Method for producing liquid pig iron from a DRI product

Patent metadata

Field	Value
Publication number	US-2023175087-A1
Application number	US-202117922236-A
Country	US
Kind code	A1
Filing date	Mar 2, 2021
Priority date	Apr 30, 2020
Publication date	Jun 8, 2023
Grant date	—

Abstract

A method for producing liquid pig iron comprises: i) providing a DRI product with an iron content of at least 75.0 wt. %, a carbon content of at least 0.10 wt. % and a content of acidic and basic slag components, comprising CaO, SiO2, MgO and Al2O3 of max. 15.0 wt. %; ii) supplying the DRI product, adding slag formers, into an electrically operated smelting unit; iii) optionally supplying further iron and/or carbon components into the electrically operated smelting unit; iv) smelting the DRI product and optionally the further iron and/or carbon components in the presence of the slag formers, so that a liquid pig iron phase and a liquid slag phase are formed; v) adjusting the slag phase such that it has a basicity of (CaO+MgO/SiO2) from 0.95 to 1.5; vi) tapping the liquid pig iron phase; and vii) tapping and granulating the slag phase.

First claim

1 .- 21 . (canceled)

22 . A method for producing liquid pig iron, comprising:
i) providing a directly reduced iron product ( 1 ) (DRI product) with an iron content of at least 75.0 wt. %, a carbon content of at least 0.10 wt. %, and a content of acidic and basic slag components, selected from the group consisting of CaO, SiO 2 , MgO and Al 2 O 3 , of max. 15.0 wt. %; ii) supplying the DRI product ( 1 ) and slag formers ( 2 ) into an electrically operated smelting unit ( 3 ); iii) optionally supplying further iron and/or carbon components ( 5 ) into the electrically operated smelting ( 3 ) unit; iv) smelting the DRI product ( 1 ) and optionally the further iron and/or carbon components ( 5 ) in presence of the slag formers ( 2 ), so that a liquid pig iron phase ( 6 ) and a liquid slag phase ( 7 ) are formed; v) adjusting the slag phase ( 7 ) such that it has a basicity of (CaO+MgO/SiO 2 ) from 0.95 to 1.5; vi) tapping the liquid pig iron phase ( 6 ); and vii) tapping and granulating the slag phase ( 7 ).

23 . The method according to claim 22 ,
wherein the slag phase ( 7 ) is adjusted such that it has a basicity of (CaO+MgO/SiO 2 ) from 1.0 to 1.25.

24 . The method according to claim 22 ,
wherein the slag phase ( 7 ) is adjusted such that it has a viscosity of 0.30 to 0.50 Pa*s.

25 . The method according to claim 22 ,
wherein the slag phase ( 7 ) is tapped at a tapping temperature in the range from 1300° C. to 1600° C.

26 . The method according to claim 22 ,
wherein the slag formers ( 2 ) are selected from the group consisting of CaO, SiO 2 , MgO, Al 2 O 3 , and mixed oxides thereof.

27 . The method according to claim 22 ,
wherein the slag formers ( 2 ) in accordance with step ii) are supplied up to a fraction of max. 10.0 wt. %, based on an amount of the DRI product.

28 . The method according to claim 22 ,
wherein the iron and/or carbon components ( 5 ) in accordance with step iii) are supplied up to a fraction of max. 20.0 wt. %, based on an amount of the DRI product.

29 . The method according to claim 22 ,
wherein granulation is carried out as wet or dry granulation.

30 . The method according to claim 22 ,
wherein supplying the slag formers ( 2 ) is carried out automatically via a process model integrated into a plant automation system, and wherein a quantity of the slag formers ( 2 ) is calculated by the process model and determined as a function of process parameters.

31 . The method according to claim 22 ,
wherein the directly reduced iron product ( 1 ) is supplied to the smelting unit ( 3 )
in hot form as HDRI product,
in cold form as CDRI product,
in hot briquette form as HBI product and/or
in particulate form with an average particle diameter of max. 10.0 mm.

32 . The method according to claim 22 ,
wherein the liquid pig iron phase ( 6 ) formed in accordance with step iv) is carburized to a carbon content of at least 2.50 wt. %.

33 . The method according to claim 22 ,
wherein the DRI product ( 1 ) and/or the slag formers ( 2 ) are supplied to the smelting unit ( 3 ) from a thermally insulated bunker reservoir ( 15 ).

34 . The method according to claim 22 ,
wherein the DRI product ( 1 ) is produced in a direct reduction plant ( 11 ) and is supplied to the smelting unit ( 3 ) and/or a bunker reservoir ( 15 ) under a protective gas atmosphere via a conveying device ( 14 ).

35 . A granulated slag obtained by the method according to claim 22 , comprising:
35.0-40.0 wt. % SiO 2 , 30.0-43.0 wt. % CaO, 8.0-12.0 wt. % Al 2 O 3 , 4.0-12.0 wt. %- MgO, along with unavoidable impurities comprising iron (Fe), MnO 2 and/or sulfur (S).

36 . The granulated slag according to claim 35 ,
wherein a total content of SiO 2 , CaO and MgO amounts to at least 70.0 wt. %.

37 . The granulated slag according to claim 35 , comprising
a vitreous solidification fraction of at least 95.0 wt. %, and a total iron content of max. 1.0 wt. %.

38 . The granulated slag according to any claim 35 , having an eluate allocation value of 0 or 1.

39 . A plant ( 10 ) for producing liquid pig iron, comprising:
a direct reduction plant ( 11 ) for producing a directly reduced iron product ( 1 ); an electrically operated smelting unit ( 3 ) in which the directly reduced iron product ( 1 ) can be smelted; and a conveying device ( 14 ) via which the directly reduced iron product ( 1 ) can be transported from the direct reduction plant ( 11 ) to the smelting unit ( 3 ).

40 . The plant ( 10 ) according to claim 39 ,
wherein the smelting unit ( 3 ) is an electric arc furnace (EAF), a submerged arc furnace (SAF), or an induction furnace (IF).

41 . The plant ( 10 ) according to claim 39 ,
wherein the conveying device ( 14 ) is a metal conveyor belt with a protective gas atmosphere.

42 . The plant ( 10 ) according to claim 39 , further comprising a thermally insulated bunker reservoir ( 15 ).

Assignees

• Sms Group Gmbh

Inventors

• Schlüter Jochen
• Nörthemann Ralf
• Henkel Thomas
• Tockert Paul

Classifications

• C21B13/12 Primary

  in electric furnaces · CPC title

• C21B13/0013

  introduction of iron oxide into a bath of molten iron containing a carbon reductant · CPC title

• C21B5/04

  Making slag of special composition · CPC title

• Y02P10/134

  by avoiding CO2, e.g. using hydrogen · CPC title

• C21B13/0006

  obtaining iron or steel in a molten state · CPC title