Method for producing inorganic fluoride luminescent material

Patent metadata

Field	Value
Publication number	US-2023220275-A1
Application number	US-202118000275-A
Country	US
Kind code	A1
Filing date	May 20, 2021
Priority date	May 29, 2020
Publication date	Jul 13, 2023
Grant date	—

Abstract

Provided is a method for producing an inorganic fluoride luminescent material having excellent light emission characteristics by using a non-aqueous hydrogen fluoride-containing liquid.
The method for producing an inorganic fluoride luminescent material includes: bringing a first inorganic fluoride luminescent material and a non-aqueous hydrogen fluoride-containing liquid having a hydrogen fluoride content in a range of 20% by mass or more and 100% by mass or less into contact with each other to obtain a non-aqueous solution containing ions derived from the first inorganic fluoride luminescent material, and bringing the non-aqueous solution and a non-aqueous organic liquid having a hydrogen fluoride content of less than 20% by mass into contact with each other to precipitate a second inorganic fluoride luminescent material.

First claim

What is claimed is:

1 . A method for producing an inorganic fluoride luminescent material comprising:
bringing a first inorganic fluoride luminescent material and a non-aqueous hydrogen fluoride-containing liquid having a hydrogen fluoride content in a range of 20% by mass or more and 100% by mass or less into contact with each other to obtain a non-aqueous solution containing ions derived from the first inorganic fluoride luminescent material; and bringing the non-aqueous solution and a non-aqueous organic liquid having a hydrogen fluoride content of less than 20% by mass into contact with each other to precipitate a second inorganic fluoride luminescent material.

2 . The method for producing an inorganic fluoride luminescent material according to claim 1 , wherein the non-aqueous hydrogen fluoride-containing liquid comprises at least one selected from the group consisting of nitrogen-containing heterocyclic compounds, amines, ureas, amides, carbamic acids, trialkylphosphines, ethers, esters, alcohols, and quaternary ammonium salts.

3 . The method for producing an inorganic fluoride luminescent material according to claim 1 , wherein the non-aqueous organic liquid comprises at least one selected from the group consisting of nitriles, ketones, amines, amides, nitrogen-containing heterocyclic compounds, fluoro-compounds, ethers, esters, alcohols, and mixtures of these.

4 . The method for producing an inorganic fluoride luminescent material according to claim 1 , wherein the non-aqueous solution has a concentration of the first inorganic fluoride luminescent material in a range of 0.01 g/mL or more and 1.0 g/mL or less.

5 . The method for producing an inorganic fluoride luminescent material according to claim 1 , wherein in the step of precipitating the second inorganic fluoride luminescent material, the temperature of the non-aqueous solution is in a range of 10° C. or higher and 40° C. or lower, the temperature of the non-aqueous organic liquid is in a range of 10° C. or higher and 40° C. or lower, and the temperature difference between the temperature of the non-aqueous solution and the temperature of the non-aqueous organic liquid is less than 10° C.

6 . The method for producing an inorganic fluoride luminescent material according to claim 1 , wherein in the step of precipitating the second inorganic fluoride luminescent material, the volume ratio of the non-aqueous solution to the non-aqueous organic liquid is 1 : 1 to 5 : 1.

7 . The method for producing an inorganic fluoride luminescent material according to claim 1 , wherein in the step of precipitating the second inorganic fluoride luminescent material, while continuously stirring the non-aqueous solution, the non-aqueous organic liquid is dropped thereinto to precipitate the second inorganic fluoride luminescent material.

8 . The method for producing an inorganic fluoride luminescent material according to claim 7 , wherein in the step of precipitating the second inorganic fluoride luminescent material, the stirring speed of the non-aqueous solution is in a range of 20 to 1,000 rpm.

9 . The method for producing an inorganic fluoride luminescent material according to claim 7 , wherein in the step of precipitating the second inorganic fluoride luminescent material, the dropping speed of the non-aqueous organic liquid is in a range of 0.1 mL/min or more and 10 mL/min or less.

10 . The method for producing an inorganic fluoride luminescent material according to claim 1 , wherein the second inorganic fluoride luminescent material comprises a composition represented by the following formula (I):

Ax

M1-zMn4+zFy

wherein A represents at least one ion selected from the group consisting of Li+, Na+, K+, Rb+, Cs+, and NH4+; M represents at least one element selected from the group consisting of Group 4 elements and Group 14 elements; x is an absolute value of an electric charge of the [M1-zMn4+zFy] ion; and y and z satisfy 5 ≤ y ≤ 7 and 0 < z < 0.2, respectively.

Assignees

• Nichia Corp

Inventors

• Sano Yohei
• TAGUCHI Hiroomi

Classifications

• C09K11/617 Primary

  Silicates · CPC title

• C09K11/67

  containing refractory metals · CPC title

• C09K11/08

  containing inorganic luminescent materials · CPC title

• C09K11/61

  containing fluorine, chlorine, bromine, iodine or unspecified halogen elements · CPC title

• C01B33/10 Primary

  Compounds containing silicon, fluorine, and other elements · CPC title