Superabsorbent Polymer and Method for Preparing the Same

Patent metadata

Field	Value
Publication number	US-2023118840-A1
Application number	US-202117792347-A
Country	US
Kind code	A1
Filing date	Apr 13, 2021
Priority date	Apr 13, 2020
Publication date	Apr 20, 2023
Grant date	—

Abstract

A superabsorbent polymer that may continuously and safely exhibit improved bacterial growth inhibition property and deodorization property, without deterioration of the properties of superabsorbent polymer such as centrifuge retention capacity and absorption under pressure, and the like, and a method for preparing the same are provided.

First claim

1 . A superabsorbent polymer comprising:
a base resin comprising crosslinked polymer of acrylic acid-based monomers having acid groups, at least a part of the acid groups being neutralized, and an internal crosslinking agent, wherein at least a part of the base resin is surface-treated by a first surface crosslinking agent, and the first surface crosslinking agent is one or more selected from the group consisting of a cationic compound, a terpene-based compounds, a phenol-based compounds, and a phosphoric acid-based compounds.

2 . The superabsorbent polymer according to claim 1 , wherein the cationic compound is a guanidine-based compound.

3 . The superabsorbent polymer according to claim 2 , wherein the guanidine-based compound is guanidine carbonate, or guanidine hydrochloride.

4 . The superabsorbent polymer according to claim 1 , wherein the terpene-based compound is menthol, or citronellol.

5 . The superabsorbent polymer according to claim 1 , wherein the phenol-based compound is gallic acid, tannic acid, coumaric acid, caffeic acid, ferulic acid or protocatechuic acid.

6 . The superabsorbent polymer according to claim 1 , wherein the phosphoric acid-based compound is phosphoric acid, phosphonic acid, amino phosphonic acid, phosphinic acid, bis(aminomethyl) phosphinic acid, or bis(hydroxymethyl) phosphinic acid.

7 . The superabsorbent polymer according to claim 1 , wherein at least a part of the base resin is surface-treated by theft first surface crosslinking agent and a second surface crosslinking agent.

8 . The superabsorbent polymer according to claim 7 , wherein the second surface crosslinking agent comprises one or more of polyhydric alcohol-based compounds; epoxy compounds; polyamine compounds; haloepoxy compounds; condensation products of haloepoxy compounds; oxazoline compounds; mono-, di- or polyoxazolidinone compounds; cyclic urea compounds; multivalent metal salts; or alkylene carbonate-based compounds.

9 . The superabsorbent polymer according to claim 1 , wherein the first surface crosslinking agent is included in an amount of 0.01 to 10 parts by weight, based on 100 parts by weight of the base resin.

10 . The superabsorbent polymer according to claim 7 , wherein a centrifuge retention capacity (CRC) measured according to EDANA method WSP 241.3 is 28 g/g to 60 g/g.

11 . The superabsorbent polymer according to claim 7 , wherein an absorption under pressure (AUP) of 0.7 psi, measured according to EDANA method WSP 242.3 is 8 g/g to 37 g/g.

12 . (canceled)

13 . The superabsorbent polymer according to claim 1 , wherein the superabsorbent polymer has a core-shell structure in which the base resin is a core, and a surface crosslink layer covers the core in the form of a shell.

14 . The superabsorbent polymer according to claim 7 , wherein a centrifuge retention capacity (CRC) measured according to EDANA method WSP 241.3 is 28 g/g to 40 g/g.

15 . The superabsorbent polymer according to claim 7 , wherein an absorption under pressure (AUP) of 0.7 psi, measured according to EDANA method WSP 242.3, is 20 g/g to 37 g/g.

16 . (canceled)

17 . The superabsorbent polymer according to claim 7 , wherein the superabsorbent polymer has a core-shell structure in which the base resin is a core, and a surface crosslink layer covers the core in the form of a shell.

18 . A method for preparing a superabsorbent polymer, comprising:
conducting crosslinking polymerization of acrylic acid-based monomers having acid groups, at least a part of the acid groups being neutralized, and an internal crosslinking agent, to form a hydrogel polymer; drying, grinding and classifying the hydrogel polymer to form a base resin; and crosslinking a surface of the base resin, in the presence of a first surface crosslinking agent, wherein the first surface crosslinking agent is one or more selected from the group consisting of cationic compounds, terpene-based compounds, phenol-based compounds, and phosphoric acid-based compounds.

19 . The method for preparing a superabsorbent polymer according to claim 18 , wherein the crosslinking the surface of the base resin is conducted at 150 to 220° C.

20 . The method for preparing a superabsorbent polymer according to claim 18 , wherein the crosslinking the surface of the base resin further comprises a second surface crosslinking agent.

21 . The method for preparing a superabsorbent polymer according to claim 20 , wherein the second surface crosslinking agent is one or more of polyhydric alcohol-based compounds; epoxy compounds; polyamine compounds; haloepoxy compounds; condensation products of haloepoxy compounds; oxazoline compounds; mono-, di- or polyoxazolidinone compounds; cyclic urea compounds; multivalent metal salts; or alkylene carbonate-based compounds.

22 . An article comprising superabsorbent polymer according to claim 1 , wherein the article is one or more of absorbent goods, hygienic goods, water-holding material for soil, water stop material for civil engineering and architecture, sheet for raising seedling, freshness preservatives, fomentation materials, electric insulators, oral or dental articles, or articles for cosmetics or skin.

23 . (canceled)

Assignees

• Lg Chemical Ltd

Inventors

• Yun Haesung
• Jung Seonjung
• Lee Ji Seok
• Choi Hyungsam
• Kim Byungguk
• Kim Sanggon

Classifications

• C08J2333/02

  Homopolymers or copolymers of acids; Metal or ammonium salts thereof · CPC title

• C08J3/245

  Differential crosslinking of one polymer with one crosslinking type, e.g. surface crosslinking · CPC title

• C08J3/075

  Macromolecular gels · CPC title

• C08F20/06

  Acrylic acid; Methacrylic acid; Metal salts or ammonium salts thereof · CPC title

• B01J20/28047

  Gels · CPC title