Method of preparing positive electrode active material for lithium secondary battery

Patent metadata

Field	Value
Publication number	US-2023202863-A1
Application number	US-202318176669-A
Country	US
Kind code	A1
Filing date	Mar 1, 2023
Priority date	Oct 27, 2020
Publication date	Jun 29, 2023
Grant date	—

Abstract

The present invention relates to a method of preparing a positive electrode active material for a lithium secondary battery, and more particularly, to a method of preparing a positive electrode active material for a lithium secondary battery, which is able to improve electrochemical properties and stability by controlling the specific surface area of a positive electrode active material.

First claim

What is claimed is:

1 . A method of preparing a positive electrode active material for a lithium secondary battery, comprising:
(a) preparing a first mixture by mixing a nickel composite precursor, a lithium compound and a first additive; (b) obtaining a first lithium composite oxide through first thermal treatment of the first mixture; (c) preparing a second mixture by mixing the first lithium composite oxide and a second additive; and (d) obtaining a second lithium composite oxide through second thermal treatment of the second mixture, wherein the first additive and the second additive each independently comprise at least one selected from Al 2 O 3 , Al(OH) 3 , AlPO 4 , Al(PO 3 ) 3 , WO 3 , Mg(OH) 2 , NH 4 F, TiO 2 , H 3 BO 3 , H 2 B 4 O 7 , B 2 O 3 , B 2 O 5 , C 6 H 5 B(OH) 2 , (C 6 H 5 O) 3 B, [(CH 3 (CH 2 ) 3 O) 3 B, C 3 H 9 B 3 O 6 , and (C 3 H 7 O 3 )B, and the temperature for the second thermal treatment is lower than that of the first thermal treatment.

2 . The method of claim 1 , wherein, in (a), the first additive is mixed to be 0.5 to 1.0 mol % with respect to the nickel composite precursor.

3 . The method of claim 1 , wherein the BET specific surface area of the first lithium composite oxide obtained in (b) is 1.5 to 1.8 m 2 /g.

4 . The method of claim 1 , wherein a ratio (s2/s1) of the BET specific surface area (s2) of the first lithium composite oxide to the BET specific surface area (s1) of the nickel composite precursor is more than 0.098 and less than 0.137.

5 . The method of claim 1 , wherein the temperature for the first thermal treatment in (b) is 600 to 800° C.

6 . The method of claim 1 , wherein the second additive in (c) is mixed to be 0.1 to 0.5 mol % with respect to the first lithium composite oxide.

7 . The method of claim 1 , wherein, in (c), the second additive comprises at least one selected from Al 2 O 3 , Al(OH) 3 , H 3 BO 3 , B 2 O 3 , and B 2 O 5 .

8 . The method of claim 1 , wherein the BET specific surface area of the second lithium composite oxide obtained in (d) is 0.8 to 1.2 m 2 /g.

9 . The method of claim 1 , wherein a ratio (s3/s2) of the BET specific surface area (s3) of the second lithium composite oxide to the BET specific surface area (s2) of the first lithium composite oxide is more than 0.394 and less than 0.823.

10 . The method of claim 1 , wherein the temperature for the second thermal treatment in (d) is 200 to 500° C.

11 . The method of claim 1 , wherein the second lithium composite oxide is represented by Formula 1 below,
Li w Ni 1−(x+y+z) Co x M1 y M2 z O 2   [Formula 1]
(Here, M1 is at least one selected from Mn and Al, M2 is at least one selected from Mn, B, Ba, Ce, Hf, Ta, Cr, F, Mg, Al, Cr, V, Ti, Fe, Zr, Zn, Si, Y, Nb, Ga, Sn, Mo, W, P, Sr, Ge, Nd, Gd and Cu, M1 and M2 are different elements, 0.5≤w≤1.5, 0≤x≤0.50, 0<y≤0.20, and 0≤z≤0.20).

12 . The method of claim 11 , further comprising: before (c),
mixing at least one selected from a M1-containing raw material and a M2-containing raw material with the first lithium composite oxide, and thermally treating the resulting mixture in a temperature range from 600 to 800° C.

13 . The method of claim 1 , further comprising: before (c),
reacting the first lithium composite oxide with a washing solution.

14 . A positive electrode comprising the positive electrode active material prepared according of claim 1 .

15 . A lithium secondary battery using the positive electrode of claim 14 .

Assignees

• Ecopro Bm Co Ltd

Inventors

• Jeon Jae Woo
• Suh Jun Won
• Yun Jin Kyeong
• Son Jin Oh
• Yun Mi Hye
• Choi Moon Ho
• Noh Hyung Joo
• Na Su Bin
• Kim Ju Chul

Classifications

• C01P2006/12

  Surface area · CPC title

• H01M4/62

  Selection of inactive substances as ingredients for active masses, e.g. binders, fillers · CPC title

• C01G53/82 Primary

  Compounds containing nickel, with or without oxygen or hydrogen, and containing two or more other elements · CPC title

• H01M4/366

  as layered products · CPC title

• C01G53/50 Primary

  of the type (MnO2)n-, e.g. Li(NixMn1-x)O2 or Li(MyNixMn1-x-y)O2 · CPC title