Alkaline electrolysis arrangement with deaerator and method therefor

Patent metadata

Field	Value
Publication number	US-2023131407-A1
Application number	US-202217974069-A
Country	US
Kind code	A1
Filing date	Oct 26, 2022
Priority date	Oct 26, 2021
Publication date	Apr 27, 2023
Grant date	—

Abstract

The invention relates to an electrolysis arrangement for alkaline electrolysis and a method for producing hydrogen and oxygen by electrolysis of an alkaline electrolysis medium. According to the invention, an anolyte deaerating means is arranged downstream of an anolyte gas-liquid separator and is arranged upstream of the electrolysis cell stack of the electrolysis arrangement, and/or a catholyte deaerating means is arranged downstream of a catholyte gas-liquid separator and arranged upstream of the electrolysis cell stack of the electrolysis arrangement. By this arrangement, the fact is exploited that many undesirable gas components have a much lower solubility in the alkaline electrolysis medium than in pure deionised water, which is supplied as fresh water to the electrolysis arrangement for compensation of the water consumed by the electrochemical reaction.

First claim

What is claimed is:

1 . An electrolysis arrangement for alkaline electrolysis, comprising
an electrolysis cell stack comprising a plurality of electrolysis cells for the electrochemical generation of hydrogen and oxygen from an alkaline electrolysis medium, wherein the electrolysis cell stack comprises an anode section for the generation of oxygen and a cathode section for the generation of hydrogen; an anolyte gas-liquid separator configured for the separation of oxygen gas from an oxygen loaded anolyte portion of the alkaline electrolysis medium; a catholyte gas-liquid separator configured for the separation of hydrogen gas from a hydrogen loaded catholyte portion of the alkaline electrolysis medium; an anolyte cooling means arranged downstream of the anolyte gas-liquid separator and upstream of the electrolysis cell stack, configured to cool an oxygen depleted anolyte withdrawn from the anolyte gas-liquid separator before the oxygen depleted anolyte is supplied to the electrolysis cell stack and/or a catholyte cooling means arranged downstream of the catholyte gas-liquid separator and upstream of the electrolysis cell stack, configured to cool a hydrogen depleted catholyte withdrawn from the catholyte gas-liquid separator before the hydrogen depleted catholyte is supplied to the electrolysis cell stack; an anolyte deaerating means arranged downstream of the anolyte gas-liquid separator and arranged upstream of the electrolysis cell stack and/or a catholyte deaerating means arranged downstream of the catholyte gas-liquid separator and arranged upstream of the electrolysis cell stack.

2 . The electrolysis arrangement according to claim 1 , wherein the alkaline electrolysis medium is a concentrated lye solution.

3 . The electrolysis arrangement according to claim 1 , wherein the anolyte deaerating means is arranged downstream of the anolyte gas-liquid separator and is arranged upstream of the anolyte cooling means and/or the catholyte deaerating means is arranged downstream of the catholyte gas-liquid separator and is arranged upstream of the catholyte cooling means.

4 . The electrolysis arrangement according to claim 1 , wherein an anolyte recirculation pump configured to recirculate anolyte between the anolyte gas-liquid separator and the electrolysis cell stack is arranged downstream of the anolyte deaerating means and upstream of the anolyte cooling means and/or a catholyte recirculation pump configured to recirculate catholyte between the catholyte gas-liquid separator and the electrolysis cell stack is arranged downstream of the catholyte deaerating means and upstream of the catholyte cooling means.

5 . The electrolysis arrangement according claim 1 , wherein the electrolysis arrangement comprises a hydrogen purification unit configured for the removal of oxygen and water from the hydrogen gas separated in the catholyte gas-liquid separator, whereby a purified hydrogen gas is obtainable by means of the hydrogen purification unit.

6 . The electrolysis arrangement according to claim 1 , wherein the catholyte deaerating means is configured for the degassing of the hydrogen depleted catholyte by means of hydrogen gas supplied to the catholyte deaerating means.

7 . The electrolysis arrangement according to claim 1 , wherein the catholyte deaerating means is configured for the degassing of the hydrogen depleted catholyte by means of hydrogen gas supplied to the catholyte deaerating means, wherein the electrolysis arrangement comprises a hydrogen purification unit configured for the removal of oxygen and water from the hydrogen gas separated in the catholyte gas-liquid separator, whereby a purified hydrogen gas is obtainable by means of the hydrogen purification unit,
wherein the hydrogen gas supplied to the catholyte deaerating means comprises the purified hydrogen gas obtainable by means of the hydrogen purification unit.

8 . The electrolysis arrangement according to claim 1 , wherein the anolyte deaerating means is configured for the degassing of the oxygen depleted anolyte by means of oxygen gas supplied to the anolyte deaerating means.

9 . The electrolysis arrangement according to claim 1 , wherein the anolyte deaerating means and/or the catholyte deaerating means comprises a heating means in order to degas the hydrogen depleted catholyte and/or the oxygen depleted anolyte.

10 . A method for producing hydrogen and oxygen by electrolysis of an alkaline electrolysis medium, the method comprising the method steps of
electrochemical splitting of water contained in the alkaline electrolysis medium by means of an electrolysis cell stack, whereby a hydrogen loaded catholyte withdrawn from a cathode section of the electrolysis cell stack and an oxygen loaded anolyte withdrawn from an anode section of the electrolysis cell stack are obtained; supplying the hydrogen loaded catholyte to a catholyte gas-liquid separator to separate hydrogen from the hydrogen loaded catholyte, whereby hydrogen gas and a hydrogen depleted catholyte are obtained; supplying the oxygen loaded anolyte to an anolyte gas-liquid separator to separate oxygen from the oxygen loaded anolyte, whereby oxygen gas and an oxygen depleted anolyte are obtained; withdrawing the hydrogen depleted catholyte from the catholyte gas-liquid separator, optionally cooling the hydrogen depleted catholyte and supplying the hydrogen depleted catholyte to the cathode section of the electrolysis cell stack; withdrawing the oxygen depleted anolyte from the anolyte gas-liquid separator, optionally cooling the oxygen depleted anolyte and supplying the oxygen depleted anolyte to the anode section of the electrolysis cell stack; degassing the hydrogen depleted catholyte withdrawn from the catholyte gas-liquid separator by means of a catholyte deaerating means and supplying the degassed hydrogen depleted catholyte to the electrolysis cell stack and/or degassing the oxygen depleted anolyte withdrawn from the anolyte gas-liquid separator by means of an anolyte deaerating means and supplying the degassed oxygen depleted anolyte to the electrolysis cell stack.

11 . The method according to claim 10 , wherein the alkaline electrolysis medium is a concentrated lye solution.

12 . The method according to claim 10 , wherein the degassing of the hydrogen depleted catholyte and/or the degassing of the oxygen depleted anolyte is carried out before cooling of the hydrogen depleted catholyte and the oxygen depleted anolyte.

13 . The method according to claim 10 , wherein the hydrogen gas separated in the catholyte gas-liquid separator is withdrawn from said gas-liquid separator and supplied to a hydrogen purification unit for removal of water and oxygen, to obtain a purified hydrogen gas.

14 . The method according to claim 10 , wherein the degassing of the hydrogen depleted catholyte is effected by introducing hydrogen gas into the hydrogen depleted catholyte.

15 . The method according to claim 1 , wherein the degassing of the hydrogen depleted catholyte is effected by introducing hydrogen gas into the hydrogen depleted catholyte,
wherein the degassing of the hydrogen depleted catholyte is affected by introducing purified hydrogen gas into the hydrogen depleted catholyte, wherein the hydrogen gas separated in the catholyte gas-liquid separator is withdrawn from said gas-liquid separator and supplied to a hydrogen purification unit for removal of water and oxygen, to obtain a purified hydrogen gas.

16 . The method according to claim 10 , wherein the degassing of the oxygen depleted anolyte is effected by introducing oxygen gas into the ox

Assignees

• Air Liquide

Inventors

• Khy Marie-Khuny
• Butler Maxime
• Portier Marie

Classifications

• Y02E60/36

  Hydrogen production from non-carbon containing sources, e.g. by water electrolysis · CPC title

• C25B1/04 Primary

  by electrolysis of water · CPC title

• C25B15/083

  Separating products · CPC title

• C25B9/67

  Heating or cooling means · CPC title

• C25B15/087

  Recycling of electrolyte to electrochemical cell · CPC title