produce a carbon dioxide stream and purified synthesis gas comprising hydrogen and carbon monoxide for synthesis gas in a Fischer-Tropsch hydrocarbon synthesis unit wherein (i) at least a portion of the FT water stream is fed to an electrolysis unit to provide an oxygen stream, which is fed to the synthesis gas generation unit. Carbon dioxide stream recovered from the carbon dioxide removal unit and a portion of the hydrogen stream produced by the electrolysis unit are fed to a reverse water-gas shift unit to produce a carbon monoxide stream, with carbon monoxide stream from the reverse water-gas shift unit fed to the Fischer-Tropsch hydrocarbon synthesis unit.

First claim

1 . A process for synthesising hydrocarbons comprising the steps of (a) making a synthesis gas comprising hydrogen, carbon monoxide and carbon dioxide from a feedstock in a synthesis gas generation unit, (b) removing carbon dioxide from the synthesis gas in a carbon dioxide removal unit to produce a carbon dioxide stream and purified synthesis gas comprising hydrogen and carbon monoxide, and (c) synthesising a mixture of hydrocarbons from the purified synthesis gas in a Fischer-Tropsch hydrocarbon synthesis unit, with co-production of a FT water stream, wherein (i) at least a portion of the FT water stream is fed to an electrolysis unit to provide an oxygen stream, which is fed to the synthesis gas generation unit, and a hydrogen stream, (ii) at least a portion of the carbon dioxide stream recovered from the carbon dioxide removal unit and a portion of the hydrogen stream produced by the electrolysis unit are fed to a reverse water-gas shift unit to produce a carbon monoxide stream, and (iii) at least a portion of the carbon monoxide stream from the reverse water-gas shift unit is fed to the Fischer-Tropsch hydrocarbon synthesis unit.

2 . A process according to claim 1 , wherein the feedstock comprises natural gas, associated gas, coal, biomass or municipal solid waste or equivalent containing non-biogenic carbon.

3 . A process according to claim 2 , wherein the feedstock is natural gas and the synthesis gas generation unit comprises a catalytic partial oxidation unit, a non-catalytic partial oxidation unit or an autothermal reformer.

4 . A process according to claim 2 , wherein the feedstock is coal, biomass or municipal solid waste or equivalent containing non-biogenic carbon and the synthesis gas generation unit comprises a gasifier, optionally with one or more downstream processing units selected from a partial oxidation unit, a tar reforming unit and purification reactors containing a purification material.

5 . A process according to claim 1 , wherein the carbon dioxide removal unit comprises a physical wash system or a reactive wash system.

6 . A process according to claim 1 , wherein the Fischer-Tropsch hydrocarbon synthesis unit comprises a tubular reactor in which catalyst carriers containing a Fischer-Tropsch catalyst are disposed within one or more tubes cooled by a cooling medium.

7 . A process according to claim 1 , further comprising a step (d) of upgrading the mixture of hydrocarbons synthesised in the Fischer-Tropsch hydrocarbon synthesis unit in a hydrotreating unit to produce hydrocarbon products.

8 . A process according to claim 7 , wherein the hydrotreating unit comprises one or more vessels containing a catalyst selected from a hydroisomerization catalyst, a hydrogenation catalyst, a hydrodeoxygenation catalyst, and/or a hydrocracking catalyst.

9 . A process according to claim 7 , wherein a portion of the hydrogen stream from the electrolysis unit is fed to the hydrotreating unit.

10 . A process according to claim 1 , wherein a water stream produced by the reverse water gas shift unit is fed to the electrolysis unit.

11 . A process according to claim 1 , wherein a portion of the hydrogen stream from the electrolysis unit is fed to the Fischer-Tropsch hydrocarbon synthesis unit.

12 . A process according to claim 1 , wherein an oxygen stream provided by the electrolysis unit is used to combust a portion of a feed gas comprising carbon dioxide and hydrogen fed to the reverse water-gas shift unit to raise the temperature of the feed gas.

13 . A process according to claim 1 , wherein water formed in the reverse water-gas shift unit is fed to the electrolysis unit.

14 . A process according to claim 1 , wherein a tail gas comprising one or more of methane, ethane, propane, butane and C5-C10 hydrocarbons, is recovered from the Fischer-Tropsch hydrocarbon synthesis unit, and is fed to the synthesis gas generation unit.

15 . A process according to claim 1 , wherein a tail gas comprising one or more of methane, ethane, propane, butane and C5-C10 hydrocarbons, is recovered from the Fischer-Tropsch hydrocarbon synthesis unit, and is subjected to a separate reforming step to form a reformed tail gas containing hydrogen, which is fed to the Fischer-Tropsch hydrocarbon synthesis unit and/or the reverse water-gas shift unit.

16 . A process according to claim 1 , wherein the hydrocarbon products recovered from the hydrotreating unit are fed to a separation unit to recover C1-C4 gases, a naphtha fraction, at least one kerosene and/or gas oil fraction and a heavy fraction.

17 . A system for performing the process according to claim 1 comprising (a) a synthesis gas generation unit for making a synthesis gas comprising hydrogen, carbon monoxide and carbon dioxide from a feedstock, (b) a carbon dioxide removal unit coupled to the synthesis gas generation unit for removing carbon dioxide from the synthesis gas to produce a carbon dioxide stream and purified synthesis gas comprising hydrogen and carbon monoxide, and (c) a Fischer-Tropsch hydrocarbon synthesis unit coupled to the carbon dioxide removal unit for synthesising a mixture of hydrocarbons from the purified synthesis gas, with co-production of a FT water stream, wherein (i) an electrolysis unit is coupled to the Fischer-Tropsch hydrocarbon synthesis unit, configured to be fed with at least a portion of the FT water to provide an oxygen stream, which is configured to be fed to the synthesis gas generation unit, and a hydrogen stream, (ii) a reverse water-gas shift unit is coupled to the carbon dioxide removal unit and the electrolysis unit and configured to be fed with at least a portion of the carbon dioxide stream from the carbon dioxide removal unit and a portion of the hydrogen stream produced by the electrolysis unit, to produce a carbon monoxide stream, and (iii) the Fischer-Tropsch hydrocarbon synthesis unit is coupled to the reverse water-gas shift unit to receive at least a portion of the carbon monoxide stream.

18 . A system according to claim 17 , further comprising (d) a hydrotreating unit coupled to the Fischer-Tropsch hydrocarbon synthesis unit for upgrading the mixture of hydrocarbons to produce hydrocarbon products.

Assignees

• Johnson Matthey Davy Technologies Ltd

Inventors

• Claxton Henry Arthur
• Coe Andrew James
• Mckenna Mark Joseph
• Ticehurst Paul Robert

Classifications

• C10J3/00 Primary

  Production of combustible gases containing carbon monoxide from solid carbonaceous fuels (destructive distillation processes C10B) · CPC title

• C10G2/32 Primary

  with the use of catalysts · CPC title

• C10K3/026

  Increasing the carbon monoxide content, e.g. reverse water-gas shift [RWGS] · CPC title

• C10J2300/1684

  with electrolysis of water · CPC title

• C10J2300/1659

  to liquid hydrocarbons · CPC title