NOVEL Mn(VI) - ACTIVATED OXIDOFLUORIDES AS LUMINESCENT MATERIALS FOR SOLID STATE LIGHT SOURCES

Patent metadata

Field	Value
Publication number	US-2023279292-A1
Application number	US-202318116847-A
Country	US
Kind code	A1
Filing date	Mar 3, 2023
Priority date	Mar 4, 2022
Publication date	Sep 7, 2023
Grant date	—

Abstract

A compound of the general formula A 2 N 1-x M x O 2x X 6-2x doped with Mn(IV), in which A is selected from the group consisting of Li, Na, K, Rb, Cs, Cu, Ag, Ti, NH 4 or a combination thereof, N is selected from the group consisting of Si, Ge, Sn, Ti, Pb, Ce, Zr, Ru, Ir, Pr and/or Hf or a combination thereof, M is selected from the group consisting of W, Cr, Mo, Te and/or Re or a combination thereof, X is selected from the group consisting of F, Cl, Br, I or a combination thereof, and 0<x≤1.

First claim

What is claimed is:

1 . A compound of the general formula (I):
A 2 N 1-x M x O2 x X 6-2x   (I)
doped with Mn(IV), wherein: A is selected from the group consisting of Li, Na, K, Rb, Cs, Cu, Ag, Tl, NH 4 or a combination thereof; N is selected from the group consisting of Si, Ge, Sn, Ti, Pb, Ce, Zr, Ru, Ir, Pr and/or Hf or a combination thereof, M is selected from the group consisting of W, Cr, Mo, Te and/or Re or a combination thereof, X is selected from the group consisting of F, Cl, Br, I or a combination thereof; and 0<x≤1.

2 . The compound according to claim 1 , represented by the general formula (II):
A 2 N 1-x-y M x O2 x X 6-2x :Mn(IV) y   (II), wherein:
A is selected from the group consisting of Li, Na, K, Rb, Cs, Cu, Ag, Tl, NH4 or a combination thereof; N is selected from the group consisting of Si, Ge, Sn, Ti, Pb, Ce, Zr, Ru, Ir, Pr and/or Hf or a combination thereof; M is selected from the group consisting of W, Cr, Mo, Te and/or Re or a combination thereof, X is selected from the group consisting of F, Cl, Br, I or a combination thereof; 0<x≤1; 0<y≤0.5; and x+y<1.

3 . The compound according to claim 1 , wherein the index x is 0.02≤x≤0.05.

4 . The compound according to claim 1 , wherein:
A is selected from the group consisting of Na, K, Cs and mixtures of two or three thereof, M is selected from the group consisting of Mo, W and mixtures of Mo and W, where Cr, Te and/or Re may optionally be present; N is selected from the group consisting of Si, Ti and mixtures of Si and Ti, where Ge, Sn, Pb, Ce, Ru, Ir, Pr, Zr, and/or Hf may optionally be present; X is Fluoride, and 0.001≤x≤0.50.

5 . The compound according to claim 1 , wherein the compound is coated on its surface with another compound.

6 . A process for preparing a compound according to claim 1 , comprising the steps of:
a) preparing a solution or suspension comprising A, M, N, and Mn in an AX-containing solution; b) stirring the suspension or the solution; and c) separating the solid obtained from the suspension or the solution.

7 . A luminophore or conversion luminophore allowing partial or complete conversion of UV light, violet light, and/or blue light to light of longer wavelength, the luminophore or conversion luminophore comprising the compound according to claim 1 .

8 . A radiation-converting mixture comprising the compound according to claim 1 .

9 . The radiation-converting mixture according to claim 8 , further comprising one or more further luminescent materials selected from conversion luminophores and/or semiconductor nanoparticles.

10 . A light source comprising at least one primary light source and at least one compound according to claim 1 .

11 . The light source according to claim 10 , wherein the primary light source comprises a luminescent Indium Aluminum Gallium Nitride material.

12 . The light source according to claim 11 , wherein the luminescent Indium Aluminum Gallium Nitride is a compound of the formula In i Ga j Al k N, and
wherein 0≤i, 0≤j, 0≤k, and i+j+k=1.

13 . A lighting unit comprising at least one light source according to claim 10 .

14 . A light emitting device, comprising:
a substrate; a light emitting diode disposed on the substrate; and a wavelength conversion unit disposed on the light emitting diode, wherein the wavelength conversion unit includes a plurality of phosphors, wherein the light emitting device is configured to generate white light by synthesizing light emitted from the light emitting diode and the plurality of phosphors, respectively, and wherein at least one of the plurality of phosphors include a Mn(IV)-activated phosphor based on an oxidohalide host lattice.

15 . The light emitting device according to claim 14 , wherein at least one of the plurality of phosphors is configured to emit light in the same color gamut as that of the Mn(IV)-activated phosphor based on the oxidohalide host lattice.

16 . The light emitting device according to claim 14 , wherein at least one of the plurality of phosphors is configured to emit light in a color gamut different from that of the Mn(IV)-activated phosphor based on the oxidohalide host lattice.

17 . The light emitting device according to claim 14 , wherein the white light formed by synthesizing the light emitted from the light emitting diode and each of the plurality of phosphors respectively has a CRI of 90 or more.

18 . The light emitting device according to claim 14 , wherein the white light formed by synthesizing the light emitted from the light emitting diode and each of the plurality of phosphors respectively has light efficiency exceeding 100%.

19 . The light emitting device according to claim 14 , wherein the wavelength conversion unit includes a first wavelength conversion unit and a second wavelength conversion unit, and
wherein the light emitting diode is laminated with the wavelength conversion unit.

20 . The light emitting device according to claim 14 , wherein the wavelength conversion unit is spaced apart from the light emitting diode.

Assignees

• Seoul Semiconductor Co Ltd
• Litec Vermogensverwaltungsgesellschaft Mbh

Inventors

• Han Bo Yong
• Tews Stefan
• Rapphahn Mathias
• Kistner Benjamin

Classifications

• H10W90/00

  Package configurations · CPC title

• H10H20/8515

  not being in contact with the bodies · CPC title

• C09K11/616

  with alkali or alkaline earth metals · CPC title

• H10H20/8513

  having two or more wavelength conversion materials · CPC title

• H10H20/8512 Primary

  Wavelength conversion materials · CPC title