Oligomer and composition

Patent metadata

Field	Value
Publication number	US-2023141271-A1
Application number	US-202217940451-A
Country	US
Kind code	A1
Filing date	Sep 8, 2022
Priority date	Nov 5, 2021
Publication date	May 11, 2023
Grant date	—

Abstract

An oligomer includes a repeating unitand a repeating unitor a combination thereof. The repeating number of the repeating unit (a) and the repeating number of the repeating unit (b1), (b2), or a combination thereof have a ratio of 1:1 to 20:1. Each Q is independently substituted or unsubstituted aliphatic group, cycloaliphatic group, aromatic group, or siloxane group. X can beand Y can beor a combination thereof, and Z can beor a combination thereof.

First claim

What is claimed is:

1 . An oligomer, comprising:
a repeating unit

and
a repeating unit

or a combination thereof,
wherein the repeating number of the repeating unit (a) and the repeating number of the repeating unit (b1), (b2), or a combination thereof have a ratio of 1:1 to 20:1;
each Q is independently substituted or unsubstituted aliphatic group, cycloaliphatic group, aromatic group, or siloxane group;
X is

wherein 12≥a≥4; 12≥b≥4; each of R 1 is independently hydrogen, C 4-12 alkyl group, C 4-12 alkenyl group, or C 4-12 alkynyl group, and at least two R 1 is not hydrogen;
Y is

or a combination thereof, wherein c is 0 or 1; d is 0 or 1; each of R 2′ is independently hydrogen or C 1-10 alkyl group, and at least one of R 2′ is not hydrogen; and each of R 2 is independently hydrogen or C 1-10 alkyl group; and
Z is

or a combination thereof, wherein 12≥e≥1; 12≥f≥1; 12≥g≥1; and each of R 3 is independently hydrogen or C 1-10 alkyl group.

2 . The oligomer as claimed in claim 1 , wherein the oligomer comprises the repeating units (a), (b1), and (b2), and the repeating number of the repeating unit (b1) and the repeating number of the repeating unit (b2) have a ratio of 1:1 to 5:1.

3 . The oligomer as claimed in claim 1 , wherein the oligomer comprises the repeating units (a) and (b1), and the repeating number of the repeating unit (a) and the repeating number of the repeating unit (b1) have a ratio of 1:1 to 5:1.

4 . The oligomer as claimed in claim 1 , wherein

is

wherein R 4 is C 1-5 alkylene group, —SO 2 —, —O—, —C(═O)—, or a single bond.

5 . The oligomer as claimed in claim 1 , wherein the repeating unit (a) is

and the repeating unit (b1) is

6 . The oligomer as claimed in claim 1 , wherein the repeating unit (a) is

and the repeating unit (b1) is

7 . The oligomer as claimed in claim 1 , wherein the repeating unit (a) is

and the repeating unit (b1) is

8 . The oligomer as claimed in 1 , wherein the repeating unit (a) is

and the repeating unit (b1) is

9 . The oligomer as claimed in 1 , wherein the repeating unit (a) is

and the repeating unit (b2) is

10 . The oligomer as claimed in 1 , wherein the repeating unit (a) is

the repeating unit (b1) is

and the repeating unit (b2) is

11 . The oligomer as claimed in claim 1 , having a terminal amino group or a terminal group modified to contain a double bond.

12 . A composition, comprising:
an oligomer; and a radical initiator, wherein the oligomer has a terminal group modified to contain a double bond, and includes: a repeating unit (a)

and
a repeating unit

or a combination thereof,
wherein the repeating number of the repeating unit (a) and the repeating number of the repeating unit (b1), (b2) or a combination thereof have a ratio of 1:1 to 20:1;
each Q is independently substituted or unsubstituted aliphatic group, cycloaliphatic group, aromatic group, or siloxane group;
X is

wherein 12≥a≥4; 12≥b≥4; each of R 1 is independently hydrogen, C 4-12 alkyl group, C 4-12 alkenyl group, or C 4-12 alkynyl group, and at least two R 1 is not hydrogen;
Y is

or a combination thereof, wherein c is 0 or 1; d is 0 or 1; each of R 2′ is independently hydrogen or C 1-10 alkyl group, and at least one of R 2′ is not hydrogen; and each of R 2 is independently hydrogen or C 1-10 alkyl group; and
Z is

or a combination thereof, wherein 12≥e≥1; 12≥f≥1; 12≥g≥1; and each of R 3 is independently hydrogen or C 1-10 alkyl group.

13 . The composition as claimed in claim 12 , further comprising a polyphenylene ether resin having a terminal methacryloxy group, a polyphenylene ether resin having a terminal vinyl benzyl ether group, or a combination thereof.

Assignees

• Ind Tech Res Inst

Inventors

• Kuo Cheng-Po
• Wu Kuan-Han
• Kuo Shin-Liang
• Huang Shu-Chuan
• Chang Wen-Sheng
• Hang Jian-Yi

Classifications

• C07D519/00 Primary

  Heterocyclic compounds containing more than one system of two or more relevant hetero rings condensed among themselves or condensed with a common carbocyclic ring system not provided for in groups C07D453/00 or C07D455/00 · CPC title

• C08G73/1046 Primary

  Polyimides containing oxygen in the form of ether bonds in the main chain · CPC title

• C08G73/1014

  in the form of (mono)anhydrid · CPC title