Air filter for high-efficiency pm2.5 capture

Patent metadata

Field	Value
Publication number	US-2023277967-A1
Application number	US-202218069126-A
Country	US
Kind code	A1
Filing date	Dec 20, 2022
Priority date	Dec 12, 2014
Publication date	Sep 7, 2023
Grant date	—

Abstract

Described here is an air filter comprising a substrate and a network of polymeric nanofibers deposited on the substrate, wherein the air filter a removal efficiency for PM2.5 of at least 70% when a light transmittance is below 50%. Also described here is an electric air filter comprising a first layer adapted to receive a first electric voltage, wherein the first layer comprises an organic fiber coated with a conductive material. Further described is an air filter for high temperature filtration, comprising a substrate and a network of polymeric nanofibers deposited on the substrate, wherein the air filter has a removal efficiency for PM2.5 of at least 70% at a temperature of a least 70° C.

First claim

What is claimed is:

1 . An air filter comprising a substrate and a network of polymeric nanofibers deposited on the substrate, wherein the air filter has a removal efficiency for PM 2.5 of at least 70% when a light transmittance through the filter is below 50%.

2 . The air filter of claim 1 , wherein the polymeric nanofibers comprise a polymer comprising a repeating unit having a dipole moment of at least 1 D.

3 . The air filter of claim 1 , wherein the polymeric nanofibers comprise a polymer comprising a repeating unit having a dipole moment of at least 2 D.

4 . The air filter of claim 1 , wherein the polymeric nanofibers comprise a polymer comprising a repeating unit having a dipole moment of at least 3 D.

5 . The air filter of claim 1 , wherein the polymeric nanofibers comprise polyacrylonitrile.

6 . The air filter of claim 1 , wherein the polymeric nanofibers comprise nylon.

7 . The air filter of claim 1 , wherein the polymeric nanofibers have an average diameter of 10-900 nm.

8 . The air filter of claim 1 , wherein the polymeric nanofibers have positive or negative net electric charge.

9 . The air filter of claim 1 , wherein the air filter has a removal efficiency for PM 2.5 of at least 90%, and a removal efficiency for PM 10-2.5 of at least 90% when a light transmittance is below 70%,

10 . The air filter of claim 1 , wherein the air filter has a removal efficiency for PM 2.5 of at least 90% after 100 hours of exposure to air having an average PM 2.5 index of 300 and an average wind speed of 1 mile/hour.

11 . The air filter of claim 1 , wherein other materials are added onto polymer nanofibers to provide more functionality.

12 . An air filtering device comprising the air filter of claim 1 .

13 . The air filtering device of claim 12 , which is incorporated into a window screen, a wearable mask, an indoor air filtration unit, a building air conditioning and ventilation system, a car air condition system, a car exhaust system, an industrial exhaust system, a clean room air filtration system, a cigarette filter, or an outdoor filtration system.

14 . A method for making the air filter of claim 1 , comprising electrospinning the polymeric nanofibers onto the substrate from a polymer solution comprising 1-20 wt. % of a polymer comprising a repeating unit having a dipole moment of at least 1 D, or at least 2 D, or at least 3 D.

15 . A method for making an air filtering device, comprising incorporating the air filter of claim 1 into a window screen, a wearable mask, an indoor air filtration unit, a building air conditioning and ventilation system, a car air condition system, a car exhaust system, an industrial exhaust system, a clean room air filtration system, a cigarette filter, or an outdoor filtration system.

16 . An electric air filter comprising a first layer adapted to receive a first electric voltage, wherein the first layer comprises an organic fiber coated with a conductive material.

17 . The electric air filter of claim 16 , wherein the organic fiber is a microfiber or nanofiber, wherein the organic fiber is partially coated with the conductive material, and wherein the conductive material is selected from carbon, metal, metal oxide, metal nitride, metal carbide and conductive polymer.

18 . The electric air filter of claim 17 , wherein the organic fiber comprises a coated side and a uncoated side, and wherein the uncoated side faces direction of air flow.

19 . The electric air filter of claim 16 , wherein the organic fiber is a microfiber or nanofiber, wherein the organic fiber is coated with the conductive material, wherein the conductive material is selected from carbon, metal, metal oxide, metal nitride, metal carbide and conductive polymer, and wherein the conductive material is surface functionalized with a polar group to increase affinity for PM 2.5 .

20 . The electric air filter of claim 16 , further comprising a second layer adapted to receive a second electric voltage.

21 . An air filtering system comprising the electric air filter of claim 16 .

22 . The air filtering system of claim 21 , which is selected from a ventilation system, an air-conditioning system, and an automotive cabin air filter.

23 . A method for making the electric air filter of claim 16 , comprising sputter coating a metal or metal oxide onto a microfiber or nanofiber, wherein the sputter coating is directional, and wherein the microfiber or nanofiber is partially coated with the metal or metal oxide.

24 . A method for making the electric air filter of claim 16 , comprising treating a microfiber or nanofiber coated with a metal or metal oxide to generate a reactive group, and reacting said reactive group with an organic compound to functionalize surface of the metal or metal oxide coating to increase affinity for PM 2.5 .

25 . A method for filtering PM 2.5 using the electric air filter of claim 16 , comprising applying an electric voltage on the first layer of the electric air filter.

26 . An air filter for high temperature filtration, comprising a substrate and a network of polymeric nanofibers deposited on the substrate, wherein the air filter has a removal efficiency for PM 2.5 of at least 70% at an operating temperature of at least 70° C.

27 . The air filter of claim 26 , wherein the polymeric nanofibers comprise a polymer comprising a repeating unit having a dipole moment of at least 1 D, or at least 2 D, or at least 3 D.

28 . The air filter of claim 26 , wherein the polymeric nanofibers comprise polyimide.

29 . The air filter of claim 26 , wherein the polymeric nanofibers have an average diameter of 10-900 nm.

30 . The air filter of claim 26 , wherein the air filter has a pressure drop of 500 Pa or less at a gas velocity of 0.2 m/s, a removal efficiency for PM 2.5 of at least 80% at an operating temperature of at least 70° C., and a removal efficiency for PM 10-2.5 of at least 80% at an operating temperature of at least 70° C.

31 . The air filter of claim 26 , wherein the air filter has a removal efficiency for PM 2.5 of at least 80% after 100 hours of exposure to air having an average PM 2.5 index of 300 and an average wind speed of 0.2 m/s at an operating temperature of at least 70° C.

32 . An air filtering device for removing high temperature PM 2.5 particles from pollution sources comprising the air filter of claim 26 .

33 . An air filtering device of claim 32 , which is selected from a vehicle exhaust filter, an industrial exhaust filter, and a power plant exhaust filter.

34 . A method for making the air filter of claim 26 , comprising electrospinning the polymeric nanofibers onto the substrate from a polymer solution comprising 1-30 wt. % of a polymer comprising a repeating unit having a dipole moment of at least 1 D.

35 . A method for making an air filtering device for removing high temperature PM 2.5 particles from pollution sources, comprising incorporating the air filter of claim 26 into a vehicle exhaust filter, an industrial exhaust filter, or a power plant exhaust filter.

Assignees

• Univ Leland Stanford Junior

Inventors

• Cui Yi
• Zhang Rufan
• Liu Chong
• Hsu Po-Chun
• Chu Steven

Classifications

• B01D39/1623 Primary

  of synthetic origin · CPC title

• C23C14/205

  by cathodic sputtering · CPC title

• C23C14/04

  Coating on selected surface areas, e.g. using masks · CPC title

• B03C3/155

  Filtration · CPC title

• B03C3/60

  Use of special materials other than liquids · CPC title