Dual function current collector

Patent metadata

Field	Value
Publication number	US-2023133093-A1
Application number	US-202218147899-A
Country	US
Kind code	A1
Filing date	Dec 29, 2022
Priority date	Feb 19, 2016
Publication date	May 4, 2023
Grant date	—

Abstract

A battery can include a separator, a first current collector, a protective layer, and a first electrode. The first current collector and the protective layer can be disposed on one side of the separator. The first electrode can be disposed on an opposite side of the separator as the first current collector and the protective layer. Subjecting the battery to an activation process can cause metal to be extracted from the first electrode and deposited between the first current collector and the protective layer. The metal can be deposited to at least form a second electrode between the first current collector and the protective layer.

First claim

What is claimed is:

1 . A battery, comprising:
a separator; a first current collector; a protective layer, the first current collector and the protective layer being disposed on one side of the separator; and a first electrode, the first electrode being disposed on an opposite side of the separator as the first current collector and the protective layer; wherein subjecting the battery to an activation process causes metal to be extracted from the first electrode and deposited between the first current collector and the protective layer, the metal being deposited to at least form a second electrode between the first current collector and the protective layer.

2 . The battery of claim 1 , wherein the activation process comprises charging the battery.

3 . The battery of any of claim 1 , wherein the activation process comprising charging the battery at less than ½ C rate and/or greater than 2 volts.

4 . The battery of any of claim 1 , wherein the first current collector comprises copper (Cu) and/or plated copper.

5 . The battery of any of claim 1 , wherein the first current comprises copper foil, stainless steel foil, titanium (Ti) foil, nickel (Ni) plated copper foil, aluminum (Al) plated copper foil, and/or titanium plated copper foil.

6 . The battery of any of claim 1 , wherein the first current collector has a thickness of 10 microns.

7 . The battery of any of claim 1 , wherein the first electrode is formed from a metal oxide, a metal fluoride, a metal sulfide, and/or a doped salt.

8 . The battery of any of claim 1 , wherein the first electrode is formed from a lithium cobalt oxide (LiCoO 2 ), lithium nickel cobalt oxide (LiNiCoO 2 ), lithium manganese nickel cobalt oxide (LiNiMnCoO 2 ), lithium manganese silicon oxide (Li 2 MnSiO 4 ), lithium iron phosphate (LiFePO 4 ), lithium fluoride (LiF), and/or lithium sulfide (Li 2 S).

9 . The battery of any of claim 1 , wherein the metal extracted from the first electrode comprises lithium metal.

10 . The battery of any of claim 1 , wherein the protective layer is formed from a polymer.

11 . The battery of any of claim 1 , wherein the protective layer is formed from a crosslinked polymer and/or a non-crosslinked polymer.

12 . The battery of any of claim 1 , wherein the protective layer is formed from a polymer composite that includes a plurality of different polymers.

13 . The battery of claim 12 , wherein the polymer composite further includes one or more additives, the one or more additives comprising ceramic particles, metal salt particles, and metal stabilizers.

14 . The battery of any of claim 1 , wherein the battery further includes an electrolyte.

15 . The battery of claim 14 , wherein the electrolyte comprises a liquid electrolyte, the liquid electrolyte including metal ions, and the liquid electrolyte further including one or more organic solvents.

16 . The battery of claim 15 , wherein the metal irons comprise lithium ions, and wherein the one or more organic solvents comprise ethylene carbonate ((CH 2 O) 2 CO) and/or lithium hexafluorophosphate (Li 1 PF 6 ).

17 . The battery of claim 14 , wherein the electrolyte comprises a solid-state electrolyte.

18 . The battery of claim 17 , wherein the solid-state electrolyte comprises a glass-ceramic binary sulfide electrolyte and/or a polymer electrolyte.

19 . The battery of any of claim 1 , wherein the battery further comprises a second current collector, the second current collector being coupled with the first electrode.

20 . The battery of claim 19 , wherein the battery further comprises a safety layer, the safety layer being deposited on the second current collector, and the safety layer being configured to respond to a temperature trigger and/or a voltage trigger.

21 . The battery of any of claim 1 , wherein the metal extracted from the first electrode and deposited between the first current collector and the protective layer comprises dendrites, and wherein the protective layer is configured to prevent the dendrites from penetrating the separator and causing an internal short within the battery.

22 . The battery of any of claim 1 , wherein the activation process causes a reduction at the first electrode, the reduction extracting metal from the first electrode, and the metal extracted from the first electrode being deposited between the first current collector and the protective layer to form the second electrode in situ between the first current collector and the protective layer.

Assignees

• American Lithium Energy Corp

Inventors

• Fan Jiang

Classifications

• H01M4/136

  Electrodes based on inorganic compounds other than oxides or hydroxides, e.g. sulfides, selenides, tellurides, halogenides or LiCoFy · CPC title

• H01M10/0569

  characterised by the solvents · CPC title

• H01M10/0525

  Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries · CPC title

• H01M4/131

  Electrodes based on mixed oxides or hydroxides, or on mixtures of oxides or hydroxides, e.g. LiCoOx · CPC title

• H01M4/505

  of mixed oxides or hydroxides containing manganese for inserting or intercalating light metals, e.g. LiMn2O4 or LiMn2OxFy · CPC title