Process and system for purification of citric acid

Patent metadata

Field	Value
Publication number	US-2023174450-A1
Application number	US-202017924264-A
Country	US
Kind code	A1
Filing date	Jun 8, 2020
Priority date	Jun 8, 2020
Publication date	Jun 8, 2023
Grant date	—

Abstract

Citric acid is purified to remove metal ions through a two-step filtration process. A first filter is used to perform a first filtration, then a second filter is used to perform a second filtration on citric acid solution that has been subject to the first filtration. The first and second filters can include the same filter membrane material. The filter used as the first filter can be a relatively dirtier, more loaded filter compared to the filter used as the second filter. The first filtration can be performed over four hours of recirculating the citric acid solution through the first filter, and the second filtration can be performed over approximately two and one half hours of recirculating the citric acid solution through the second filter. Such a purification process can remove calcium and magnesium ions to render citric acid suitable as a cleaning solution in semiconductor processing.

First claim

1 . A method for purifying citric acid, comprising:
performing a first filtration of citric acid using a first filter; and performing a second filtration, the second filtration being performed on the citric acid following the first filtration, using a second filter separate from the first filter.

2 . The method of claim 1 , wherein the first filter and the second filter each include a same filter membrane material.

3 . The method of claim 2 , further comprising selecting a filter having comparatively greater trapped metal ions to be used as the first filter, and a filter having comparatively fewer trapped metal ions to be used as the second filter.

4 . The method of claim 3 , further comprising replacing the first filter after completion of the first filtration.

5 . The method of claim 1 , wherein the performing of the first filtration includes recirculating the citric acid through a fluid circuit including the first filter for approximately 4 hours.

6 . The method of claim 1 , wherein the performing of the second filtration includes recirculating the citric acid through a fluid circuit including the second filter for approximately 2.5 hours.

7 . The method of claim 1 , wherein the citric acid is a 30% solution of citric acid.

8 . The method of claim 1 , wherein after the second filtration, the citric acid includes less than 5 parts per billion (ppb) of magnesium ions, and less than 10 ppb of calcium ions.

9 . A citric acid purification system, comprising:
a tank configured to hold a citric acid solution; a first filter configured to remove metal ions from the citric acid solution; a second filter configured to remove metal ions from the citric acid solution, in parallel with the first filter; one or more valves configured to direct a flow of a fluid from the tank to one of the first filter or the second filter; a return line, configured to convey the fluid from the one of the first filter or the second filter to the tank; and a controller configured to control the one or more valves such that the citric acid solution is first circulated through one of the first filter or the second filter for a first predetermined amount of time, and then the citric acid solution is circulated through the other of the first filter or the second filter for a second predetermined amount of time.

10 . The citric acid purification system of claim 9 , further comprising an outlet line including an outlet valve, connected to the return line.

11 . The citric acid purification system of claim 9 , wherein the first filter and the second filter each include a same membrane material.

12 . The citric acid purification system of claim 9 , wherein the first filter is included in a first replaceable filter cartridge and the second filter is included in a second replaceable filter cartridge.

13 . The citric acid purification system of claim 9 , wherein the first predetermined amount of time is approximately 4 hours and the second predetermined amount of time is approximately 2.5 hours.

14 . The citric acid purification system of claim 9 , wherein the controller is further configured to determine when to replace one or more of the first filter and the second filter based on a loading of the one or more of the first filter and the second filter.

15 . The citric acid purification system of claim 14 , wherein the loading of the one or more of the first filter and the second filter is determined based on a number of purification cycles performed since a most recent replacement of the one or more of the first filter and the second filter.

Assignees

• Entegris Inc

Inventors

• Song Yuxin
• Wu Xianxin
• Zhou Chao
• Dong Yu
• Jiang Ping
• Du Zhengzheng
• Song Zicheng

Classifications

• B01D61/12 Primary

  Controlling or regulating · CPC title

• C07C51/42 Primary

  Separation; Purification; Stabilisation; Use of additives · CPC title

• B01D2313/44

  Cartridge types · CPC title

• B01D61/22

  Controlling or regulating · CPC title

• B01D61/00

  Processes of separation using semi-permeable membranes, e.g. dialysis, osmosis or ultrafiltration; Apparatus, accessories or auxiliary operations specially adapted therefor (separation of gases or vapours by diffusion B01D53/22) · CPC title