Compatibilized polymer compositions

Patent metadata

Field	Value
Publication number	US-2023212395-A1
Application number	US-202318177196-A
Country	US
Kind code	A1
Filing date	Mar 2, 2023
Priority date	Apr 29, 2016
Publication date	Jul 6, 2023
Grant date	—

Abstract

A polymer composition includes a poly(para-phenylene sulfide) (PPS), at least one poly(aryl ether sulfone) (PAES), and at least one alkali metal carbonate. Preferably, the polymer composition is free or substantially free of solvent. A method includes melt mixing a poly(para-phenylene sulfide) (PPS), at least one poly(aryl ether sulfone) (PAES), and at least one alkali metal carbonate.

First claim

1 - 15 . (canceled)

16 . A polymer composition comprising:
i) a poly(para-phenylene sulfide) (PPS); ii) at least one poly(aryl ether sulfone) (PAES); and iii) about 0.05 to about 2 wt. % of at least one alkali metal carbonate, based on the total weight of polymers in the composition, wherein the weight ratio of the poly(para-phenylene sulfide) (PPS) to the at least one poly(aryl ether sulfone) (PAES) ranges from 0.2 to 20; wherein i) the at least one poly(aryl ether sulfone) (PAES) is a reactive poly(aryl ether sulfone) (rPAES), or ii) the polymer composition further comprises at least one reactive poly(aryl ether sulfone) (rPAES), wherein the reactive poly(aryl ether sulfone) (rPAES) includes —OH end groups in a concentration greater than 5 μeq/g of the reactive poly(aryl ether sulfone) (rPAES).

17 . The polymer composition of claim 16 , wherein the polymer composition does not comprise solvent(s) or comprises solvent(s) in an amount not exceeding 2 wt. % based on the total weight of the composition.

18 . The polymer composition of claim 16 , wherein the poly(aryl ether sulfone) (PAES) is selected from the group consisting of a polysulfone (PSU), a polyethersulfone (PES) and a polyphenylsulfone (PPSU).

19 . The polymer composition of claim 16 , wherein the at least one alkali metal carbonate comprises sodium carbonate, potassium carbonate, lithium carbonate, cesium carbonate, or a combination thereof.

20 . The polymer composition of claim 16 , wherein the at least one alkali metal carbonate comprises potassium carbonate.

21 . The polymer composition of claim 16 , wherein the at least one alkali metal carbonate is potassium carbonate in an amount ranging from about 0.1 to about 0.5 wt. % based on the total weight of polymers in the polymer composition.

22 . The polymer composition of claim 16 , wherein:
the weight ratio of the poly(para-phenylene sulfide) (PPS) to the at least one poly(aryl ether sulfone) (PAES) ranges from 0.5 to 5, and the polymer composition includes from 0.15 to 0.4 wt. % of the least one alkali metal carbonate based on the total weight of polymers in the composition.

23 . The polymer composition of claim 22 , wherein the polymer composition includes from 0.15 to 0.4 wt. % of potassium carbonate based on the total weight of polymers in the composition.

24 . The polymer composition of claim 16 , wherein the poly(para-phenylene sulfide) (PPS) is an acid-washed poly(para-phenylene sulfide) (PPS).

25 . The polymer composition of claim 16 , further comprising an acid component having a pKa≤7.5.

26 . The polymer composition of claim 16 , wherein the polymer composition includes either:
a dispersed phase with a surface area per dispersed particle of s about 4 μm 2 , or a co-continuous phase wherein the average width of ribbons of a single polymer is less than or equal to about 2 μm, wherein the average width is calculated by taking 10 random measurements of the ribbon width, discarding the longest and shortest measurements, and dividing the sum of the remaining measurements by 8.

27 . The polymer composition of claim 16 , wherein the polymer composition is free or substantially free of a polyetherimide (PEI) or free or substantially free of an epoxy.

28 . The polymer composition of claim 16 , wherein the at least one poly(aryl ether sulfone) (PAES) in the polymer composition comprises a polyethersulfone (PES) and a reactive polyethersulfone (rPES).

29 . A method of making a polymer composition comprising melt mixing:
i) a poly(para-phenylene sulfide) (PPS); ii) at least one poly(aryl ether sulfone) (PAES); and iii) about 0.05 to about 2 wt. % of at least one alkali metal carbonate, based on the total weight of polymers in the composition, wherein:
the weight ratio of the poly(para-phenylene sulfide) (PPS) to the at least one poly(aryl ether sulfone) (PAES) ranges from 0.2 to 20, and
the polymer composition is substantially free of solvent; and
wherein i) the at least one poly(aryl ether sulfone) (PAES) is a reactive poly(aryl ether sulfone) (rPAES), or ii) the polymer composition further comprises at least one reactive poly(aryl ether sulfone) (rPAES), wherein the reactive poly(aryl ether sulfone) (rPAES) includes —OH end groups in a concentration greater than 5 μeq/g of the reactive poly(aryl ether sulfone) (rPAES).

30 . The method of claim 29 , wherein the method comprises:
(a1) contacting the poly(para-phenylene sulfide) (PPS), the at least one poly(aryl ether sulfone) (PAES), and the alkali metal carbonate to form a first initial mixture; (a2) contacting the poly(para-phenylene sulfide) (PPS) with the alkali metal carbonate to form a second initial mixture, and subsequently contacting the second initial mixture with the at least one poly(aryl ether sulfone) (PAES) to form a second mixture; (a3) contacting the at least one poly(aryl ether sulfone) (PAES) with the alkali metal carbonate to form a third initial mixture, and subsequently contacting the third initial mixture with the poly(para-phenylene sulfide) (PPS) to form a third mixture; or (a4) contacting the poly(para-phenylene sulfide) (PPS) and the at least one poly(aryl ether sulfone) (PAES) to form a fourth initial mixture and subsequently contacting the fourth initial mixture with the alkali metal carbonate to form a forth mixture; and (b) optionally contacting the first initial mixture, the second mixture, the third mixture, or the fourth mixture with an acid component having a pKa≤7.5.

31 . The method of claim 29 , wherein the at least one poly(aryl ether sulfone) (PAES) in the polymer composition comprises a polyethersulfone (PES) and a reactive polyethersulfone (rPES).

32 . A polymer composition made by the method of claim 29 .

33 . A shaped article comprising the polymer composition of claim 16 .

34 . A polymer composition comprising:
i) a poly(para-phenylene sulfide) (PPS); ii) at least one poly(aryl ether sulfone) (PAES); and iii) about 0.05 to about 2 wt. % of at least one alkali metal carbonate, based on the total weight of polymers in the composition, wherein the weight ratio of the poly(para-phenylene sulfide) (PPS) to the at least one poly(aryl ether sulfone) (PAES) ranges from 0.2 to 20, wherein the PPS is acid washed and in reactive form and includes at least 5 microequivalents per gram (μeq/g) of hydroxyl (—OH) end groups, wherein the at least one alkali metal carbonate comprises sodium carbonate, potassium carbonate or a combination thereof, and wherein the PAES denotes a polymer of which at least 60 mol % of recurring units are recurring units (R PAES ) of formula (K):

in which:
each R, equal to or different from each other, is selected from a halogen, an alkyl, an alkenyl, an alkynyl, an aryl, an ether, a thioether, a carboxylic acid, an ester, an amide, an imide, an alkali or alkaline earth metal sulfonate, an alkyl sulfonate, an alkali or alkaline earth metal phosphonate, an alkyl phosphonate, an amine, and a quaternary ammonium;
each h, equal to or different from each other, is an integer ranging from 0 to 4; and
T is selected from the group consisting of a bond, a sulfone group [—S(═O) 2 —], and a group —C(R j )(R k )—, where R j and R k , equal to or different from each other, are selected from a hydrogen, a halogen, an alkyl, an alkenyl, an alkynyl, an ether, a thioether, a carboxylic acid, an ester, an amide, an imide, an alkali or alkaline

Assignees

• Solvay Specialty Polymers Usa

Inventors

• Jeol Stéphane
• Momtaz Maryam
• Bushelman Corinne
• Sattich William E

Classifications

• C08K2003/262

  Alkali metal carbonates · CPC title

• C08K3/26

  Carbonates; Bicarbonates · CPC title

• C08K3/32

  Phosphorus-containing compounds · CPC title

• C08L81/02 Primary

  Polythioethers; Polythioether-ethers · CPC title

• C08L81/06 Primary

  Polysulfones; Polyethersulfones · CPC title