Methods and Apparatuses for Making Nanomaterials

Patent metadata

Field	Value
Publication number	US-2023249147-A1
Application number	US-202318094490-A
Country	US
Kind code	A1
Filing date	Jan 9, 2023
Priority date	Jan 25, 2022
Publication date	Aug 10, 2023
Grant date	—

Abstract

Methods and apparatuses for making nanomaterials are disclosed. The methods involve passing one or more source materials through a high pressure and high temperature chamber with an open throat, and then allowing the reactants to expand into a lower pressure, lower temperature zone. The source material is non-stoichiometric and fuel-rich so that excess un-combusted primary source material can form the nanomaterials. In some cases, the apparatus may be in the form of a modified rocket engine. The methods may be used to make various materials including: carbon nanotubes, boron nitride nanomaterials, titanium dioxide, and any materials that are currently produced by flame synthesis, including but not limited to electrocatalysts. The methods may also be used to make nanomaterials outside the Earth's atmosphere. The methods can include making, coating, or repairing structures in space, such as antennae.

First claim

What is claimed is:

1 . A method of making nanomaterials comprising:
a) introducing at least two materials into the chamber of an apparatus, wherein when the materials are in said chamber, they are at a first pressure and a first temperature, said first pressure and said first temperature being relatively high, said apparatus having a throat having a reduced size opening, said throat being downstream from said chamber, wherein said apparatus further comprises a reduced pressure and temperature zone downstream from said throat, said zone having an exit, wherein at least one of said materials comprises a primary source material for the nanomaterials to be formed; b) passing said materials into said throat; c) passing said materials into said reduced pressure and temperature zone wherein said materials expand at a lower pressure than said first pressure; d) forming nanomaterials in said apparatus; and e) collecting said nanomaterials at the exit from said zone.

2 . The method of claim 1 wherein the chamber is a combustion chamber.

3 . The method of claim 2 wherein the chamber and said reduced pressure and temperature zone are provided in the form of a rocket engine comprising a nozzle, wherein said reduced pressure and temperature zone is in said nozzle.

4 . The method of claim 2 wherein at least one of said materials comprises a fuel and at least one of said materials comprises an oxidizer, wherein said fuel comprises said primary source material.

5 . The method of claim 1 wherein when at least two of said materials combine, they create an exothermic reaction to contribute to the creation of said first pressure and first temperature.

6 . The method of claim 1 wherein the first pressure and first temperature are at least partially produced by external heating, wherein said external heating comprises at least one of the following steps: a) heating at least one of said materials prior to introducing said material or materials into said chamber; and b) heating said chamber.

7 . The method of claim 4 wherein said primary source material comprises a carbon source, and said nanomaterials comprise carbon nanotubes.

8 . The method of claim 7 wherein the carbon source comprises a carbon-containing fuel, wherein the ratio of fuel and oxidizer is non-stoichiometric and fuel-rich so that when combusted, excess un-combusted carbon is created that will provide the primary source material for the nanomaterials.

9 . The method of claim 8 wherein the carbon source comprises one or more of the following: hydrocarbon, alcohol, gasified coal, gasified waste, natural gas, field gas or unprocessed natural gas.

10 . The method of claim 8 wherein the oxidizer comprises one or more of the following: air or oxygen.

11 . The method of claim 7 further comprising a step of introducing a catalyst or catalyst precursor into the chamber prior to step (b), and said carbon source and catalyst or catalyst precursor participate in a reaction.

12 . The method of claim 11 wherein the catalyst or catalyst precursor comprises a metal or an alloy of two or more metals.

13 . The method of claim 1 wherein said primary source material comprises a boron source, and said nanomaterials comprise boron nitride compounds.

14 . The method of claim 1 wherein said primary source material comprises a source of titanium, and said nanomaterials comprise titanium dioxide nanoparticles.

15 . The method of claim 4 wherein the fuel comprises a hydrocarbon, the oxidizer comprises one or more of the following: air or oxygen, and said nanomaterials formed comprise at least one of catalysts and electrocatalysts.

16 . An apparatus for making nanomaterials comprising:
a chamber for introducing at least two materials and containing said materials at a first pressure and a first temperature, wherein said first pressure and said first temperature are relatively high, said apparatus having inlets for said at least two materials and a throat having a reduced size opening, said throat being downstream from said chamber; a reduced pressure and temperature zone downstream from said throat, which is at a lower pressure and lower temperature than said first pressure and first temperature, said zone having an exit; and a nanomaterial collection zone downstream from the reduced pressure and temperature zone.

17 . The apparatus of claim 16 wherein said inlets comprise a first inlet for a fuel and a second inlet for an oxidizer, and said chamber is a combustion chamber, wherein said apparatus is configured to receive said materials in a fuel-rich, substantially non-stoichiometric ratio, so that said fuel is incompletely combusted.

18 . The apparatus of claim 17 wherein said chamber and said reduced pressure and temperature zone are provided in the form of a rocket engine comprising a nozzle, wherein said reduced pressure and temperature zone is in the nozzle.

19 . The apparatus of claim 18 wherein said apparatus produces substantially no thrust.

20 . The apparatus of claim 16 wherein said chamber is heated by an external source.

21 . The apparatus of claim 20 wherein said external source comprises one or more of the following: a) a mechanism for heating at least one of said materials prior to introducing said material or materials into said chamber; and b) a mechanism for heating the chamber.

22 . A method of making bulk diamond comprising:
a) introducing at least two materials into the chamber of an apparatus, wherein at least one of said materials comprises a carbon source material for the bulk diamond to be formed an another of said materials comprises atomic hydrogen, wherein when the materials are in said chamber, they are at a first pressure and a first temperature, said first pressure and said first temperature being relatively high, said apparatus having a throat having a reduced size opening, said throat being downstream from said chamber, wherein said apparatus further comprises a reduced pressure and temperature zone downstream from said throat, said zone having an exit; b) passing said materials into said throat; c) passing said materials into said reduced pressure and temperature zone wherein said materials expand at a lower pressure than said first pressure; d) forming bulk diamond in said apparatus; and e) collecting said bulk diamond at the exit from said zone.

Assignees

• Us Gov Air Force

Inventors

• Maruyama Benji

Classifications

• B01J19/26

  Nozzle-type reactors, i.e. the distribution of the initial reactants within the reactor is effected by their introduction or injection through nozzles · CPC title

• B01J3/062 Primary

  characterised by the composition of the materials to be processed · CPC title

• C01B32/162

  characterised by catalysts · CPC title

• C01G23/07 Primary

  Producing by vapour phase processes, e.g. halide oxidation · CPC title

• C01P2004/64

  Nanometer sized, i.e. from 1-100 nanometer · CPC title