Plasma-Enabled Liquid Filtration and Decontamination

Patent metadata

Field	Value
Publication number	US-2023278896-A1
Application number	US-202318177850-A
Country	US
Kind code	A1
Filing date	Mar 3, 2023
Priority date	Mar 4, 2022
Publication date	Sep 7, 2023
Grant date	—

Abstract

Apparatus and method for decontaminating both contaminated waters and sorbent filter media, either separately or simultaneously, in a single system. Contaminants in a liquid flowing through a reaction chamber are removed by first generating a plasma within the liquid in the chamber, with the contaminants being broken into smaller particles at the interfaces between the generated plasma and the liquid. The combined plasma-liquid solution is then passed through a solid filter, which captures the smaller contaminant particles to decontaminate the liquid. To decontaminate the filter media, plasma flows through the filter material without the presence of liquid, the plasma reacting with the filter material to remove contaminants previously adsorbed by the filter.

First claim

1 . An apparatus for decontamination of a liquid, comprising:
a reaction chamber having a first end and a second end opposite the first end; a hollow tube electrode and a solid electrode, each of the hollow tube and solid electrodes extending into the reaction chamber, a portion of each of the hollow tube electrode and the solid electrode being submerged within a liquid flowing through the reaction chamber; a power supply connected to the hollow tube electrode and to the solid electrode; and wherein a gas is introduced into the reaction chamber at the first end via the hollow tube electrode, the gas contacting both the hollow tube electrode and the liquid, a plasma volume being generated from the gas when a voltage from the power supply is applied across the hollow tube electrode and the solid electrode; wherein the liquid surrounds the plasma volume as it flows through the reaction chamber, the plasma causing parent species contaminant molecules in the liquid to break apart into daughter products comprising smaller molecular fragments as it contacts the liquid; wherein the liquid then passes through a filter situated between the plasma volume and an outlet from the reaction chamber; and wherein the parent species and daughter products in the liquid are adsorbed by the filter before the liquid is output from the reaction chamber via the outlet.

2 . The decontamination apparatus according to claim 1 , wherein the hollow tube electrode is situated at the first end of the reaction chamber and the solid electrode is situated at the second end of the reaction chamber.

3 . The decontamination apparatus according to claim 1 , wherein the hollow tube electrode is connected to a positive voltage lead from the power supply and the solid electrode is connected to a negative voltage lead from the power supply.

4 . The decontamination apparatus according to claim 1 , wherein the electrodes have ends that are planar disks with holes that allow liquid and gas, but not the filter material, to pass through the electrodes such that when power is applied to the electrodes, a plasma is generated in and around the filter material, exposing the liquid to the plasma while the liquid is flowing through the filter material.

5 . The decontamination apparatus according to claim 1 , wherein both the hollow tube electrode and the solid electrode are situated at the first end of the reaction chamber, the plasma being generated between the hollow tube electrode and the solid electrode.

6 . The decontamination apparatus according to claim 1 , wherein the gas comprises helium (He), xenon (Xe), argon (Ar), neon (Ne), or mixtures thereof

7 . The decontamination apparatus according to claim 1 , wherein the gas comprises oxygen (O 2 ), nitrogen (N 2 ), air, or mixtures thereof.

8 . The decontamination apparatus according to claim 1 , wherein the filter comprises granular activated carbon (GAC), ion exchange (IX) resins, or polymer fibers.

9 . A method for decontaminating a liquid, comprising:
providing a reaction chamber having a first end and a second end opposite the first end, the reaction chamber having a filter material situated within a filter cage situated near the second end; providing a hollow tube electrode and a solid electrode, each of the hollow tube and solid electrodes extending into the reaction chamber, a portion of each of the hollow tube electrode and the solid electrode being submerged within a liquid flowing through the reaction chamber; providing a power supply connected to the hollow tube electrode and to the solid electrode; introducing a gas introduced into the reaction chamber at the first end via the hollow tube electrode, the gas contacting both the hollow tube electrode and the liquid; and applying a voltage from the power supply to generate a plasma volume from the gas within the reaction chamber; wherein the liquid surrounds the plasma volume as it flows through the reaction chamber, the plasma causing parent species contaminant molecules in the liquid to break apart into daughter products comprising smaller molecular fragments as it contacts the liquid; wherein the liquid then passes through a filter situated between the plasma volume and an outlet from the reaction chamber; and wherein the parent species and daughter products in the liquid are adsorbed by the filter before the liquid is output from the reaction chamber via the outlet.

10 . The method for decontaminating a liquid according to claim 9 , wherein the gas comprises helium (He), xenon (Xe), argon (Ar), neon (Ne), or mixtures thereof

11 . The method for decontaminating a liquid according to claim 9 , wherein the gas comprises oxygen (O 2 ), nitrogen (N 2 ), air, or mixtures thereof.

12 . The method for decontaminating a liquid according to claim 9 , wherein the filter comprises granular activated carbon (GAC), ion exchange (IX) resins, or polymer fibers.

13 . A method for regenerating a decontamination filter in a reaction chamber, comprising:
providing a reaction chamber having a first end and a second end opposite the first end, the reaction chamber having decontamination filter material situated within a filter cage situated near the second end; providing a hollow tube electrode and a solid electrode, each of the hollow tube and solid electrodes extending into the reaction chamber; providing a power supply connected to the hollow tube electrode and to the solid electrode; introducing a gas into the reaction chamber at the first end via the hollow tube electrode; and applying a voltage from the power supply across the gas to generate a plasma within the reaction chamber; wherein the plasma passes through the filter material, the plasma causing contaminant molecules adsorbed by the filter material to be desorbed from the filter material and output from the reaction chamber.

14 . The method for regenerating a decontamination filter in a reaction chamber according to claim 13 , wherein the gas comprises ambient air, O 2 , H 2 , halogen gases, or reactive gases, either alone or in combination with a noble gas.

Assignees

• Us Gov Sec Navy

Inventors

• Walton Scott G
• Maza William A
• Johnson Michael J
• Boris David R
• Breslin Vanessa M
• Daniels Grant C
• Balow Robert B

Classifications

• C02F1/4608 Primary

  using electrical discharges · CPC title

• C02F2101/36

  containing halogen · CPC title

• C02F1/283

  using coal, charred products, or inorganic mixtures containing them · CPC title

• C02F1/42

  by ion-exchange (ion-exchange in general B01J) · CPC title

• C02F1/001

  Processes for the treatment of water whereby the filtration technique is of importance (C02F1/44 takes precedence; construction of filters in general B01D24/00 - B01D41/00) · CPC title