Sulfate-poor calcium-containing porous mineral materials

Patent metadata

Field	Value
Publication number	US-2023219850-A1
Application number	US-202118015763-A
Country	US
Kind code	A1
Filing date	Jun 30, 2021
Priority date	Jul 13, 2020
Publication date	Jul 13, 2023
Grant date	—

Abstract

The present invention relates to calcium-containing, porous, mineral materials having a sulfate content of not more than 1.5% by weight and a biopolymer content in the range of 0.001 to 5.00% by weight, each relative to the total weight of the materials, a method for producing these materials with the aid of biopolymers as stabilizers and the use of biopolymers for producing sulfate-poor calcium-containing, porous, mineral materials.

First claim

1 . A calcium-containing porous mineral material having a sulfate content of not more than 1.5% by weight and a content of biopolymers in the range from 0.001% to 5.00% by weight, in each case based on the total weight of the materials.

2 . The material according to claim 1 , which has no detectable content of plasticizers.

3 . The material according to claim 1 , wherein the biopolymers comprising polysaccharides including alginic acid and derivatives thereof, such as alginic acid, sodium alginate, potassium alginate, ammonium alginate, calcium alginate, or propylene glycol alginate, pectin and derivatives thereof, such as a high-ester pectin having a degree of esterification of more than 50%, low-ester pectin having a degree of esterification of 5-50%, pectic acid, and amidopectin, poly-L-guluronic acid and derivatives thereof, poly-D-mannuronic acid and derivatives thereof, agar-agar, carrageenan, furcellaran, tragacanth, gum arabic, xanthan gum, karaya gum, gellan gum, or mixtures thereof.

4 . The material according to claim 1 having a dry bulk density of 50 kg/m 3 to 1000 kg/m 3 .

5 . The material according to claim 1 is selected from the following list:
Autoclaved aerated concrete
Foamed concrete/foamed cement
Alkali-activated building materials (geopolymers)
Porous refractory materials (refractory ceramics, refractory concrete), i.e. materials that are used in high-temperature processes (>600° C.) or for lining furnaces or thermal aggregates
Porous mineral insulation materials for the construction industry based on foamed concrete (hydraulic) or aerated concrete (autoclaved)
Porous mineral insulation materials for industrial insulation of pipes, containers, boilers, furnaces, heating cabinets based on foamed concrete (hydraulic) or aerated concrete (autoclaved)
Foamed ceramic
Lime foam
Porous air-hardening lime hardened by carbonation in air or a CO 2 -enriched atmosphere or in liquid CO 2
Mineral-based porous sound absorbers
Porous granulates for lightweight concrete

6 . A process for producing calcium-containing porous mineral materials according to claim 1 , comprising:
a) producing an aqueous suspension comprising a calcium oxide source, optionally one or more further mineral raw material sources, and one or more biopolymers; b) producing a green body from the suspension from process step a); c) hardening of the green body from process step b); d) obtaining the calcium-containing porous mineral material.

7 . The process as claimed in claim 6 , wherein the biopolymers comprise polysaccharides including alginic acid and derivatives thereof, such as alginic acid, sodium alginate, potassium alginate, ammonium alginate, calcium alginate, and propylene glycol alginate, pectin and derivatives thereof, such as high-ester pectin having a degree of esterification of more than 50%, low-ester pectin having a degree of esterification of 5-50%, pectic acid, and amidopectin, poly-L-guluronic acid and derivatives thereof, poly-D-mannuronic acid and derivatives thereof, agar-agar, carrageenan, furcellaran, tragacanth, gum arabic, xanthan gum, karaya gum, gellan gum, or mixtures thereof.

8 . The process according to claim 6 , wherein the proportion by weight of the biopolymers in the dry compound of the suspension is in the range from 0.001% to 5.0% by weight based on the total weight of the dry compound.

9 . The process according to claim 6 , wherein the dry compound of the suspension contains sulfate-containing materials in a weight proportion of 0% to 10% by weight based on the total weight of the dry compound.

10 . The process according to claim 9 , wherein the sulfate-containing materials comprise gypsum, anhydrite, bassanite, portland cement, or mixtures thereof.

11 . The process according to claim 6 , wherein the dry compound of the suspension is free of plasticizers.

12 . (canceled)

Assignees

• Fraunhofer Ges Forschung

Inventors

• Kaiser Christian
• Thome Volker
• Seifert Severin
• Dittrich Sebastian
• Schober Georg

Classifications

• C04B28/006 Primary

  containing mineral polymers, e.g. geopolymers of the Davidovits type · CPC title

• C04B28/18 Primary

  containing mixtures of the silica-lime type · CPC title

• C04B2111/1018

  Gypsum free or very low gypsum content cement compositions · CPC title

• C04B28/10

  Lime cements or magnesium oxide cements · CPC title

• Y02P40/10

  Production of cement, e.g. improving or optimising the production methods; Cement grinding · CPC title