Cerium oxide nanoparticles, methods for fabricating the same and methods for fabricating a semiconductor device using the same

Patent metadata

Field	Value
Publication number	US-2023167566-A1
Application number	US-202217874442-A
Country	US
Kind code	A1
Filing date	Jul 27, 2022
Priority date	Nov 30, 2021
Publication date	Jun 1, 2023
Grant date	—

Abstract

Cerium oxide nanoparticles and methods of fabricating the same are provided. The cerium oxide nanoparticles may be fabricated by a method that may include injecting metal ions into cerium oxide particles and then removing (e.g., desorbing) at least some of the injected metal ions from the cerium oxide particles.

First claim

1 . A method for fabricating cerium oxide nanoparticles, the method comprising:
providing a structure that includes a cathode functional layer including cerium oxide particles, an ion generating layer including metal and a separating membrane between the cathode functional layer and the ion generating layer; applying a voltage across the cathode functional layer and the ion generating layer, thereby injecting metal ions generated from the ion generating layer into the cathode functional layer; and cleaning the cathode functional layer to remove at least some of the metal ions from the cathode functional layer.

2 . The method for fabricating cerium oxide nanoparticles of claim 1 , wherein an oxygen vacancy ratio of surfaces of the cerium oxide nanoparticles is about 20% to about 50% after cleaning the cathode functional layer.

3 . The method for fabricating cerium oxide nanoparticles of claim 1 , wherein the ion generating layer includes at least one of an alkali metal, an alkaline earth metal, an alkali metal-containing alloy, and an alkaline earth metal-containing alloy.

4 . The method for fabricating cerium oxide nanoparticles of claim 3 , wherein the ion generating layer includes at least one of lithium (Li), sodium (Na), potassium (K), magnesium (Mg), and calcium (Ca).

5 . The method for fabricating cerium oxide nanoparticles of claim 1 , wherein the separating membrane includes an electrolyte including metal ions and a porous polymer that is wetted with the electrolyte, and
the metal ions of the electrolyte and the metal ions generated from the ion generating layer include the same metallic element.

6 . The method for fabricating cerium oxide nanoparticles of claim 1 , wherein cleaning of the cathode functional layer includes cleaning of the cathode functional layer using an organic solvent.

7 . The method for fabricating cerium oxide nanoparticles of claim 6 , wherein cleaning of the cathode functional layer further includes cleaning of the cathode functional layer using at least one of distilled water and an acidic aqueous solution after cleaning the cathode functional layer using the organic solvent.

8 . The method for fabricating cerium oxide nanoparticles of claim 1 , further comprising drying the cathode functional layer after cleaning the cathode functional layer.

9 . A method for fabricating cerium oxide nanoparticles, the method comprising:
providing a cell that includes a cathode functional layer including cerium oxide particles, an ion generating layer including lithium (Li), and a separating membrane between the cathode functional layer and the ion generating layer; applying a voltage to the cell to inject lithium ions into the cathode functional layer; separating the cathode functional layer from the cell; and cleaning the cathode functional layer using an organic solvent.

10 . The method for fabricating cerium oxide nanoparticles of claim 9 , wherein an oxygen vacancy ratio of surfaces of the cerium oxide nanoparticles is about 20% to about 50% after cleaning the cathode functional layer.

11 . The method for fabricating cerium oxide nanoparticles of claim 9 , wherein the cathode functional layer is fabricated by providing a slurry including CeO 2 powder, a binder, a conductive material, and an organic solvent,
applying the slurry onto a base layer, and
drying the slurry applied onto the base layer.

12 . The method for fabricating cerium oxide nanoparticles of claim 9 , wherein the separating membrane includes an electrolyte including lithium ions and a porous polymer that is wetted with the electrolyte.

13 . The method for fabricating cerium oxide nanoparticles of claim 12 , wherein the electrolyte includes LiPF 6 .

14 . The method for fabricating cerium oxide nanoparticles of claim 9 , wherein the organic solvent includes at least one of acetone, ethanol, anhydrous tetrahydrofuran (THF), benzene, potassium hydroxide/methanol, methanol, toluene, dichloromethane, hexane, dimethylmethanamide, dimethylformamide (DMF), diisopropyl ether, diethyl ether, dioxane, dimethylacetamide (DMA), dimethyl sulfoxide (DMSO), and chlorobenzene.

15 . The method for fabricating cerium oxide nanoparticles of claim 9 , further comprising after cleaning the cathode functional layer with the organic solvent, cleaning the cathode functional layer with distilled water, cleaning the cathode functional layer with an acidic aqueous solution, and neutralizing the cathode functional layer.

16 . The method for fabricating cerium oxide nanoparticles of claim 15 , wherein the acidic aqueous solution includes an acetic acid aqueous solution.

17 . A cerium oxide nanoparticle fabricated by a method comprising:
injecting metal ions into cerium oxide particles; and then removing at least some of the metal ions from the cerium oxide particles, wherein the cerium oxide nanoparticle is represented by Chemical formula 1:
.

18 . The cerium oxide nanoparticle of claim 17 , wherein an oxygen vacancy ratio of a surface of the cerium oxide nanoparticle is about 20% to about 50% after removing at least some of the metal ions from the cerium oxide particle.

19 . The cerium oxide nanoparticle of claim 17 , wherein the cerium oxide nanoparticle has a size of about 3 nm to 10 nm.

20 . The cerium oxide nanoparticle of claim 17 , wherein the metal ions include lithium ions.

21 - 29 . (canceled)

Assignees

• Samsung Electronics Co Ltd
• Univ Yonsei Iacf

Inventors

• Kim In Kwon
• Lee Kyu Hyoung
• Kim Sang Kyun
• Park Chul Oh
• Kim Min Young
• Lee Hyo San

Classifications

• C25C5/00 Primary

  Electrolytic production, recovery or refining of metal powders or porous metal masses · CPC title

• C25C7/002 Primary

  of cells comprising at least an electrode made of particles (C25C7/005, C25C7/02 - C25C7/06 take precedence) · CPC title

• C25C7/04

  Diaphragms; Spacing elements · CPC title

• C25C7/08

  Separating of deposited metals from the cathode · CPC title

• H10P52/403

  of conductive or resistive materials · CPC title